Journal of Electrochemical Science and Technology

  • 제13권3호
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  • Pages.369-376
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  • 2022
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  • 2093-8551(pISSN)
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  • 2288-9221(eISSN)
한국전기화학회 (The Korean Electrochemical Society)
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Stability Tests on Anion Exchange Membrane Water Electrolyzer under On-Off Cycling with Continuous Solution Feeding

  • Niaz, Atif Khan (School of Materials Science and Engineering, Changwon National University) ;
  • Lim, Hyung-Tae (School of Materials Science and Engineering, Changwon National University)
  • 투고 : 2022.03.25
  • 심사 : 2022.05.05
  • 발행 : 2022.08.28
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초록

In this study, the stability of an anion exchange membrane water electrolyzer (AEMWE) cell was evaluated in an on-off cycling operation with respect to an applied electric bias, i.e., a current density of 500 mA cm-2, and an open circuit. The ohmic and polarization resistances of the system were monitored during operation (~800 h) using electrochemical impedance spectra. Specific consideration was given to the ohmic resistance of the cell, especially that of the membrane under on-off cycling conditions, by consistently feeding the cell with KOH solution. Owing to an excess feed solution, a momentary increase in the polarization resistance was observed immediately after the open-circuit. The excess feed solution was mostly recovered by subjecting the cell to the applied electric bias. Stability tests on the AEMWE cell under on-off cycling with continuous feeding even under an open circuit can guarantee long-term stability by avoiding an irreversible increase in ohmic and polarization resistances.

키워드

과제정보

This research was supported by Changwon National University in 2021-2022.

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