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Preparation and Properties of Silicone Hydrogel Material Containing Silane Group with Cobalt Oxide Nanoparticles through Thermal Polymerization

  • Lee, Min-Jae (Department of Optometry & Vision Science, Daegu Catholic University) ;
  • Kong, Ki-Oh (R&D Center, Sooyang Chemtec Co.) ;
  • Sung, A-Young (Department of Optometry & Vision Science, Daegu Catholic University)
  • Received : 2020.03.03
  • Accepted : 2020.05.31
  • Published : 2020.06.27

Abstract

This research is conducted to analyze the compatibility of used monomers and produce the high functional hydrogel ophthalmic polymer containing silane and nanoparticles. VTMS (vinyltrimethoxysilane), TAVS [Triacetoxy(vinyl)silane] and cobalt oxide nanoparticles are used as additives for the basic combination of SilM (silicone monomer), MMA (methyl methacrylate) and MA (methyl acrylate). Also, the materials are copolymerized with EGDMA (ethylene glycol dimethacrylate) as cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the lenses of all combinations are optically excellent and thus have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic ophthalmic polymer are different in each case. Especially for TAVS, the addition of cobalt oxide nanoparticles increases the oxygen permeability. These materials are considered to create synergy, so they can be used in functional hydrogel ophthalmic lenses.

Keywords

References

  1. N. Efron, Contact lens practice, 3rd ed., p. 1-281, Elsevier, Edinburgh, UK (2010).
  2. A. N. Kimberly and W. G. Thomas, Am. J. Pathol., 153, 665 (1998). https://doi.org/10.1016/S0002-9440(10)65607-6
  3. N. P. D. Tran and M. C. Yang, Polymers, 11, 944 (2019). https://doi.org/10.3390/polym11060944
  4. L. Cheng, S. J. Muller and C. J. Radke, Curr. Eye Res., 28, 93 (2004). https://doi.org/10.1076/ceyr.28.2.93.26231
  5. D. D. Mitchell, U.S. Patent 4487905, 11 December 1984.
  6. R. C. Chromecek, W. G. Deichert, J. J. Falcetta and M. F. VanBuren, U.S. Patent 4276402, 30 June 1981.
  7. N. G. Gaylord, U. S. Patent 3808178, 30 April 1974.
  8. P. Keogh, J. F. Kunzler and G. C. C. Niu, U.S. Patent 4260725, 7 April 1981.
  9. H. Gleiter, Nanostruct. Mater., 6, 3 (1995). https://doi.org/10.1016/0965-9773(95)00025-9
  10. M. Valden, X. Lai and D. W. Goodman, Science, 281, 1647 (1998). https://doi.org/10.1126/science.281.5383.1647
  11. J. A. Rodriguez, G. Liu, T. Jirsak, Hrbek, Z. Chang, J. Dvorak and A. Maiti, J. Am. Chem. Soc., 124, 5247 (2002).
  12. M. Baumer and H. J. Freund, Surf. Sci., 61, 127 (1999).
  13. M. L. Trudeau and J. Y. Ying, Nanostruct. Mater., 7, 245 (1996). https://doi.org/10.1016/0965-9773(95)00308-8
  14. C. Noguera, Physics and Chemistry at Oxide Surfaces, p. 128-159, Cambridge University Press, Cambridge, UK (1996).
  15. H. H. Kung, Transition Metal Oxides: Surface Chemistry and Catalysis, p.1-281, Elsevier, Amsterdam (1989).
  16. V. E. Henrich and P. A. Cox, The Surface Chemistry of Metal Oxides, p.464, Cambridge University Press, Cambridge, UK (1994).
  17. A. F. Wells, Structural Inorganic Chemistry, 6th ed, p. 439-515, Oxford University Press, New York (1987).
  18. J. A. Rodriguez and M. Fernandez-Garcia, Synthesis, Properties and Applications of Oxide Nanoparticles, p. 137-714, Whiley, New Jersey (2007).
  19. M. Fernandez-Garcia, A. Martinez-Arias, J. C. Hanson, J. A. Rodriguez, Chem. Rev., 104, 4063 (2004). https://doi.org/10.1021/cr030032f
  20. X. H. Xia, J. P. Tu, J. Zhang, X. H. Huang, X. L. Wang, W. K. Zhang, H. Huang, Electrochemistry Communications, 10, 1815 (2008). https://doi.org/10.1016/j.elecom.2008.09.025
  21. ISO 18369-4:2017 (Ophthalmic Optics-Contact lenses Part 4:Physicochemical properties of contact lens materials;4.5 Refractive-Index).
  22. ISO 18369-4:2017 (Ophthalmic optics-Contact lenses-Part4: Physi chochemical properties of contact lens materials;4.6 water content).
  23. ANSI Z80.20-2010.
  24. ISO 18369-4:2017 (Ophthalmic Optics-Contact lenses Part 4:Physicochemical properties of contact lens materials;4.4.3 Polarographic method).
  25. KFDA Notification No. 2014-115, Korea, Ministry of Food and Drug Safety, General Standard for Biological Safety of Medical Devices.
  26. R. N. Wenzel, Ind. Eng. Chem., 28, 988 (1936). https://doi.org/10.1021/ie50320a024