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Study on combustion and emission characteristics of chars from low-temperature and fast pyrolysis of coals with TG-MS

  • Liu, Lei (State Key Laboratory of Heavy Oil, China University of Petroleum) ;
  • Gong, Zhiqiang (State Key Laboratory of Heavy Oil, China University of Petroleum) ;
  • Wang, Zhenbo (State Key Laboratory of Heavy Oil, China University of Petroleum) ;
  • Zhang, Haoteng (State Key Laboratory of Heavy Oil, China University of Petroleum)
  • Received : 2019.05.27
  • Accepted : 2019.08.01
  • Published : 2020.08.31

Abstract

To achieve the clean and efficient utilization of low-rank coal, the combustion and pollutant emission characteristics of chars from low-temperature and fast pyrolysis in a horizontal tube furnace were investigated in a TG-MS analyzer. According to the results, the combustion characteristic of chars was poorer than its parent coals. The temperature range of gaseous product release had a good agreement with that of TGA weight loss. Gaseous products of samples with high content of volatile were released earlier. The NO and NO2 emissions of chars were lower than their parent coals. Coals of high rank (anthracite and sub-bituminous) released more NO and NO2 than low rank coals of lignite, so were chars from coals of different ranks. SO2 emissions of char samples were lower than parent coals and did not show obvious relationship with coal ranks.

