Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
권호 표지
DOI QR코드

DOI QR Code

A Study on the Aggregation properties of Sodium hyaluronate with Alkanediyl-bis(dimethylalkylammonium bromide) surfactants in aqueous solution

수용액에서 Sodium hyaluronate와 Alkanediyl-bis(dimethylalkylammonium bromide) 계면활성제의 회합성질에 관한 연구

  • Ahn, Beom-Shu (Division of Life Science & Chemistry, Daejin University)
  • 안범수 (대진대학교 과학기술대학 생명화학부)
  • Received : 2021.07.28
  • Accepted : 2021.08.25
  • Published : 2021.08.31
Download PDF
⟨ Previous Next ⟩

Abstract

A study on the associative properties of sodium hyaluronate (NaHA) and Alkane-bis (dimethylalkylammonium bromide) surfactants in aqueous solution was investigated in relation to the chemical structure of surfactants. As a result of measuring the interfacial tension, a parabolic graph showing the minimum value (cmin) at a specific concentration was shown. Above this minimum concentration the increase in interfacial tension is thought to be related to the formation of aggregates of NaHA chains and dimeric surfactants. The plot of viscosity vs surfactant concentration shows a slight maxium at cmin and a viscosity decrease at high surfactant concentrations. Viscosity nonlinear behavior is related to the size increase due to the complex growth and to the size shrinkage following from the interaction with electrolyte ions and free micelles. The results of surface tension measurements show a broad region of surface tension decrease, indicating the NaHA-surfactant interaction. The increase in surface tension above cmin may be related to the adsorption of clusters, consisting of free NaHA chains and dimeric surfactant. The strong adsorption of surfactant is observed at high concentrations.

수용액에서 Sodium hyaluronate(NaHA)와 Alkanediyl-bis(dimethylalkylammonium bromide) 계면활성제의 회합성질에 관한 연구를 계면활성제의 화학적 구조와 관련하여 조사하였다. 계면장력을 측정한 결과 특정 농도에서 최소값(Cmin)을 나타내는 포물선 모양의 그래프를 보여주었다. 이 최소 농도 이상에서 계면장력의 증가는 공기와 물의 접촉면에서 NaHA사슬과 이합체 계면활성제들로 이루어진 집합체의 형성과 관계있다고 생각된다. NaHA와 계면활성제의 착물결합체에서 하나의 NaHA 음전하에 대한 계면활성제의 양전하 비율을 보면 약간 양전하가 우세하나, 전체적으로 전하의 균형은 크게 벗어나지 않았다. NaHA/이합체 계면활성제의 착물결합체에서 계면활성제 농도와 점성도의 관계가 비 선형성을 나타내는 것은 계면활성제의 화학적 구조와 관계되기 때문이다. 이 비 선형성은 착물체의 성장에 따른 크기 증가와 Cmin 농도 이상에서의 수축 현상과 밀접하게 관련된다고 볼 수 있다.

Keywords

Acknowledgement

본 논문은 2021학년도 대진대학교 학술연구비 지원에 의한 것임.

