DOI QR코드

DOI QR Code

Synthesis of Mesoporous Hollow Silica Sphere Using Water Glass: Filler for Weight Reduction of Rubber

  • 투고 : 2020.10.05
  • 심사 : 2020.10.25
  • 발행 : 2020.12.31

초록

In this study, mesoporous hollow silica spheres were synthesized using a polystyrene core and cetyltriammonium chloride (CTACl) as a pore template, and a low-cost water glass instead of expensive tetraethyl orthosilicate (TEOS) as a precursor. In addition, the material was synthesized by varying the concentration of polystyrene. Later, the polystyrene core and CTACl were removed by firing in a high-temperature heat-treatment process. The synthesized product was analyzed by various methods, such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffractometry (XRD), and N2-sorption analysis. It was confirmed that the hollow silica sphere had a hexagonal structure with a Brunauer-Emmett-Teller (BET) specific area of 1623 ㎡/g.

키워드

참고문헌

  1. L. D. Keklikian and R. E. Partch, "Microencapsulation of oil droplets by aerosol techniques---l. Metal oxide coatings", J. Aerosol Sci., 19 (1988).
  2. Y. S. Nam, J. K. Yu, G. W. Park, H. J. Kim, D. G. Kim, M. G. Kim, and K. Hyun, "Effect of Surface Modification of Hollow Glass Microspheres (HGM) in Rubber Composites", Polymer(Korea), 43, 567 (2019). https://doi.org/10.1016/S1089-3156(01)00011-3
  3. K. M. Lee, Y. G. Kim, and M. B. Moon, "New Technology for Light Weight Car Body", Trans. Mater. Process(Korea), 22, 286 (2013).
  4. J. Y. Lee, C. H. Park, and D. S. Kim, "Polymer materials used in shoes", Polymer Science and Technology(Korea), 13, 447 (2002).
  5. C. H. Ji, J. J. Li, C. J. Hou, D. Q. Huo, and L. Zhang, "Mesoprous hollow silica shells modified with functional diamine groups show high-performance absorption capacity and selective colorimetric response to copper ions in aqueous solutions", Seonsors and Actuators B : Chemical, 240, 718 (2017). https://doi.org/10.1016/j.snb.2016.09.017
  6. X. M. Guo, X. G. Liu, B. S. Xu, and T. Dou, "Synthesis and characterization of carbon sphere-silica core-shell structure and hollow silica spheres", Colloids and Surfaces A : Physicochemical and Engineering Aspects, 345, 141 (2009). https://doi.org/10.1016/j.colsurfa.2009.04.048
  7. S. G. Zhang, L. Xu, H. C. Liu, Y. F. Zhao, and Z. M. Liu, "A dual template method for synthesizing hollow silica spheres with mesoporous shells", Materials Letters, 63, 258 (2009). https://doi.org/10.1016/j.matlet.2008.10.004
  8. M. Yang, G. Wang, and Z. Z. Yang, "Synthesis of hollow spheres with mesoporous silica nanoparticles shell", Materials Chemistry and Physics, 111, 5 (2008). https://doi.org/10.1016/j.matchemphys.2008.03.014
  9. C. J. Tsou and C. Y. Mou, "Hollow mesoporous silica nanoparticles with tunable shell thickness and pore size distribution for application as broad-ranging pH nanosensor", Microporous and Mesoporous Materials, 190, 181 (2014). https://doi.org/10.1016/j.micromeso.2014.02.011
  10. J. W. Kim, J. W. Lee, H. K. Chang, J. W. Choi, and H. D. Jang, "Synthesis of hollow silica particles with tunable size, shell thickness, and morphology", Journal of Crystal Growth, 373, 128 (2013). https://doi.org/10.1016/j.jcrysgro.2012.09.047