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Physical and Mechanical Properties of Methyl Methacrylate-Impregnated Wood from Three Fast-Growing Tropical Tree Species

  • Hadi, Yusuf Sudo (Forest Products Department, IPB University (Bogor Agricultural University)) ;
  • Massijaya, Muh Yusram (Forest Products Department, IPB University (Bogor Agricultural University)) ;
  • Zaini, Lukmanul Hakim (Forest Products Department, IPB University (Bogor Agricultural University)) ;
  • Pari, Rohmah (Forest Products Research and Development Center)
  • Received : 2019.01.11
  • Accepted : 2019.05.13
  • Published : 2019.05.25

Abstract

Timber from plantation forests has inferior physical and mechanical properties compared to timber from natural forest because it is mostly from fast-growing tree species that are cut at a young age. Filling cell voids with methyl methacrylate (MMA) can improve the wood properties. The purpose of this study was to determine the physical and mechanical properties of MMA-impregnated wood from three fast-growing wood species, namely jabon (Anthocephalus cadamba (Roxb.) Miq.), mangium (Acacia mangium Willd) and pine (Pinus merkusii Jungh. & de Vriese). Wood samples were either immersed in MMA monomer or impregnated with it and then heated to induce the polymerization process. Jabon, which was the lowest density wood, had the highest polymer loading, followed by pine and mangium. The physical and mechanical properties of samples were affected by wood species and the presence of MMA, with higher-density wood having better properties than wood with a lower density. Physical and mechanical properties of MMA wood were enhanced compared to untreated wood. Furthermore, the impregnation process was better than immersion process resulting the physical and mechanical properties. Based on MOR values, the MMA woods were one strength class higher compared to untreated wood with regard to Strength Classification of Indonesian Wood.

Keywords

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Fig. 1. Entering MMA monomer to the wood voids: (a) immersion- and (b) impregnation-process.

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Fig. 2. MOR-MOE tested wood specimens: (a) MMAimpregnated pine, (b) MMA immersed mangium, and(c) untreated jabon.

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Fig. 3. Side- and end-hardness tested wood specimens:(a) untreated jabon, (b) MMA immersed pine, and(c) MMA impregnated mangium.

Table 1. Strength classification of Indonesian wood

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Table 2. Physical properties of each wood species and treatmenta

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Table 3. Analysis of variance results (F test) for physical properties

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Table 4. Further data analysis of wood species factor in physical and mechanical propertiesa

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Table 5. Further data analysis of treatment factor in physical and mechanical propertiesa

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Table 6. Mechanical properties of each wood species and treatmenta

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Table 7. Analysis of variance results (F test) for mechanical properties

