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Zeolite Based Pervaporation Membrane: A Review

제올라이트 기반 투과증발 분리막: 총설

  • JooYeop, Lee (Nano Science and Engineering, Underwood International College, Yonsei University) ;
  • Rajkumar, Patel (Energy and Environmental Science and Engineering, Integrated Science and Engineering Division, Underwood International College, Yonsei University)
  • 이주엽 (연세대학교 언더우드학부 융합과학공학부 나노과학공학) ;
  • 라즈쿠마 파텔 (연세대학교 언더우드학부 융합과학공학부 에너지환경융합전공)
  • Received : 2022.11.11
  • Accepted : 2022.12.09
  • Published : 2022.12.31

Abstract

Membrane separation process is an important technique utilized for various applications. This separation process proceeds due to a driving force such as concentration gradient, pressure or electrical potential gradient etc. Pervaporation is one of the separation process based on solution-diffusion mechanism. The pressure of the permeate side is reduced by creating vacuum and separation is driven due to pressure difference. Purity of the fuel or chemical like ethanol or isopropyl alcohol are improved by dehydration process through porous zeolite membrane. These membranes have high thermal, chemical, mechanical stability. This review is classified mainly into two different sections: Ethanol and bio-oil dehydration by zeolite membrane.

막 분리 공정은 다양한 응용 분야에서 사용되는 중요한 기술이다. 이러한 분리 공정은 농도 구배, 압력 또는 전위구배 등의 구동력에 의해 수행된다. 투과증발은 용액 메커니즘에 기초한 분리 과정 중 하나이다. 분리막을 투과한 쪽에서 압력은 진공에 의해 감소되고 분리는 압력차에 의해 구동된다. 다공성 제올라이트 분리막을 통한 탈수 공정에 의해 에탄올 또는 이소프로필 알코올과 같은 연료 및 화학 물질의 순도를 향상시킨다. 이러한 분리막들은 높은 열적, 화학적, 기계적 안정성을 가지고 있다. 이 총설에서는 제올라이트 분리막에 의한 에탄올 회수 및 바이오 오일 탈수라는 두 개의 섹션으로 나누어 소개한다.

