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Investigation of Transparent Electrodes for Solution-Processed Organic Solar Cells

용액법 기반의 유기태양전지 제작을 위한 투명전극 개발

  • Lee, Sumin (School of Electronics Engineering, Chungbuk National University) ;
  • Kang, Moon Hee (School of Electronics Engineering, Chungbuk National University)
  • Received : 2021.01.15
  • Accepted : 2021.01.25
  • Published : 2021.03.01

Abstract

In this study, composite transparent electrodes were fabricated either from a conductive polymer poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) or silver nanowire (AgNW). Three transparent electrodes such as PEDOT:PSS, PEDOT:PSS and AgNW mixture, and AgNW were fabricated. As for a transparent electrode, measured sheet resistance values were 89.6, 60.6 and 28.6 Ω/sq, and the transmittance values were 80.2, 82.0 and 83.8% while surface roughness (Rq) values were 4.1, 8.1, 20.4 nm for PEDOT:PSS, PEDOT:PSS and AgNW mixture, and AgNW, respectively. To verify the overall performance of these composite electrodes, we applied these electrodes to the top electrode of the solution-processed organic solar cells (OSCs). PEDOT:PSS provided the best performance with a fill factor (FF) of 51.2% and a photoconversion efficiency (PCE) of 2.2%, while traditional metal top electrode OSC provided FF of 60.5% and PCE of 3.1%.

Keywords

References

  1. Z. Hu, J. Zhang, and Y. Zhu, Renewable Energy, 62, 100 (2014). [DOI: https://doi.org/10.1016/j.renene.2013.06.042]
  2. K. L. Woon, W. S. Wong, N. Chanlek, H. Nakajima, S. Tunmee, V. S. Lee, A. Ariffin, and P. Songsiriritthigul, RSC Adv., 10, 17673 (2020). [DOI: https://doi.org/10.1039/D0RA02575E]
  3. J. Ouyang and Y. Yang, Adv. Mater., 18, 2141 (2006). [DOI: https://doi.org/10.1002/adma.200502475]
  4. J. Ouyang, Q. Xu, C. W. Chu, Y. Yang, G. Li, and J. Shinar, Polymer, 45, 8443 (2004). [DOI: https://doi.org/10.1016/j.polymer.2004.10.001]
  5. Y. K. Seo, C. W. Joo, J. Lee, J. W. Han, D. J. Lee, S.A.N. Entifar, S. Kim, N. S. Cho, and Y. H. Kim, J. Lumin., 187, 221 (2017). [DOI: https://doi.org/10.1016/j.jlumin.2017.03.002]
  6. L. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, and J. R. Reynolds, Adv. Mater., 12, 481 (2000). [DOI: https://doi.org/10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO;2-C]
  7. D. Alemu, H. Y. Wei, K. C. Ho, and C. W. Chu, Energy Environ. Sci., 5, 9662 (2012). [DOI: https://doi.org/10.1039/C2EE22595F]
  8. H. Shi, C. Liu, Q. Jiang, and J. Xu, Adv. Electron. Mater., 1, 1500017 (2015). [DOI: https://doi.org/10.1002/aelm.201500017]
  9. F. Guo, X. Zhu, K. Forberich, J. Krantz, T. Stubhan, M. Salinas, M. Halik, S. Spallek, B. Butz, E. Spiecker, T. Ameri, N. Li, P. Kubis, D. M. Guldi, G. J. Matt, and C. J. Brabec, Adv. Energy Mater., 3, 1062 (2013). [DOI: https://doi.org/10.1002/aenm.201300100]
  10. J. H. Yim, S. Y. Joe, C. Pang, K. M. Lee, H. Jeong, J. Y. Park, Y. H. Ahn, J. C. de Mello, and S. Lee, ACS Nano, 8, 2857 (2014). [DOI: https://doi.org/10.1021/nn406672n]
  11. S. Pang, Y. Hernandez, X. Feng, and K. Mullen, Adv. Mater., 23, 2779 (2011). [DOI: https://doi.org/10.1002/adma.201100304]
  12. J. Zou, H. L. Yip, S. K. Hau, and A.K.Y. Jen, Appl. Phys. Lett., 96, 203301 (2010). [DOI: https://doi.org/10.1063/1.3394679]
  13. H. Kim, A. Pique, J. S. Horwitz, H. Mattoussi, H. Murata, Z. H. Kafafi, and D. B. Chrisey, Appl. Phys. Lett., 74, 3444 (1999). [DOI: https://doi.org/10.1063/1.124122]
  14. H. Kim, C. M. Gilmore, A. Pique, J. S. Horwitz, H. Mattoussi, H. Murata, Z. H. Kafafi, and D. B. Chrisey, J. Appl. Phys., 86, 6451 (1999). [DOI: https://doi.org/10.1063/1.371708]
  15. C. Y. Li, T. C. Wen, T. H. Lee, T. F. Guo, J.C.A. Huang, Y. C. Lin, and Y. J. Hsu, J. Mater. Chem., 19, 1643 (2009). [DOI: https://doi.org/10.1039/B815523B]
  16. H. L. Yip and A.K.Y. Jen, Energy Environ. Sci., 5, 5994 (2012). [DOI: https://doi.org/10.1039/C2EE02806A]
  17. F. C. Krebs, Sol. Energy Mater. Sol. Cells, 93, 394 (2009). [DOI: https://doi.org/10.1016/j.solmat.2008.10.004]
  18. D. H. Kim, D. J. Lee, B. Kim, C. Yun, and M. H. Kang, Solid-State Electron., 169, 107808 (2020). [DOI: https://doi.org/10.1016/j.sse.2020.107808]
  19. L. Yang, T. Zhang, H. Zhou, S. C. Price, B. J. W iley, and W. You, ACS Appl. Mater. Interfaces, 3, 4075 (2011). [DOI: https://doi.org/10.1021/am2009585]