Journal of Electrochemical Science and Technology

  • 제12권3호
  • /
  • Pages.365-376
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  • 2021
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  • 2093-8551(pISSN)
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  • 2288-9221(eISSN)
한국전기화학회 (The Korean Electrochemical Society)
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Arylamino Substituted Mercaptoimidazole Derivatives as New Corrosion Inhibitors for Carbon Steel in Acidic Media: Experimental and Computational Study

  • Duran, Berrin (Eskisehir Osmangazi University, Faculty of Science and Letters, Department of Chemistry) ;
  • Yurttas, Leyla (Anadolu University, Faculty of Pharmacy, Department of Pharmaceutical Chemistry) ;
  • Duran, Murat (Eskisehir Osmangazi University, Faculty of Science and Letters, Department of Chemistry)
  • 투고 : 2021.01.14
  • 심사 : 2021.03.08
  • 발행 : 2021.08.28
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초록

Two arylamino substituted mercaptoimidazole derivatives namely 4,5-dimethyl-1-(phenylamino)-1H-imidazole-2(3H)-thione (I1) and 4,5- dimethyl-1-((p-chlorophenyl)amino)- 1H-imidazole-2(3H)-thione (I2) were synthesized and investigated as corrosion inhibitors for carbon steel in 0.5 M HCl solution by means of electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, ATR-FTIR spectroscopy and SEM. The results showed that the investigated mercaptoimidazole derivatives act as mixed type inhibitors and inhibition efficiency follows the I2>I1 order. Adsorption of inhibitors on metal surface was found to obey the Langmuir adsorption isotherm. Thermodynamic parameters revealed that adsorption of the inhibitors has both physisorption and chemisorption adsorption mechanism. Electrochemical test results were supported by quantum chemical parameters obtained from DFT calculations.

키워드

과제정보

The authors are grateful to Eskisehir Osmangazi University (ESOGU) for financial support. This work was supported by the Commission of Scientific Research Projects of ESOGU (Grant Number: 201819068).

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