DOI QR코드

DOI QR Code

Assessment of Corrosion Lifetime of a Copper Disposal Canister Based on the Finnish Posiva Methodology

  • Received : 2020.08.19
  • Accepted : 2020.11.09
  • Published : 2020.11.30

Abstract

In this paper, an approach developed by the Finnish nuclear waste management organization, Posiva, for the construction license of a geological repository was reviewed. Furthermore, a computer program based on the approach was developed. By using the computer program, the lifetime of a copper disposal canister, which was a key engineered barrier of the geological repository, was predicted under the KAERI Underground Research Tunnel (KURT) geologic conditions. The computer program was developed considering the mass transport of corroding agents, such as oxygen and sulfide, through the buffer and backfill. Shortly after the closure of the repository, the corrosion depths of a copper canister due to oxygen in the pores of the buffer and backfill were calculated. Additionally, the long-term corrosion of a copper canister due to sulfide was analyzed in two cases: intact buffer and eroded buffer. Under various conditions of the engineered barrier, the corrosion lifetimes of the copper canister due to sulfide significantly exceeded one million years. Finally, this study shows that it is necessary to carefully characterize the transmissivity of rock and sulfide concentration during site characterization to accurately predict the canister lifetime.

Keywords

References

  1. Svensk Karnbranslehantering AB. Long-term safety for the final repository for spent nuclear fuel at Forsmark, SKB Technical Report, SKB-TR-11-01 (2011).
  2. Posiva Oy. Safety Case for the Disposal of Spent Nuclear Fuel at Olkiluoto, POSIVA Oy Report, Posiva 2012-04 (2012).
  3. Agence nationale pour la gestion des dechets radioactifs. Evaluation of the feasibility of a geological repository in an argillaceous formation, ANDRA, Chatenay-Malabry (2005).
  4. Nuclear Waste Management Organization of Japan. Development of Repository Concepts for Volunteer Siting Environment, NWMO Report, NUMO-TR-04-03 (2004).
  5. J.Y. Lee, D. Cho, H. Choi, and J. Choi, "Concept of a Korean Reference Disposal System for Spent Fuels", J. Nucl. Sci. Technol., 44(12), 1565-1573 (2007). https://doi.org/10.3327/jnst.44.1565
  6. H.-J. Choi, J.Y. Lee, and J. Choi, "Development of geological disposal systems for spent nuclear fuels and high-level radioactive waste in Korea", Nucl. Eng. Technol., 45(1), 29-40 (2013). https://doi.org/10.5516/NET.06.2012.006
  7. J. Lee, I. Kim, H. Choi, and D. Cho, "An Improved Concept of Deep Geological Disposal System Considering Arising Characteristics of Spent Fuels from Domestic Nuclear Power Plants", J. Nucl. Fuel Cycle Waste Technol., 17(4), 405-418 (2019). https://doi.org/10.7733/jnfcwt.2019.17.4.405
  8. J. Smith, Z. Qin, D. W. Shoesmith, F. King, and L. Werme, "Corrosion of Copper Nuclear Waste Containers In Aqueous Sulphide Solutions", Mater. Res. Soc. Symp. Proc., 824, CC1.12.1 (2004).
  9. F. King, M. Kolar, and P. Maak, "Reactive-transport model for the prediction of the uniform corrosion behavior of copper used fuel container", J. Nucl. Mater., 379(1-3), 133-141 (2008). https://doi.org/10.1016/j.jnucmat.2008.06.017
  10. F. King, M. Kolar, M. Vahanen, and C. Lilja, "Modelling long term corrosion behavior of copper canister in KBS-3 repository", Corros. Eng. Sci. Technol., 46(2), 217-222 (2011). https://doi.org/10.1179/18211Y.0000000004
  11. Svensk Karnbranslehantering AB. Corrosion calculations report for the safety assessment SR-Site, SKB Technical Report, SKB-TR-10-66 (2010).
  12. F. King. Theory Manual for the Copper Corrosion Model for Uniform Corrosion in Sedimentary Rock CCM-UC.1.1, Nuclear Waste Management Organization Report, NWMO-TR-2008-07 (2008).
  13. M. Yoo, H.-J. Choi, M.-S. Lee, and S.-Y. Lee, "Measurement of Properties of Domestic Bentonite for a Buffer of an HLW Repository", J. Nucl. Fuel Cycle Waste Technol., 14(2), 135-147 (2016). https://doi.org/10.7733/JNFCWT.2016.14.2.135
  14. H.-J. Choi, J.-Y. Lee, S. Kim, and J.H. Cha. Development of a Computer Program (CAVE) for the Analysis of an Excavation Volume of an Underground Disposal System, Korea Atomic Energy Research Institute Report, KAERI/TR-3433/2007 (2007).
  15. F. King. Mixed-Potential Modelling of the Corrosion of Copper in the Presence of Sulphide, POSIVA Oy Working Report 2007-63 (2008).
  16. J. Smith, Z. Qin, F. King, L. Werme, and D.W. Shoesmith, "Sulphide Film Formation on Copper Under Electrochemical and Natural Corrosion Conditions", Corrosion, 63(2), 135-144 (2007). https://doi.org/10.5006/1.3278338
  17. P. Smith, L. Johnson, M. Snellman, B. Pastina, and P. Gribi. Safety Assessment for a KBS-3H Spent Nuclear Fuel Repository at Olkiluoto, Posiva Oy Report, POSIVA 2007-08 (2007).
  18. I. Neretnieks, L. Liu, and L. Moreno. Mass transfer between waste canister and water seeping in rock fracture, Svensk Karnbranslehantering AB Technical Report, SKB-TR-10-42 (2010).