Environmental Engineering Research

  • 제24권4호
  • /
  • Pages.600-607
  • /
  • 2019
  • /
  • 1226-1025(pISSN)
  • /
  • 2005-968X(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
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Removal of volatile organic compounds from air using activated carbon impregnated cellulose acetate electrospun mats

  • Patil, Kashyap (Department of Chemical Engineering, Changwon National University) ;
  • Jeong, Seonju (Department of Advanced Materials and Chemical Engineering, Catholic University of Daegu) ;
  • Lim, Hankwon (Department of Advanced Materials and Chemical Engineering, Catholic University of Daegu) ;
  • Byun, Hun-Soo (Department of Chemical and Biomolecular Engineering, Chonnam National University) ;
  • Han, Sangil (Department of Chemical Engineering, Changwon National University)
  • 투고 : 2018.09.20
  • 심사 : 2018.12.01
  • 발행 : 2019.12.30
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초록

Volatile organic compounds (VOCs) are released from various sources and are unsafe for human health. Porous materials are promising candidates for the adsorption of VOCs owing to their increased ratio of surface area to volume. In this study, activated carbon (AC) impregnated cellulose acetate (CA) electrospun mats were synthesized using electrospinning for the removal of VOCs from the air mixture of ACs, and CA solution was electrospun at different proportions (5%, 10%, and 15%) in a single nozzle system. The different AC amounts in the electrospun mats were distributed within the AC fibers. The adsorption capacities were measured for acetone, benzene, and dichloromethane, using quartz crystal microbalance. The results elicited an increasing adsorption capacity trend as a function of the impregnation of ACs in the electrospun mats, while their capacities increased as a function of the AC concentration. Dichloromethane resulted in a faster adsorption process than acetone and benzene owing to its smaller molecular size. VOCs were desorbed with the N2 gas purging, while VOCs were adsorbed at higher temperatures owing to the increased vapor pressures. The adsorption analysis using Dubinin-Astakhov equation showed that dichloromethane is more strongly adsorbed on mats.

