DOI QR코드

DOI QR Code

다황화암모늄에 의해 제조된 황화니켈을 이용한 리튬전지의 전기 화학적 특성 평가

Electrochemical Properties of Lithium Batteries with Nickel Sulfide by Ammonium Polysulfide

  • 유호석 (경운대학교 항공신소재공학과)
  • RYU, HO SUK (Deptmemt Advanced Aerospace Materials Engineering, Kyungwoon University)
  • 투고 : 2021.11.08
  • 심사 : 2021.12.20
  • 발행 : 2021.12.30

초록

In the case of a metal sulfide electrode, it is used as an anode or cathode active material in a lithium battery. The reason is that the voltage exists between 0.8 and 2.0 V via lithium electrode and the discharge and charge capacity is high. In order to manufacture nickel sulfide for electrode, which are widely used, nano-nickel powder was sulfided using ammonium polysulfide, and single-phase NiS electrodes were manufactured through heat treatment. The prepared NiS electrode had a high initial capacity of 500 mAh/g or more, and was stabilized after 20 cycles to maintain a capacity of 400 mAh/g or more until 100 cycles.

키워드

과제정보

이 연구는 2021년도 경운대학교 교내학술연구비 지원으로 연구되었습니다.

참고문헌

  1. K. S. Lee, S. T. Myung, K. Amine, H. Yashiro, and Y. K. Sun, "Structural and electrochemical properties of layered Li [Ni1-2xCoxMnx] O2 (x = 0.1-0.3) positive electrode materials for Li-Ion batteries", J. Electrochem. Soc., Vol. 154, No. 10, 2007, pp. A971-A977. Retrieved from https://iopscience.iop.org/article/10.1149/1.2769831.
  2. K. Zhang, F. Chen, H. Pan, L. Wang, D. Wang, Y. Jiang, L. Wang, and Y. Qian, "Study on the effect of transition metal sulfide in lithium-sulfur battery", Inorg. Chem. Front., Vol. 6, No. 2, 2019, pp. 477-481, doi: https://doi.org/10.1039/C8QI01193A.
  3. J. Z. Wang, S. L. Chou, S. Y. Chew, J. Z. Sun, M. Forsyth, D. R. MacFarlane, and H. K. Liu, "Nickel sulfide cathode in combination with an ionic liquid-based electrolyte for rechargeable lithium batteries", Solid State Ionics, Vol. 179, No. 40, 2008, pp 2379-2382, doi: https://doi.org/10.1016/j.ssi.2008.09.007.
  4. S. C. Han, H. S. Kim, M. S. Song, P. S. Lee, J. Y. Lee, and H. J. Ahn, "Electrochemical properties of NiS as a cathode material for rechargeable lithium batteries prepared by mechanical alloying", J. Alloys and Comp., Vol. 349, No.1-2, 2003, pp. 290-296, doi: https://doi.org/10.1016/S0925-8388(02)00882-4.
  5. S. C. Han, H. S. Kim, M. S. Song, J. H. Kim, H. J. Ahn, and J. Y Lee, "Nickel sulfide synthesized by ball milling as an attractive cathode material for rechargeable lithium batteries", J. Alloys and Comp., Vol. 351, No. 1-2, 2003, pp. 273-278, doi: https://doi.org/10.1016/S0925-8388(02)01037-X.
  6. S. C. Han, H. S. Kim, M. S. Song, J. H. Kim, H. J. Ahn, and J. Y Lee, "Charge-discharge mechanism of mechanically alloyed NiS used as a cathode in rechargeable lithium batteries", J Alloys and Comp., Vol. 361, No. 1-2, 2003, pp. 247-251, doi: https://doi.org/6. https://doi.org/10.1016/S0925-8388(03)00380-3
  7. N. Mahmood, C. Zhang, and Y. Hou, "Nickel sulfide/nitrogen-doped graphene composites: phase-controlled synthesis and high performance anode materials for lithium ion batteries" Small, Vol. 9, No. 8, 2013, pp. 1321-1328, doi: https://doi.org/10.1002/smll.201203032.
  8. D. Mondal, G. Villemure, and C. Song, "Synthesis, characterization, and evaluation of unsupported porous NiS sub-micrometer spheres as a cathode material for lithium batteries", J. Applied Electrochem., Vol. 44, 2014, pp. 599-606, doi: https://doi.org/10.1007/s10800-014-0658-2.
  9. T. S. Sonia, P. Anjali, S. Roshny, V. Lakshmi, R. Ranjusha, K. R. V. Subramanian, S. V. Nair, and A. Balakrishnan, "Nano/micro-hybrid NiS cathodes for lithium ion batteries", Ceramics International, Vol. 40, No. 6, 2014, pp. 8351-8356, doi: https://doi.org/10.1016/j.ceramint.2014.01.041.
  10. S. Ni, X. Yang, and T, Li, "Fabrication of a porous NiS/Ni nanostructured electrode via a dry thermal sulfuration method and its application in a lithium ion battery", J. Mater. Chem., Vol. 22, No. 6, 2012, pp. 2395-2397, doi: https://doi.org/10.1039/C2JM15394G.
  11. G. B. Cho, S. M. Park, S. S. Jeong, K. W. Kim, and T. H. Nam, "Structural and electrochemical properties of thermal sulfurized Ni-Ti alloy for the integration electrode", Materials Letters, Vol. 60, No, 5, 2006, pp. 643-645, doi: https://doi.org/10.1016/j.matlet.2005.09.051.
  12. N. H. Idris, M. M. Rahman, S. L. Chou, J. Z. Wang, D. Wexler, and H. K. Liu, "Rapid synthesis of binary α-NiS-β-NiS by microwave autoclave for rechargeable lithium batteries", Electrochimica Acta, Vol. 8, 2011, pp. 456-462, doi: https://doi.org/10.1016/j.electacta.2011.09.066.