한국포장학회지 (KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY)

한국포장학회 (Korea Society of Packaging Science and Technology)
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폴리에틸렌옥사이드가 PLA/PBAT 블렌드 물성에 미치는 영향

Effects of PEO Additions on the Mechanical and Thermal Proprieties of PLA/PBAT Blends

  • 투고 : 2020.08.14
  • 심사 : 2020.08.24
  • 발행 : 2020.08.31
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초록

PEO 첨가에 따른 PLA/PBAT 블렌드 필름의 물성개선 효과를 확인하였다. PEO 농도에 따른 영향을 확인하기 위하여 기계적특성, 열적특성 및 화학적 특성을 조사하였다. PEO 농도가 증가함에 따라 PLA/PBAT/PEO 블렌드 필름의 인장강도는 소폭 감소하지만 열안정성은 증가하였다. PEO 2% 첨가군은 다른 샘플들에 비해 인장강도 감소폭 대비 높은 파단연신율(46.8%) 개선 효과를 보였다. 반면, PEO 4% 수준에서 PEO 무첨가와 유사한 파단연신율과 인장강도의 저하가 발생하였다. 열특성 분석을 통해 PLA/PBAT 블렌드 내 낮은 혼화성으로 발생한 두개의 Tm 피크가 PEO 첨가로 상용성이 증가하여 피크가 하나로 합쳐지는 것을 확인하였다. 또한, 1H-NMR 분석을 통해 블렌드 내의 PEO의 농도가 증가함을 확인하였다. 향후, PEO 농도가 증가함에 따라 감소된 인장강도 유지와 파단연신율을 확보하기 위한 PEO의 분산성 향상에 대한 추가적인 연구가 필요하다.

The blends of Poly(lactic acid) (PLA) and Poly(butylene adipate-co-terephthalate) (PBAT) have been recognized as a replacement for commodity plastic films and bags in biodegradable packaging industries. The purpose of this study is to identify changes in the thermal and mechanical properties of PLA/PBAT blends with the addition of poly(ethylene oxide)(PEO). PLA (80%) and PBAT (20%) were melt mixed with 0 to 10 phr of PEO and processed using a hot press. The addition of PEO into PLA/PBAT increased the elongation at break and improved thermal stability. With PEO addition, two melting temperature (Tm) peaks of PLA/PBAT merged into one peak showing improved miscibility. The result of this study showed that the addition of PEO increased the ductility and thermal stability of PLA/PBAT blends.

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