Keywords

References

  1. Wang M, Li Z, Huang W, Yang J, Xue H. Coal pyrolysis characteristics by TG-MS and its late gas generation potential. Fuel 2015;156:243-253. https://doi.org/10.1016/j.fuel.2015.04.055
  2. Russell NV, Beeley TJ, Man CK, Gibbins JR, Williamson J. Development of TG measurements of intrinsic char combustion reactivity for industrial and research purposes. Fuel Proc. Technol. 1998;57:113-130. https://doi.org/10.1016/S0378-3820(98)00077-0
  3. Shaw KJ, Beamish BB, Rodgers KA. Thermogravimetric analytical procedures for determining reactivities of chars from New Zealand coals. Thermochim. Acta. 1997;302:181-187. https://doi.org/10.1016/S0040-6031(97)00234-7
  4. Rong H, Sato JI, Chen Q, Chen C. Thermogravimetric analysis of char combustion. Combust. Sci. Technol. 2002;174:1-18.
  5. Basil BB, Shaw KJ, Rodgers KA, Newman J. Thermogravimetric determination of the carbon dioxide reactivity of char from some New Zealand coals and its association with the inorganic geochemistry of the parent coal. Fuel Proc. Technol. 1998;53:243-253. https://doi.org/10.1016/S0378-3820(97)00073-8
  6. Arenillas A, Rubiera F, Pis JJ, Jones JM, Williams A. The effect of the textural properties of bituminous coal chars on NO emissions. Fuel 1999;78:1779-1785. https://doi.org/10.1016/S0016-2361(99)00127-1
  7. Arenillas A, Pevida C, Rubiera F, GarciA R, Pis JJ. Characterisation of model compounds and a synthetic coal by TG/MS/FTIR to represent the pyrolysis behaviour of coal. J. Anal. Appl. Pyrol. 2004;71:747-763. https://doi.org/10.1016/j.jaap.2003.10.005
  8. Gong Z, Liu Z, Zhou T, Lu Q, Sun Y. Combustion and NO emission of Shenmu Char in a 2 MW circulating fluidized bed. Energ. Fuels 2015;29:1219-1226. https://doi.org/10.1021/ef502768w
  9. Gong Z, Xia H, Liu Z, Lu Q. TG-MS Study on Coal/Char combustion by equivalent characteristic spectrum analysis. In: Clean Coal Technology and Sustainable Development. Berlin:Springer; 2015.
  10. Wang S, Tang Y, Schobert HH, Guo Yn, Gao W, Lu X. FTIR and simultaneous TG/MS/FTIR study of late permian coals from Southern China. J. Anal. Appl. Pyrol. 2013;100:75-80. https://doi.org/10.1016/j.jaap.2012.11.021
  11. Zou C, Wu H, Zhao J, Li X. Effects of dust collection from converter steelmaking process on combustion characteristics of pulverized coal. Powder Technol. 2018;332:70-78. https://doi.org/10.1016/j.powtec.2018.03.012
  12. Zhao Z, Wang R, Ge L, Wu J, Yin Q, Wang C. Energy utilization of coal-coking wastes via coal slurry preparation: The characteristics of slurrying, combustion, and pollutant emission. Energy 2019;168:609-618. https://doi.org/10.1016/j.energy.2018.11.141
  13. Mehmood MA, Ahmad MS, Liu Q, et al. Helianthus tuberosus as a promising feedstock for bioenergy and chemicals appraised through pyrolysis, kinetics, and TG-FTIR-MS based study. Energ. Convers. Manage. 2019;194:37-45. https://doi.org/10.1016/j.enconman.2019.04.076
  14. Lu C, Wang X, Li R, et al. Emissions of fine particulate nitrated phenols from residential coal combustion in China. Atmos. Environ. 2019;203:10-17. https://doi.org/10.1016/j.atmosenv.2019.01.047
  15. Hu G, Liu G, Wu D, Fu B. Geochemical behavior of hazardous volatile elements in coals with different geological origin during combustion. Fuel 2018;233:361-376. https://doi.org/10.1016/j.fuel.2018.06.069
  16. Oliveira MLS, Boit KD, Pacheco F, et al. Multifaceted processes controlling the distribution of hazardous compounds in the spontaneous combustion of coal and the effect of these compounds on human health. Environ. Res. 2018;160:562. https://doi.org/10.1016/j.envres.2017.08.009
  17. Liu Z, Wang G, Li P, Li C. Investigation on combustion of high-sulfur coal catalyzed with industrial waste slags. J. Energ. Inst. 2019;92:621-629. https://doi.org/10.1016/j.joei.2018.03.010
  18. Li Z, Jiang L, Ouyang J, Cao L, Luo G, Yao H. A kinetic study on char oxidation in mixtures of O2, CO2 and H2O. Fuel Proc. Technol. 2018;179:250-257. https://doi.org/10.1016/j.fuproc.2018.07.007
  19. Wang L, Su S, Qing M, et al. Melting solidification and leaching behaviors of V/As during co-combustion of the spent SCR catalyst with coal. Fuel 2019;252:164-171. https://doi.org/10.1016/j.fuel.2019.03.150
  20. Guo F, Zhong Z. Optimization of the co-combustion of coal and composite biomass pellets. J. Clean. Prod. 2018;185:399-407. https://doi.org/10.1016/j.jclepro.2018.03.064
  21. Jiang Y, Zong P, Tian B, et al. Pyrolysis behaviors and product distribution of Shenmu coal at high heating rate: A study using TG-FTIR and Py-GC/MS. Energ. Convers. Manage. 2019;179:72-80. https://doi.org/10.1016/j.enconman.2018.10.049
  22. Salema AA, Ting RMW, Shang YK. Pyrolysis of blend (oil palm biomass and sawdust) biomass using TG-MS. Bioresour. Technol. 2019;274:439-446. https://doi.org/10.1016/j.biortech.2018.12.014
  23. Zhu Y, Wen W, Li Y, et al. Pyrolysis study of Huainan coal with different particle sizes using TG analysis and online Py-PI-TOF MS. J. Energ. Inst. 2019.
  24. Jayaraman K, Kok MV, Gokalp I. Pyrolysis, combustion and gasification studies of different sized coal particles using TGA-MS. Appl. Therm. Eng. 2017;125:1446-1455. https://doi.org/10.1016/j.applthermaleng.2017.07.128
  25. Fang P, Gong Z, Wang Z, Wang Z, Meng F. Study on combustion and emission characteristics of microalgae and its extraction residue with TG-MS. Renew. Energ. 2019;140:884-894. https://doi.org/10.1016/j.renene.2019.03.114
  26. Lin Y, Liao Y, Yu Z, Fang S, Ma X. A study on co-pyrolysis of bagasse and sewage sludge using TG-FTIR and Py-GC/MS. Energ. Convers.Manage. 2017;151:190-198. https://doi.org/10.1016/j.enconman.2017.08.062
  27. Li R, Chen Q, Xia H. Study on pyrolysis characteristics of pretreated high-sodium (Na) Zhundong coal by skimmer-type interfaced TG-DTA-EI/PI-MS system. Fuel Proc. Technol. 2018;170:79-87. https://doi.org/10.1016/j.fuproc.2017.10.023
  28. Gong Z, Wang Z, Wang Z, Fang P, Meng F. Study on the migration characteristics of nitrogen and sulfur during co-combustion of oil sludge char and microalgae residue. Fuel 2019;238:1-9. https://doi.org/10.1016/j.fuel.2018.10.087
  29. Wang Z, Gong Z, Wang Z, Fang P, Han D. A TG-MS study on the coupled pyrolysis and combustion of oil sludge. Thermochim. Acta. 2018;663:137-144. https://doi.org/10.1016/j.tca.2018.03.019
  30. Luo L, Liu J, Zhang H, Ma J, Wang X, Jiang X. TG-MS-FTIR study on pyrolysis behavior of superfine pulverized coal. J. Anal. Appl. Pyrol. 2017;128:64-74. https://doi.org/10.1016/j.jaap.2017.10.024
  31. Jayaraman K, Kok MV, Gokalp I. Thermogravimetric and mass spectrometric (TG-MS) analysis and kinetics of coal-biomass blends. Renew. Energ. 2017;101:293-300. https://doi.org/10.1016/j.renene.2016.08.072

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