DOI QR코드

DOI QR Code

Biosorption of methylene blue from aqueous solution by agricultural bioadsorbent corncob

  • Choi, Hee-Jeong (Department of Health and Environment, Catholic Kwandong University) ;
  • Yu, Sung-Whan (Department of Health and Environment, Catholic Kwandong University)
  • 투고 : 2018.03.19
  • 심사 : 2018.06.20
  • 발행 : 2019.03.31

초록

Using the abandoned agricultural by-product corncobs, the most commonly used methylene blue (MB) dyestuffs were removed. This experiment is very meaningful because it is the recycling of resources and the use of environmentally friendly adsorbents. According to the Hauser ratio and porosity analysis, the corncob has a good flow ability of the adsorbent material and many pores, which is very advantageous for MB adsorption. As a result of the experiment, MB concentration of less than 0.005 g/L was very efficiently removed with 10 g/L of bioadsorbent corncob and the maximum adsorption capacity of corncob for MB dyes was obtained at 417.1 mg/g. In addition, adsorption process of MB onto corncob was a physical process according to adsorption energy analysis. Corncob can efficiently and environmentally remove MB in aqueous solution, and is very cost effective and can recycle the abandoned resources.

키워드

참고문헌

  1. Annadurai G, Juang RS, Lee DJ. Use of cellulose-based wastes for adsorption of dyes from aqueous solutions. J. Hazard. Mater. 2002;B92:263-274. https://doi.org/10.1016/S0304-3894(02)00017-1
  2. Ahmed MJ, Dhedan SK. Equilibrium isotherms and kinetics modeling of methylene blue adsorption on agricultural wastes-based activated carbons. Fluid Phase Equilib. 2010;317:9-14. https://doi.org/10.1016/j.fluid.2011.12.026
  3. Lee S, Ong S. Oxalic acid modified rice hull as a sorbent for methylene blue removal. APCBEE Procedia 2014;9:165-169. https://doi.org/10.1016/j.apcbee.2014.01.029
  4. Choi HJ, Kim KH. Parametric study a dyeing wastewater treatment by modified sericite. Environ. Technol. 2016;37:2572-2579. https://doi.org/10.1080/09593330.2016.1155652
  5. Peydayesh M, Kelishami AR. Adsorption of methylene blue onto Platanus orientalis leaf powder: Kinetic, equilibrium and thermodynamic studies. J. Ind. Eng. Chem. 2015;21:1014-1019. https://doi.org/10.1016/j.jiec.2014.05.010
  6. Yagub MT, Sen TK, Afroze S, Ang HM. Dye and its removal from aqueous solution by adsorption: A review. Adv. Colloid Interf. Sci. 2014;209:172-184. https://doi.org/10.1016/j.cis.2014.04.002
  7. Ebrahimian A, Saberikhah E, Badrouh M, Emami MS. Alkali treated foumanat tea waste as an efficient adsorbent for methylene blue adsorption from aqueous solution. Water Resour. Ind. 2014;6:64-80. https://doi.org/10.1016/j.wri.2014.07.003
  8. Gong R, Li M, Yang C, Sun Y, Chen J. Removal of cationic dyes from aqueous solution by adsorption on peanut hull. J. Hazard. Mater. 2005;B121:247-250.
  9. Rafatullah M, Sulaiman O, Hashim R, Ahmad A. Adsorption of methylene blue on low-cost adsorbents: A review. J. Hazard. Mater. 2010;177:70-80. https://doi.org/10.1016/j.jhazmat.2009.12.047
  10. Balarak D, Jaafari J, Hassani G, et al. The use of low cost adsorbent (Canola residues) for the adsorption of methylene blue from aqueous solution: Isotherm, kinetic and thermodynamic studies. Colloid Interf. Sci. Commun. 2015;7:16-19. https://doi.org/10.1016/j.colcom.2015.11.004
  11. Kamel HA, Jibouri A, Wu J, Upreti SR. Continuous ozonation of methylene blue in water. J. Water Process Eng. 2015;8:142-150. https://doi.org/10.1016/j.jwpe.2015.10.002
  12. Kumar PS, Abhinaya RV, Arthi V, Gayathrilashmi K, Priyadharshini M, Sivanesan S. Adsorption of methylene blue dye onto surface modified cashew nut shell. Environ. Eng. Manag. J. 2014;13:545-556. https://doi.org/10.30638/eemj.2014.058
  13. Sych NV, Trofymenko SJ, Poddubnaya OI, et al. Porous structure and surface chemistry of phosphoric acid activated carbon from corncob. Appl. Surf. Sci. 2012;261:75-82. https://doi.org/10.1016/j.apsusc.2012.07.084
  14. Abdelfattah I, Ismail AA, Sayed FA, Almedolab A, Aboeloghait KM. Biosorption of heavy metals ions in real industrial wastewater using peanut husk as efficient and cost effective adsorbent. Environ. Nanotechnol. Monit. Manag. 2016;6:176-183. https://doi.org/10.1016/j.enmm.2016.10.007