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References

  1. [ASTM] American Society forTesting Materials. 1992. Direct moisture content measurement of wood and wood-base materials (ASTM D4442-92). ASTM International, West Conshohocken, PA.
  2. [ASTM] American Society for Testing Materials. 2007. Specific gravity of wood and wood-based materials (ASTM D2395-07). ASTM International, West Conshohocken, PA.
  3. [BS] British Standard. 1957. Methods of testing small clear specimens of timber (BS 373:1957).
  4. Cho, N.S., Jo, J.M., Ahn, W.Y. 1974. On the manufacturing of WPC (Wood Plastic Composites) with heat catalyst polymerization (I) On the characteristics of composites made from monomer methyl methacrylate and several commercial woods in Korea. J. of Korean Wood Science and Technology 2(3): 3-16
  5. Ding, W.D., Koubaa, A., Chaala, A., Belem, T., Krause, C. 2008. Relationship between wood porosity, wood density and methyl methacrylate impregnation rate. Wood Material Science & Engineering 3(1-2): 62-67. https://doi.org/10.1080/17480270802607947
  6. Ding, W.D., Koubaaa, A., Chaala, A. 2012. Dimensional stability of methyl methacrylate hardened hybrid poplar wood. BioResources 7(1): 504-520.
  7. Fajriani, E., Ruelle, J., Dlouha, J., Fournier, M., Hadi, Y.S., Darmawan, W. 2013. Radial variation of wood properties of sengon (Paraserianthes falcataria) and jabon (Anthocephalus cadamba). J. Indian Academy of Wood Science. 10(2): 110-117. https://doi.org/10.1007/s13196-013-0101-z
  8. Hadi, Y.S., Darma, I.G.K.T., Febrianto, F., Herliyana, E.N. 1995. Acetylated rubber-wood flakeboard resistance to bio-deterioration. Forest Products Journal 45(10): 64-66.
  9. Hadi, Y.S., Nawawi, D.S., Herliyana, E.N., Lawniczak, M. 1998. Termite attack resistance of four polystyrene impregnated woods from Poland. Forest Products Journal 48(9): 60-62.
  10. Hadi, Y.S., Westin, M., Rasyid, E. 2005. Resistance of furfurylated wood to termite attack. Forest Products Journal 55(11): 85-88.
  11. Hadi, Y.S., Hadjib, N., Utama, M. 2008. Effect of urea concentration and vacuum treatment on physical and mechanical properties of methyl methacrylate bamboo. Molecular Crystals and Liquid Crystals 484: 151-156. https://doi.org/10.1080/15421400801904369
  12. Hadi, Y.S., Rahayu, I.S., Danu, S. 2013. Physical and mechanical properties of methyl methacrylate impregnated jabon wood. Journal of the Indian Academy of Wood Science 10(2): 77-80. https://doi.org/10.1007/s13196-013-0098-3
  13. Hadi, Y.S., Massijaya, M.Y., Hermawan, D., Arinana, A. 2015a. Feeding rate of termites in wood treated with borax, acetylation, polystyrene, and smoke. Journal of the Indian Academy of Wood Science 12(1): 74-80. https://doi.org/10.1007/s13196-015-0146-2
  14. Hadi, Y.S., Rahayu, I.S., Danu, S. 2015b. Termite resistance of jabon wood impregnated with methyl methacrylate. Journal of Tropical Forest Science 27: 25-29.
  15. Hadi, Y.S., Massijaya, M.Y., Zaini, L.H., Abdillah, I.B., Arsyad, W.O.M. 2018. Resistance of methyl methacrylate impregnated wood to subterranean termite attack. Journal of the Korean Wood Science and Technology 46(6): 748-755. https://doi.org/10.5658/WOOD.2018.46.6.748
  16. Hartono, R., Hidayat, W., Wahyudi, I., Febrianto, F., Dwianto, W., Jang, J.H., Kim, N.H. 2016. Effect of phenol formaldehyde impregnation on the physical and mechanical properties of soft-inner part of oil palm trunk. Journal of the Korean Wood Science and Technology 44 (6): 842-851. https://doi.org/10.5658/WOOD.2016.44.6.842
  17. Hendrik, J., Hadi, Y.S., Massijaya, M.Y., Santoso, A. 2016. Properties of laminated panels made from fast-growing species glued with mangium tannin adhesive. BioResources 11(3): 5949-5960.
  18. Islam, M.S., Hamdan, S., Jusoh,I., Rahman, M.R., Talib, Z.A. 2011. Dimensional stability and dynamic Young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with hexamethylene diisocyanate cross-linker. Industrial & Engineering Chemistry Research (2011)50: 3900-3906. https://doi.org/10.1021/ie1021859
  19. Koubaa, A., Ding, W.D., Chaala,A., Bouafif, H. 2012. Surface properties of methyl methacrylate hardened hybrid poplar wood. Journal of Applied Polymer Science 123: 1428-1436. https://doi.org/10.1002/app.33799
  20. Lee, W.Y. 1983. Plastic combination on the penetration of MMA polymer and dimensional stability. Journal of the Korean Wood Science and Technology 11(3):49-57.
  21. Martawijaya, A., Kartasujana, I., Kadir, K., Prawira, S.A. 2005. Atlas Kayu Indonesia (Indonesian Wood Atlas). Ministry of Forestry, Forestry Development and Research Agency, Bogor, Indonesia.
  22. Ministry of Environment and Forestry. 2017. Statistic of Indonesian Forestry. Jakarta, Indonesia.
  23. Olpan, D., Guven, O. 2001.Modification of some mechanical properties of spruce by radiation induced copolymerization of acrylonitrile and methyl methacrylate with allyl glycidyl ether. Polymer. Composites 22(1): 90-96. https://doi.org/10.1002/pc.10520
  24. Prabawa, S.B. 2005. The physical and fiber dimension properties of 4-year old mangium wood from Sebulu of East Kalimantan. Jurnal Penelitian Hasil Hutan (Forest Products Research Journal) 23(5):339-348. https://doi.org/10.20886/jphh.2005.23.5.339-348
  25. Wang, X., Cui, Y., Zhang, H., Xie, B. 2012.Effects of methyl methacrylate grafting and polyamide coating on the interfacial behavior and mechanical properties of jute-fiber-reinforced polypropylene composites. Journal of Vinyl and Additive Technology 18(2):113-119. https://doi.org/10.1002/vnl.20296
  26. Won, K.R., Hong, N.E., Park, H.M., Byeon, H,S,. 2016. Evaluation of sapwood and heartwood decay resistance after immersion treatment with pyroligneous liquor. Journal of the Korean Wood Science and Technology 44(6): 880-889. https://doi.org/10.5658/WOOD.2016.44.6.880