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참고문헌

  1. Dwivedi P, Gaur V, Sharma A, Verma N. Comparative study of removal of volatile organic compounds by cryogenic condensation and adsorption by activated carbon fiber. Sep. Purif. Technol. 2004;39:23-37. https://doi.org/10.1016/j.seppur.2003.12.016
  2. Huang C, Song M, Gu Z, Wang H, Yan X. Probing the adsorption characteristic of metal-organic framework MIL-101 for volatile organic compounds by quartz crystal microbalance. Environ. Sci. Technol. 2011;45:4490-4496. https://doi.org/10.1021/es200256q
  3. Das D, Gaur V, Verma N. Removal of volatile organic compound by activated carbon fiber. Carbon 2004;42:2949-2962. https://doi.org/10.1016/j.carbon.2004.07.008
  4. Nugent P, Belmabkhout Y, Burd SD, et al. Porous materials with optimal adsorption thermodynamics and kinetics for $CO_2$ separation. Nature 2013;495:1-5.
  5. Fletcher AJ, Cussen EJ, Prior TJ, Rosseinsky MJ. Adsorption dynamics of gases and vapors on the nanoporous MOF material $Ni_2(4,4'-Bipyridine)_3(NO_3)_4$: Guest modification of host sorption behaviour. J. Am. Chem. Soc. 2001;123:10001-10011. https://doi.org/10.1021/ja0109895
  6. Chiang Y, Chiang P, Huang C. Effects of pore structure and temperature on VOC adsorption on activated carbon. Carbon 2001;39:523-534. https://doi.org/10.1016/S0008-6223(00)00161-5
  7. Kim K, Ahn H. The effect of the pore structure of zeolite on the adsorption of VOCs and their desorption properties by microwave heating. Microporous Mesoporous Mater. 2012;152:78-83. https://doi.org/10.1016/j.micromeso.2011.11.051
  8. Yang K, Suna Q, Xue F, Lina D. Adsorption of volatile organic compounds by metal-organic frameworks MIL-101: Influence of molecular size and shape. J. Hazard. Mater. 2011;195:124-131. https://doi.org/10.1016/j.jhazmat.2011.08.020
  9. Huang Z, Zhang Y, Kotaki M, Ramakrishna S. A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos. Sci. Technol. 2003;63:2223-2253. https://doi.org/10.1016/S0266-3538(03)00178-7
  10. Carletto VA, Carletto RA, Mazzuchetti G. Experimental investigations on the multi-jet electrospinning process. J. Mater. Process. Technol. 2009;209:5178-5185. https://doi.org/10.1016/j.jmatprotec.2009.03.003
  11. Feng C, Khulbe KC, Tabe S. Volatile organic compound removal by membrane gas stripping using electrospun nanofiber membrane. Desalination 2012;287:98-102. https://doi.org/10.1016/j.desal.2011.04.074
  12. Shim WG, Kim C, Lee JW, et al. Adsorption characteristics of benzene on electrospun-derived porous carbon nanofibers. J. Appl. Polym. Sci. 2006;102:2454-2462. https://doi.org/10.1002/app.24554
  13. Li Q, Xu Y, Wei H, Wang X. An electrospun polycarbonate nano fibrous membrane for high-efficiency particulate matter filtration. RSC Adv. 2016;6:65275-65281. https://doi.org/10.1039/C6RA12320A
  14. Scholten E, Bromberg L, Rutledge GC, Hatton TA. Electrospun polyurethane fibers for absorption of volatile organic compounds from the air. ACS Appl. Mater. Interfaces 2010;3:3902-3909.
  15. Han S, Rutledge GC. Thermoregulated gas transport through electrospun nanofiber membranes. Chem. Eng. Sci. 2015;123:557-563. https://doi.org/10.1016/j.ces.2014.11.040
  16. Su CI, Shih JH, Huang MS, Wang CM, Shih WC, Liu YS. A study of hydrophobic electrospun membrane applied in seawater desalination by membrane distillation. Fiber. Polym. 2012;13:698-702. https://doi.org/10.1007/s12221-012-0698-3
  17. Muhammad SK, Shaikh AR, Mohammad MH. Catalytic oxidation of volatile organic compounds (VOCs) - A review. Atmos. Environ. 2016;140:117-134. https://doi.org/10.1016/j.atmosenv.2016.05.031
  18. Gupta VK, Verma N. Removal of volatile organic compounds by cryogenic condensation followed by adsorption. Chem. Eng. Sci. 2002;57:2679-2696. https://doi.org/10.1016/S0009-2509(02)00158-6
  19. Zhou Y, Zhou L, Zhang X, Chen Y. Preparation of zeolitic imidazolate framework-8/graphene oxide composites with enhanced VOCs adsorption capacity. Microporous Mesoporous Mater. 2016;225:488-493. https://doi.org/10.1016/j.micromeso.2016.01.047
  20. Liu P, Long C, Li Q, Qian H, Li A, Zhang Q. Adsorption of trichloroethylene and benzene vapors onto hypercrosslinked polymeric resin. J. Hazard. Mater. 2009;166:46-51. https://doi.org/10.1016/j.jhazmat.2008.10.124
  21. Goss KU, Eisenrreich SJ. Adsorption of VOCs from the gas phase to different minerals and a mineral mixture. Environ. Sci. Technol. 1996;30:2135-2142. https://doi.org/10.1021/es950508f
  22. Si P, Mortensen J, Komolov A, Denborg J, Moller PJ. Polymer coated quartz crystal microbalance sensors for detection of volatile organic compounds in gas mixtures. Anal. Chim. Acta 2007;597:223-230. https://doi.org/10.1016/j.aca.2007.06.050
  23. Xueyang Z, Bin G, Anne EC, Chengcheng C, Yuncong L. Adsorption of VOCs onto engineered carbon materials: A review. J. Hazard. Mater. 2017;338:102-123. https://doi.org/10.1016/j.jhazmat.2017.05.013
  24. Xiaofeng Lu, Ce W, Frédéric F, Nicola P. Electrospun nanomaterials for supercapacitor electrodes: Designed architectures and electrochemical performance. Adv. Energ. Mater. 2017;7:1601301. https://doi.org/10.1002/aenm.201601301
  25. Hongjiao N, Chi X, Wei Z, et al. Free-standing thin webs of activated carbon nanofibers by electrospinning for rechargeable $Li-O_2$ batteries. ACS Appl. Mater. Interfaces 2016;8:1937-1942. https://doi.org/10.1021/acsami.5b10088
  26. Vijayakumara E, Subramania A, Fei Z, Dyson PJ. High-performance dye-sensitized solar cell based on an electrospun poly(vinylidene fluoride-co-hexafluoropropylene)/cobalt sulfide nanocomposite membrane electrolyte. RSC Adv. 2015;5:52026-52032. https://doi.org/10.1039/C5RA04944J
  27. Kumar A, Brunet J, Varenne C, et al. Tetra-tert-butyl copper phthalocyanine-based QCM sensor for toluene detection in air at room temperature. Sensor. Actuat. B-Chem. 2015;210:398-407. https://doi.org/10.1016/j.snb.2015.01.010
  28. Lu F, Lee HP, Lim SP. Quartz crystal microbalance with rigid mass partially attached on electrode surfaces. Sensor. Actuat. A-Phys. 2004;112:203-210. https://doi.org/10.1016/j.sna.2004.01.018
  29. Gaikwad S, Kim S, Han S. $CO_2$ capture using amine-functionalized bimetallic MIL-101 MOFs and their stability on exposure to humid air and acid gases. Microporous Mesoporous Mater. 2019;277:253-260. https://doi.org/10.1016/j.micromeso.2018.11.001
  30. Huang C, Song M, Gu Z, Wang H, Yan X. Probing the adsorption characteristic of metal organic framework MIL-101 for volatile organic compounds by quartz crystal microbalance. Environ. Sci. Technol. 2011;45:4490-4496. https://doi.org/10.1021/es200256q

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