  15. Pirbazari AE, Saberikhah E. $Fe_3O_4$- wheat straw: Preparation, characterization and its application for methylene blue adsorption. Water Res. Ind. 2014;7-8:23-37. https://doi.org/10.1016/j.wri.2014.09.001
  16. Pereira H, Carvalho D, Huang J, et al. Improvement of methylene blue removal by electrocoagulation/banana peel adsorption coupling in a batch system. Alexandria Eng. J. 2015;54:777-786. https://doi.org/10.1016/j.aej.2015.04.003
  17. Argun ME, Guclu D, Karatas M. Adsorption of reactive blue 114 dye by using a new adsorbent: pomelo peel. J. Ind. Eng. Chem. 2014;20:1079-1084. https://doi.org/10.1016/j.jiec.2013.06.045
  18. Low LW, Teng TT, Morad N, Azahari B. Studies on the adsorption of methylene blue dye from aqueous solution onto low-cost tartaric acid treated bagasse. APCBEE Procedia 2012;1:103-109. https://doi.org/10.1016/j.apcbee.2012.03.018
  19. Vadivelan V, Kumar KV. Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk. J. Colloid Interf. Sci. 2005;286:90-100. https://doi.org/10.1016/j.jcis.2005.01.007
  20. Kumar PS, Abhinaya RV, Lashmi KG, Arthi V, Pavithra R, Sathyaselvabala V. Adsorption of methylene blue dye from aqueous solution by agricultural waste: Equilibrium, thermodynamics, kinetics, mechanism and process design. Colloid J. 2011;73:651-661. https://doi.org/10.1134/S1061933X11050061
  21. Kumar PS, Fernando PSA, Ahmed RT, et al. Effect of temperature on the adsorption of methylene blue dye onto sulphuric acid-treated orange peel. Chem. Eng. Commun. 2014;201:1526-1547. https://doi.org/10.1080/00986445.2013.819352
  22. Kumar PS, Sivaranjanee R, Vinothini U, Raghavi M, Rajasekar K, Ramakrishnan K. Adsorption of dye onto raw and surface modified tamarind seeds: Isotherms, process design, kinetics and mechanism. Desalin. Water Treat. 2014;52:2620-2633. https://doi.org/10.1080/19443994.2013.792016
  23. Gupta VK, Nayak A. Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and $Fe_2O_3$ nanoparticles. Chem. Eng. J. 2012;80:81-90. https://doi.org/10.1016/j.ces.2012.06.007
  24. Nwadiogbu JO, Ajiwe VIE, Okoye PAC. Removal of crude oil from aqueous medium by sorption on hydrophobic corncobs: Equilibrium and kinetics studies. J. Taibah Univ. Sci. 2016;10:56-63. https://doi.org/10.1016/j.jtusci.2015.03.014
  25. El-Sayed G, Yehia MM, Asaad AA. Assessment of activated carbon prepared from corncob by chemical activation with phosphoric acid. Water Res. Ind. 2014;7-8:66-75. https://doi.org/10.1016/j.wri.2014.10.001
  26. Azubuike CP, Okhamafe AO. Physicochemical, spectroscopic and thermal properties of microcrystalline cellulose derived from corncobs. Int. J. Recycl. Org. Waste Agr. 2012;1:9-11. https://doi.org/10.1186/2251-7715-1-9
  27. Hameed BH, Ahmad AA. Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass. J. Hazard. Mater. 2009;164:870-875. https://doi.org/10.1016/j.jhazmat.2008.08.084
  28. Salazar-Rabage JJ, Leyva-Ramos R, Rivera-Utrilla J, Ocampo-Perez R, Cerino-Cordova FJ. Biosorption mechanism of methylene blue from aqueous solution onto white pine (Pinus durangensis) sawdust: Effect of operating conditions. Sustain. Environ. Res. 2017;7:32-40.
  29. Yao YJ, Xu FF, Chen M, Xu ZX, Zhu ZW. Adsorption behavior of methylene blue on carbon nanotubes. Bioresour. Technol. 2010;101:3040-3046. https://doi.org/10.1016/j.biortech.2009.12.042
  30. Ali RM, Hamad HA, Hussein MM, Malash GF. Potential of using green adsorbent of heavy metal removal from aqueous solutions: Adsorption kinetics, isotherm, thermodynamic, mechanism and economic analysis. Ecol. Eng. 2016;91:317-332. https://doi.org/10.1016/j.ecoleng.2016.03.015
  31. Hameed BH, Ahmad AL, Latiff KNA. Adsorption of basic dye (methylene dye) onto activated carbon prepared from rattan sawdust. Dyes Pigm. 2007;75:143-146. https://doi.org/10.1016/j.dyepig.2006.05.039
  32. Zhang S, Wang Z, Zhang Y, Pan H, Tao L. Adsorption of methylene blue on organosolv lignin from rice straw. Procedia Environ. Sci. 2016;31:3-11. https://doi.org/10.1016/j.proenv.2016.02.001
  33. Uddin MT, Islam MA, Mahmud S, Rukanuzzaman M. Adsorptive removal of methylene blue by tea waste. J. Hazard. Mater. 2009;164:53-60. https://doi.org/10.1016/j.jhazmat.2008.07.131

