Korean Journal of Environmental Agriculture (한국환경농학회지)

The Korean Society of Environmental Agriculture (한국환경농학회)
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Characteristics and Mechanisms of Phosphate Sorption by Calcined Oyster Shell

소성 굴패각에 의한 인산염의 흡착특성 및 메커니즘

  • Park, Jong-Hwan (Department of Applied Life Chemistry (Institute of Agriculture and Life Science), College of Agriculture and Life Science, Gyeongsang National Universty) ;
  • Heo, Jae-Young (Environmental Agriculture Research Division, Gyeongsangnam-do Agricultural Research and Extension Service) ;
  • Lee, Su-Lim (Department of Applied Life Chemistry (Institute of Agriculture and Life Science), College of Agriculture and Life Science, Gyeongsang National Universty) ;
  • Lee, Jae-Hoon (Department of Applied Life Chemistry (Institute of Agriculture and Life Science), College of Agriculture and Life Science, Gyeongsang National Universty) ;
  • Hwang, Se-Wook (Department of Applied Life Chemistry (Institute of Agriculture and Life Science), College of Agriculture and Life Science, Gyeongsang National Universty) ;
  • Cho, Hyeon-Ji (Environmental Agriculture Research Division, Gyeongsangnam-do Agricultural Research and Extension Service) ;
  • Kwon, Jin-Hyeuk (Environmental Agriculture Research Division, Gyeongsangnam-do Agricultural Research and Extension Service) ;
  • Chang, Young-Ho (Research and Development Bureau, Gyeongsangnam-do Agricultural Research and Extension Service) ;
  • Seo, Dong-Cheol (Department of Applied Life Chemistry (Institute of Agriculture and Life Science), College of Agriculture and Life Science, Gyeongsang National Universty)
  • 박종환 (경상국립대학교 농업생명과학대학 환경생명화학과 (농업생명과학연구원)) ;
  • 허재영 (경남농업기술원 환경농업연구과) ;
  • 이수림 (경상국립대학교 농업생명과학대학 환경생명화학과 (농업생명과학연구원)) ;
  • 이재훈 (경상국립대학교 농업생명과학대학 환경생명화학과 (농업생명과학연구원)) ;
  • 황세욱 (경상국립대학교 농업생명과학대학 환경생명화학과 (농업생명과학연구원)) ;
  • 조현지 (경남농업기술원 환경농업연구과) ;
  • 권진혁 (경남농업기술원 환경농업연구과) ;
  • 장영호 (경남농업기술원 연구개발국) ;
  • 서동철 (경상국립대학교 농업생명과학대학 환경생명화학과 (농업생명과학연구원))
  • Received : 2021.03.03
  • Accepted : 2021.03.18
  • Published : 2021.03.31
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Abstract

BACKGROUND: Although the calcined oyster shell can be used as a calcium-rich adsorbent for phosphate removal, information about it is limited. The purpose of this study was to evaluate the phosphate adsorption characteristics and its mechanism using calcined oyster shells. METHODS AND RESULTS: In this study, calcined oyster shell (C-OS600) was prepared by calcining oyster shells (P-OS) at 600℃ for 20 min. Phosphate adsorption by C-OS600 was performed under various environmental conditions. Phosphate adsorption by C-OS600 occurred rapidly at the beginning of the reaction, and the time to reach equilibrium was less than 1 h. The optimal isotherm and kinetic models for predicting the adsorption of phosphate by C-OS600 were the Langmuir isotherm and pseudo-second order kinetic model, respectively, and the maximum adsorption capacity derived from the Langmuir isotherm was 68.0 mg/g. The adsorption properties of phosphate by C-OS600 were dominantly influenced by the initial pH and C-OS600 dose. In addition, SEM-EDS and FTIR analysis clearly showed a difference in C-OS600 before and after phosphate adsorption, which proved that phosphate was adsorbed on the surface of C-OS600. CONCLUSION: Overall, the calcined oyster shell can be considered as an useful and effective adsorbent to treat wastewater containing phosphate.

Keywords

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