DOI QR코드

DOI QR Code

Effect of Inorganic Nanocomposite Based Liners on Deodorization of Kimchi

  • Chung, Kwon (Department of Biotechnology, College of Life Sciences and Biotechnology, Korea University) ;
  • Park, Hyun Jin (Department of Biotechnology, College of Life Sciences and Biotechnology, Korea University) ;
  • Shin, Yang Jai (Department of Biotechnology, College of Life Sciences and Biotechnology, Korea University)
  • Received : 2021.07.26
  • Accepted : 2021.08.04
  • Published : 2021.08.31

Abstract

This study aims to reduce the rancid odor generated during the fermentation process of kimchi by inserting zinc oxide (ZnO) into an inorganic porous material with a high surface area to decompose or adsorb the fermentation odor. ZnO activated by the presence of moisture exhibits decomposition of rancid odors. Mixed with Titanium dioxide (TiO2), a photocatalyst. To manufacture the packaging liner used in this study, NaOH, ZnCl2, and TiO2 powder were placed in a tank with diatomite and water. The sludge obtained via a hydrothermal ultrasonication synthesis was sintered in an oven. After being pin-milled and melt-blended, the powders were mixed with linear low-density polyethylene (L-LDPE) to make a masterbatch (M/B), which was further used to manufacture liners. A gas detector (GasTiger 2000) was used to investigate the total amount of sulfur compounds during fermentation and determine the reduction rate of the odor-causing compounds. The packaging liner cross-section and surface were investigated using a scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDS) to observe the adsorption of sulfur compounds. A variety of sulfur compounds associated with the perceived unpleasant odor of kimchi were analyzed using gas chromatography-mass spectrometry (GC-MS). For the analyses, kimchi was homogenized at room temperature and divided into several sample dishes. The performance of the liner was evaluated by comparing the total area of the GC-MS signals of major off-flavor sulfur compounds during the five days of fermentation at 20℃. As a result, Nano-grade inorganic compound liners reduced the sulfur content by 67 % on average, compared to ordinary polyethylene (PE) foam liners. Afterwards SEM-EDS was used to analyze the sulfur content adsorbed by the liners. The findings of this study strongly suggest that decomposition and adsorption of the odor-generating compounds occur more effectively in the newly-developed inorganic nanocomposite liners.