피인용 문헌

  1. 표면개질된 소나무 수피를 이용한 수용액의 구리이온 흡착 vol.33, pp.2, 2019, https://doi.org/10.11001/jksww.2019.33.2.131
  2. Regeneration of Washing Effluents for Remediation of Petroleum-Hydrocarbons-Contaminated Soil by Corncob-Based Biomass Materials vol.4, pp.20, 2019, https://doi.org/10.1021/acsomega.9b02651
  3. Design of Crosslinked Hydrogels Comprising Poly(Vinylphosphonic Acid) and Bis[2-(Methacryloyloxy)Ethyl] Phosphate as an Efficient Adsorbent for Wastewater Dye Removal vol.10, pp.1, 2020, https://doi.org/10.3390/nano10010131
  4. Adsorption of Methylene Blue from Aqueous Solution by Pumpkin-Seed Residue vol.42, pp.1, 2019, https://doi.org/10.4491/ksee.2020.42.1.10
  5. Evaluation of several white-rot fungi for the decolorization of a binary mixture of anionic dyes and characterization of the residual biomass as potential organic soil amendment vol.254, 2020, https://doi.org/10.1016/j.jenvman.2019.109805
  6. Response Surface Optimization of Graphene Oxide-Reinforced Dual-Crosslinked Alginate/Poly(Vinyl Alcohol) Hydrogel Beads for Methylene Blue Adsorption vol.1005, 2020, https://doi.org/10.4028/www.scientific.net/msf.1005.101
  7. Performance and characteristics of methylene blue adsorption using nanomagnetite graphite adsorbent vol.615, 2019, https://doi.org/10.1088/1755-1315/615/1/012071
  8. Studies on Adsorption Characteristics of Corn Cobs Activated Carbon for the Removal of Oil and Grease from Oil Refinery Desalter Effluent in a Downflow Fixed Bed Adsorption Equipment vol.5, pp.1, 2021, https://doi.org/10.29333/ejosdr/9285
  9. Study on isotherm, kinetics, and thermodynamics of adsorption of crystal violet dye by calcium oxide modified fly ash vol.26, pp.1, 2021, https://doi.org/10.4491/eer.2019.372
  10. Removal of methylene blue from aqueous solution using Lathyrus sativus husk: Adsorption study, MPR and ANN modelling vol.149, 2019, https://doi.org/10.1016/j.psep.2020.11.003
  11. Optimization, Equilibrium and Kinetic Modeling of Methylene Blue Removal from Aqueous Solutions Using Dry Bean Pods Husks Powder vol.14, pp.19, 2019, https://doi.org/10.3390/ma14195673
  12. New micronutrient biocomponents based on blackcurrant seeds pomace - Bench-scale kinetic studies vol.32, pp.8, 2019, https://doi.org/10.1177/0958305x20942106
  13. Sono-assisted adsorption of acid violet 7 and basic violet 10 dyes from aqueous solutions: Evaluation of isotherm and kinetic parameters vol.27, pp.1, 2019, https://doi.org/10.4491/eer.2020.287
  14. Assessment of sulfonation in lignocellulosic derived material for adsorption of methylene blue vol.27, pp.3, 2019, https://doi.org/10.4491/eer.2021.034