Keywords

References

  1. B-J. Yoon, Y-M Kim, D-H. Lee, and C-H. Cho, "Improvement of pervaporative water flux of mordenite zeolite membrane by controlling membrane thickness", Membr. J., 29, 263 (2019).
  2. X. Ren, S. Yang, R. Xu, M. Guo, W. Huang, M. Ding, and J. Zhong, "Mono- and di-valent ion exchange of mordenite membranes for dehydration of acetic acid by pervaporation", J. Membr. Sci., 643, 119998 (2022).
  3. S. M. Sharafi, S. M. Moghimi, M. J. Vaezi, and A. A. Babaluo, "Synthesis a low template B-ZSM-5 membrane with suitable morphology and high performance for the separation of acetone/water mixtures", J. Environ. Chem. Eng., 10, 107079 (2022).
  4. J. Wang, L. Wang, L. Li, J. Li, W. raza, J. Lu, and J. Yang, "A green synthesis of MOR zeolite membranes by wet gel conversion for dehydration of water-acetic acid mixtures", Sep. Purif. Technol., 286, 120311 (2022).
  5. L. Wang, J. Yang, W. Raza, J. Wang, J. Lu, Y. Zhang, and G. He, "Sustainable fabrication of large-scale tubular LTA zeolite membranes by a simple wet gel conversion", Microporous Mesoporous Mater., 329, 111541 (2022).
  6. Y. F. Lin, Z. M. Zhan, Z. L. Xu, Z. R. Shi, X. Zhang, S. J. Xu, and K. K. Zhu, "SUZ-4 zeolite membrane fabricated by dynamic hydrothermal crystallization for pervaporation separation of MeOH/MMA mixture", J. Membr. Sci., 642, 119974 (2022).
  7. X. Ren, H. Yu, M. Guo, R. Xu, and J. Zhong, "Long alkyl chain-containing organosilica/silicalite-1 composite membranes for alcohol recovery", Micropor. Mesopor. Mater., 338, 111947 (2022).
  8. H. Saulat, J. Yang, S. Wensen, W. Raza, and G. He, "Fabrication of isomorphously substituted W-MFI membrane with high performance for ethanol separation from water:, Chem. Asian J., 17, e202101404 (2022).
  9. S. Senol, B. Kaya, I. Salt, B. Tirnakci, and Y. Salt, "Pervaporation separation of ethylacetate-ethanol mixtures using zeolite 13X-filled poly(dimethylsiloxane) membrane:, Chem. Eng. Commun., 209, 1048 (2022).
  10. S. M. Woo, Y. H. Park, and S. Y. Nam, "Pervaporation performance of submerged type membrane for the separation of water from aqueous isopropanol solution", Membr. J., 28, 279 (2018).
  11. L. Vane, F. Alvarez, V. Namboodiri, and M. Abar, "Ethanol dehydration performance of three types of commercial-grade zeolite permselective membranes", J. Chem. Technol. Biotechnol., 97, 1966 (2022).
  12. X. Wu, Z. Yan, Y. Li, B. Zhu, T. Gui, Y. Li, M. Zhu, F. Zhang, X. Chen, and H. Kita, "Fabrication of low cost and high performance NaA zeolite membranes on 100-cm-long coarse macroporous supports for pervaporation dehydration of dimethoxymethane", Sep. Purif. Technol., 281, 119822 (2022).
  13. Z. Yan, X. Wu, B. Zhu, Y. Li, T. Gui, Y. Li, M. Zhu, X. Chen, and H. Kita, "Improvement of esterification conversion by rapid pervaporation dehydration using a high-flux and acid-resistant MOR zeolite membrane", Sep. Purif. Technol., 286, 120415 (2022).
  14. M. Azarshab, F. Mohammadi, H. Maghsoodloorad, and T. Mohammadi, "Ceramic membrane synthesis based on alkali activated blast furnace slag for separation of water from ethanol", Ceram Int., 42, 15568 (2016).
  15. Y. Cao, M. Wang, Z. L. Xu, X. H. Ma, and S. M. Xue, "A novel seeding method of interfacial polymerization-assisted dip coating for the preparation of zeolite NaA membranes on ceramic hollow fiber supports", ACS Appl. Mater. Interfaces, 8, 26386 (2016).
  16. D. Liu, Y. Zhang, J. Jiang, X. Wang, C. Zhang, and X. Gu, "High-performance NaA zeolite membranes supported on four-channel ceramic hollow fibers for ethanol dehydration", RSC Adv., 5, 95866 (2015).
  17. G. Liu, F. Xiangli, W. Wei, S. Liu, and W. Jin, "Improved performance of PDMS/ceramic composite pervaporation membranes by ZSM-5 homogeneously dispersed in PDMS via a surface graft/coating approach", Chem. Eng. J., 174, 495 (2011).
  18. V. Sebastian, R. Mallada, J. Coronas, A. Julbe, R. A. Terpstra, and R. W. J. Dirrix, "Microwave-assisted hydrothermal rapid synthesis of capillary MFI-type zeolite-ceramic membranes for pervaporation application", J. Membr. Sci., 355, 28 (2010).
  19. W. Yuan, H. Chen, R. Chang, and L. Li, "Synthesis and characterization of high performance NaA zeolite-polyimide composite membranes on a ceramic hollow fiber by dip-coating deposition", Desalination, 273, 343 (2011).
  20. J. Kittikarnchanaporn and S. Jitkarnka, "Characteristics of catalysts for enhanced green production of distillates and chemicals in bio-oil from catalytic dehydration of bio-ethanol", Clean Technol. Environ. Policy, 17, 1127 (2015).
  21. G. Li, S. Ma, F. Ye, Y. Luo, S. Fan, X. Lang, Y. Wang, and L. Zhou, "Permeation characteristics of a T-type zeolite membrane for bio-oil pervaporation dehydration", Microporous Mesoporous Mater., 315, 110884 (2021).
  22. G. Li, S. Ma, F. Ye, L. Zhou, Y. Wang, X. Lang, and S. Fan, "Robust ZSM-5 membranes for efficient bio-oil dehydration: Transport mechanism and its implication on structural tuning", Ind. Eng. Chem. Res., 60, 1799 (2021).
  23. A. V. Klinov, R. R. Akberov, A. R. Fazlyev, and M. I. Farakhov, "Experimental investigation and modeling through using the solution-diffusion concept of pervaporation dehydration of ethanol and isopropanol by ceramic membranes HybSi", J. Membr. Sci., 524, 321 (2017).
  24. E. Lv, T. Dou, S. Ding, J. Lu, Z. Li, W. Yi, J. Li, and J. Ding, "Membrane dehydration-enhanced esterification for biodiesel production from a potential feedstock of Firmiana platanifolia L.f. seed oil", Chem. Eng. Res. Des., 153, 1 (2020)