Keywords

References

  1. Hawer, W. D. (1994). Study of changes in flavor components in Chinese cabbage Kimchi during fermentation. In: Science of Kimchi. Abstract of symposium of Korean Society of Food Science and Technology, Seoul:175-190
  2. Block, E., Naganathan, S., Putman, D., & Zhao, S. H. (1992). Allium chemistry: HPLC analysis of thiosulfinates from onion, garlic, wild garlic (ramsoms), leek, scallion, shallot, elephant (great-headed) garlic, chive, and Chinese chive. Uniquely high allyl to methyl ratios in some garlic samples. Journal of Agricultural and Food Chemistry, 40(12):2418-2430. https://doi.org/10.1021/jf00024a017
  3. Yu, T. H., Wu, C. M., & Ho, C. T. (1993). Volatile compounds of deep-oil fried, microwave-heated and oven-baked garlic slices. Journal of Agricultural and Food Chemistry, 41(5): 800-805 https://doi.org/10.1021/jf00029a023
  4. Choi, Y. J., Yong, S., Lee, M. J., Park, S. J., Yun, Y. R., Park, S. H., & Lee, M. A. (2019). Changes in volatile and non-volatile compounds of model Kimchi through fermentation by lactic acid bacteria. LWT - Food Science and Technology, 105:118-126. https://doi.org/10.1016/j.lwt.2019.02.001
  5. Ha, J. H. (2002). Analysis of volatile organic compounds in Kimchi adsorbed in SPME by GC-AED and GC-MSD. Journal of the Korean Society of Food Science and Nutrition, 31(3):543-545. https://doi.org/10.3746/jkfn.2002.31.3.543
  6. Hong, E. J., Kim, Y. J., & Noh, B. S. (2010). The reduction of "off-flavor" in Cheonggukjang and Kimchi. Korean Journal of Food Culture, 25(3):324-333
  7. Jeong, H. S., & Ko, Y. T. (2010). Major odor components of raw Kimchi materials and changes in odor components and sensory properties of Kimchi during ripening. Korean Journal of Food Culture, 25(5):607-614
  8. Jeong, S., and Yoo, S. (2016). Deodorizing effects of natural deodorants on the kimchi smells. Korean Society of Food Science and Nutrition, 2016 KFN International Symposium and Annual Meeting:366-366.
  9. Lee, J., Jo, Y., Kporwodu, F., Coralia, V. G., Kim, J. T. (2016). Characterization of Metal Oxide Nanoparticles in Applied Food Packaging Materials. Korean Society of Food Science and Nutrition, 2016 KFN International Symposium and Annual Meeting:366-366.
  10. Lee, W., & Ko, S. (2018). A Study on the Functionality and Stability of LDPE-Nano ZnO Composite Film. Korean Journal of Packaging Science and Technology, 24(1):27-34. https://doi.org/10.20909/kopast.2018.24.1.27
  11. Galikhanov, M. F., Guzhova, A. A., Efremova, A. A., & Nazmieva, A. I. (2015). Effect of aluminum oxide coating on structural, barrier and electret properties of polyethylene terephthalate films. IEEE Transactions on Dielectrics and Electrical Insulation, 22(3):1492-1496. https://doi.org/10.1109/TDEI.2015.7116342
  12. Hirvikorpi, T., Vaha-Nissi, M., Mustonen, T., Iiskola, E., & Karppinen, M. (2010). Atomic layer deposited aluminum oxide barrier coatings for packaging materials. Thin Solid Films, 518(10):2654-2658. https://doi.org/10.1016/j.tsf.2009.08.025
  13. Wang, L., Wang, Z., Yang, H., & Yang, G. (1999). The study of thermal stability of the SiO2 powders with high specific surface area. Materials Chemistry and Physics, 57(3):260-263. https://doi.org/10.1016/S0254-0584(98)00226-0
  14. Kim, S. H., Jeong, S. G., Na, S. E., Kim, S. Y., & Ju, C. S. (2013). Preparation of TiO2 powder by hydrothermal precipitation method and their photocatalytic properties. Korean Chemical Engineering Research, 51(2):195-202. https://doi.org/10.9713/kcer.2013.51.2.195
  15. Baek, S. Y., Lim, S. Y., Lee, D. H., Min, K. H., & Kim, C. M. (2000). Incidence and characterization of Listeria monocytogenes from domestic and imported foods in Korea. Journal of Food Protection, 63(2):186-189. https://doi.org/10.4315/0362-028X-63.2.186
  16. Mheen, T. I., & Kwon, T. W. (1984). Effect of temperature and salt concentration on Kimchi fermentation. Korean Journal of Food Science Technology, 16(4):443-450
  17. Hong, S. P., Lee, E. J., Kim, Y. H., & Ahn, D. U. (2016). Effect of fermentation temperature on the volatile composition of Kimchi. Journal of Food Science, 81(11):C2623-C2629. https://doi.org/10.1111/1750-3841.13517
  18. Lee, H. J., Joo, Y. J., Park, C. S., & Lee, J. S. (1999). Fermentation patterns of green onion Kimchi and Chinese cabbage Kimchi. Korean Journal of Food Science Technology, 31(2): 488-494
  19. Nishikawa, H., & Takahara, Y. (2001). Adsorption and photocatalytic decomposition of odor compounds containing sulfur using TiO2/SiO2 bead. Journal of Molecular Catalysis A: Chemical, 172(1-2):247-251. https://doi.org/10.1016/S1381-1169(01)00124-8
  20. Wu, C. M., Baltrusaitis, J., Gillan, E. G., & Grassian V. H. (2011). Sulfur dioxide adsorption on ZnO nanoparticles and nanorods. The Journal of Physical Chemistry, 115(20):10164-10172. https://doi.org/10.1021/jp201986j
  21. Bonne, M., Pronier, S., Can, F., Courtois, X., Valange, S., Tatibouet, J. M., Royer, S., Marecot, P., & Duprez, D. (2010). Synthesis and characterization of high surface area TiO2-SiO2 mesostructured nanocomposite. Solid State Sciences, 12(6):1002-1012. https://doi.org/10.1016/j.solidstatesciences.2009.10.009