References

  1. J. Penfold, I. Tucker, R. Thomas, and R. Schuermann, "Structure of mixed anionic/nonanionic surfactants micelles", Journal of Physics Chemistry B. Vol.109, pp. 10760-10770, (2005). https://doi.org/10.1021/jp050727f
  2. A, Dar, G. M. Rather, and A. R. Das, "Mixed micelle formation and solubilization brhavior toward polycyclic hydrocabons binry and ternary cationic surfactants", Journal of Physics Chemistry B. Vol.111, pp. 3122-3135, (2007). https://doi.org/10.1021/jp066926w
  3. C, S. Kweon, D. W. Kim, and S. T. Noh, "Synthesis and physical properties of oligopropylene oxide allyl methyl ether", Journal of Indian Engineering Chemistry Vol.9, No.2, pp. 146-152, (2003).
  4. Z. Peng, Q. Wu, T. Cai, and K. Chen, "Synthesis and properties of hydrolysis resistant trioxane surfactants", Colloids and Surfaces A, Vol.342, pp. 127-131, (2009). https://doi.org/10.1016/j.colsurfa.2009.04.028
  5. A. K. Sood and K. Singh, "Micellization behavior of the gemini surfactants with some conventional syrfactants at different temperatures", Journal of Surfactant & Detergent, Vol.14, pp. 235-244, (2011). https://doi.org/10.1007/s11743-010-1217-4
  6. S. Gerber, V. M. Garamus, and V. Vill, "Mixed micelles formed by a polaamphile with carbohhydrate headgroups", Langmuir, Vol.21, pp. 6707-6711, (2005). https://doi.org/10.1021/la050439a
  7. H. Salminen, S. Aulbach, and C. Tedeshe, "Influence of surfactant composition on physical and oxidative stability of lipid particles", Colloids & Surfactants B Biointerface, Vol.122, No.1, pp. 46-55, (2014). https://doi.org/10.1016/j.colsurfb.2014.06.045
  8. M. J. Rang, "Trend on development and application of polymeric surfactants", Journal of Korean Oil Chemistry Society, Vol.30, No.3, pp. 546-567, (2015). https://doi.org/10.12925/jkocs.2015.32.3.546
  9. N. M. Lee, B. H. Lee, "Mixed micellization TTAB with with other surfactants", Journal of Korean Chemistry Society, Vol.56, No.5, pp. 556-562 (2012). https://doi.org/10.5012/jkcs.2012.56.5.556
  10. C. Wang, W. Ou, Q. Gao, and Q. Li, "Adsorption and aggreation behavior tetrasiloxane tailed suffactants containig methyl ester", Journal of Physics Chemistry, B. Vol. 115, pp. 3811-3815, (2011). https://doi.org/10.1021/jp110578u
  11. S. J. Kim, Y. L. Jeong, J. J. Nam, and J. B. Lee, "A study of stabilization for insoluble active ingredients using swollen micelles", Journal of Cosmetic Science Korea, Vol. 42, No.1, pp. 9-13, (2016). https://doi.org/10.15230/SCSK.2016.42.1.9
  12. P. Scajev, S. Miasojedovas and S. Jursenus, "A carrier density dependent diffusion coefficient, recombivnation rate and diffusion length", Journal of Material Chemistry C, Vol.8, pp. 1029-1038, (2020).
  13. M. Kim, "A study of emulsion fuel of cellulosic biomass oil", Journal of Korean Oil Chemistry Society, Vol.33, No.4, pp. 836-847, (2016). https://doi.org/10.12925/jkocs.2016.33.4.836
  14. J. Kim and H. Kim, "Emulsion viscosity with oil polarity and interpretation by organic concetual diagram", Journal of Korean Oil Chemistry Society, Vol.31, No.4, pp. 623-627, (2014). https://doi.org/10.12925/jkocs.2014.31.4.623
  15. M. Manick, G. Farid, and M. Kruk, "Swollen mixed pluonic surfactant micelles as templates for mesoporous nanotubes with diverse framework", Journal of Colloid and Interface Society, Vol.524, pp. 445-455 (2018). https://doi.org/10.1016/j.jcis.2018.04.011
  16. J. S. Park and J. C. Lim, "Investigation on a Zwitterionic surfactant having ethylene oxide", Appllied Chemistry Engineering, Vol.110, No.2, pp. 605-608, (2006).
  17. S. Tian, J. Guo, X. Len, and S. Gao, "Synthesis, characterization, and exploatory application of anionic surfactant fatty acid methyl ester", Journal of Surfactants & Detergents, Vol.19, pp. 467-475, (2016). https://doi.org/10.1007/s11743-016-1813-z
  18. D. W. Kim, C. H. Lim, and S. T. Noh, "Surface active properties and LCST behaviour of ol;igo propylene oxide sufactants in aqueous solutions", Bulletin of Korean Chemistry Society, Vol. 25, No.8, 1182-1188, (2004). https://doi.org/10.5012/bkcs.2004.25.8.1182
  19. C. Zhang, Y. Jiang, H. LUI, and Y. Wang, "Synergetic effect of binary mixtures contained newly cationic surfactants", Journal of Molecular Liquid, Vol.232, pp. 36-44, (2017). https://doi.org/10.1016/j.molliq.2017.02.055
  20. W. Wang, Z. Du, Q. Cao, and L. Wang, "Properties and glucosamide based tetrasiloxsane surfactants", Journal of Dispergent Science & Technology, Vol.33, 654-659, (2012). https://doi.org/10.1080/01932691.2011.579824
  21. S. Lee, B. J. Kim, J. G. Lee, and J. C. Lim, "Synthesis and characterization of interfacial properties of sorbitan laurate surfactant", Appllied Chemistry Enginering, Vol.22, No.1, pp 37-44, (2011).
  22. X. Zeng, J. Xu, and LWang, "Synthesis and propertied of new triceplic tetrasiloxane surfactants containing hydrocabon chain", Journal of Dispergent Science & Technology, Vol.37, pp. 846-853, (2016). https://doi.org/10.1080/01932691.2015.1065505