DOI QR코드

DOI QR Code

Physicochemical characteristics of carotenoid-enriched extract prepared from persimmon peels by ultrasound-assisted extraction with soybean oil solvent

초음파와 대두유 용매를 이용한 감 껍질 추출물의 이화학적 특성

  • Hun Sik Chung (Department of Food Science and Technology, Pusan National University) ;
  • Kwang Sup Youn (Department of Food Science and Technology, Catholic University of Daegu) ;
  • Soo Won Lee (Department of Food and Food Service Industry, Kyungpook National University) ;
  • Hey Kyung Moon (Center for Scientific Instruments, Kyungpook National University) ;
  • Jong Kuk Kim (Department of Food and Food Service Industry, Kyungpook National University)
  • 정헌식 (부산대학교 식품공학과) ;
  • 윤광섭 (대구가톨릭대학교 식품공학과) ;
  • 이수원 (경북대학교 식품외식산업학과) ;
  • 문혜경 (경북대학교 공동실험실습관) ;
  • 김종국 (경북대학교 식품외식산업학과)
  • Received : 2022.10.21
  • Accepted : 2023.02.03
  • Published : 2023.02.28

Abstract

Persimmon peels are mostly discared as a by-product of dried persimmon manufacturing, but effective use is required as it contains various functional constituents. This study covers the preparation of carotenoid-enriched oil by ultrasound treatment of persimmon peel in soybean oil solvent, and the investigation of its physicochemical characteristics. Using the Box-Behnken design and response surface methodology, the optimal extraction conditions (temperature, 62℃; time, 32 min; and persimmon peel to oil ratio, 1:3.1) were determined based on the carotenoid concentration of the extract. The physicochemical characteristics of the extract obtained under optimal conditions and the untreated soybean oil (control) were compared. The total carotenoid content of the extract increased. The carotenoid-enriched soybean oils had a lighter color than the controls, but with high redness and yellowness values. The effect of sonication and a component of the persimmon peel on the oxidation and heating stability of soybean oil was weak. The viscosity and activation energy of carotenoid-enriched soybean oil were slightly higher than those of the control. Thus, it was possible to prepare yellow-red carotenoid-enriched soybean oil by applying ultrasonic-soybean oil solvent extraction to persimmon peel. The oil is expected to be useful as an additive as well as a substitute for general edible oils.

초음파와 대두유 용매를 병용하여 감 껍질 유래 카로티노이드 함유 대두유를 제조하고 그의 이화학적 특성을 파악하기 위하여, Box-Behnken design과 반응표면분석법을 이용하여 추출물의 카로티노이드 농도 기준 최적 추출조건(온도 62℃, 시간 32 min, 대두유/감 껍질 비율 3.1)을 결정하였고, 이 조건에서 얻은 추출물(카로티노이드 강화 대두유)과 무처리 대두유(control)의 이화학적 특성을 비교하였다. 추출물의 총카로티노이드 함량은 강화되었고, 이러한 카로티노이드 강화 대두유의 색도는 대조구보다 명도는 낮았지만 높은 적색도와 황색도값을 보였다. 대두유의 산화 및 가열 안정성에 대한 초음파 처리와 감 껍질 유래 카로티노이드의 영향은 미미한 것으로 나타났다. 카로티노이드 강화 대두유의 점도와 활성화 에너지는 대조구보다 약간 높았다. 이로써 감 껍질에 초음파-대두유 용매 추출법을 적용하여 황적색의 카로티노이드 강화 대두유의 제조가 가능하였고, 이는 일반 유지 대체제는 물론 첨가물로서도 활용성이 높을 것으로 기대된다.

Keywords

References

  1. Box GEP, Behnken DW. Some new three level designs for the study of quantitative variables. Technometrics, 2, 455-475 (1960) https://doi.org/10.1080/00401706.1960.10489912
  2. Chang YK, Lee JW, Kim TJ. A study on quality changes of domestic frying oils by thermal oxidation. Korean J Food Sci Technol, 10, 112-118 (1978)
  3. Chemat F, Vian MA, Cravotto G. Green extraction of natural products: Concept and principles. Int J Mol Sci, 13, 8615-8627 (2012) https://doi.org/10.3390/ijms13078615
  4. Cho E, Seddon JM, Rosner B, Willett WC, Hankinson SE. Prospective study of intake of fruits, vegetables, vitamins, and carotenoids and risk of age-related maculopathy. Arch Ophthalmol, 122, 883-892 (2004) https://doi.org/10.1001/archopht.122.6.883
  5. Chung HS, Cho JS, Kim HS, Kim DS, Lee YG, Seong JH, Moon DK. Quality characteristics of coffee beverage processed by ultrasound-assisted extraction. Korean J Food Preserv, 23, 660-665 (2016) https://doi.org/10.11002/kjfp.2016.23.5.660
  6. Fasina OO, Colley Z. Viscosity and specific heat of vegetable oils as a function of temperature: 35℃ to 180℃. Int J Food Prop, 11, 738-746 (2008) https://doi.org/10.1080/10942910701586273
  7. Hong JH, Shin MK, Choi YH. Optimization for extraction condition of β-carotene from persimmon peel by microwave-assisted extraction. Food Eng Prog, 6, 308-313 (2002)
  8. Karabagias I, Michos C, Badeka A, Kontakos S, Stratis I, Kontominas MG Classification of Western Greek virgin olive oils according to geographical origin based on chromatographic, spectroscopic, conventional and chemometric analyses. Food Res Int, 54, 1950-1958 (2013) https://doi.org/10.1016/j.foodres.2013.09.023
  9. Kim SK, Lim JH, Kim YC, Kim MY, Lee BW, Chung SK. Chemical composition and quality of persimmon peels according to cultivars. J Korean Soc Appl Biol Chem, 48, 70-76 (2005)
  10. Kim YC, Kim JB, Cho KJ, Lee IS, Chung SK. Carotenoid content of Korean persimmon peel and their changes in storage. Food Sci Biotechnol, 11, 477-479 (2002)
  11. Korea Food and Drug Administration. Korean Food Standards Codex. Korea Food and Drug Administration, Cheongju, Korea (2013)
  12. Korean Statistical Information Service. Available from: http://kosis.kr/index/index.do. Accessed Oct. 10, 2022.
  13. Lee JM, Chang PS, Lee JH. Comparison of oxidative stability for the thermally-oxidized vegetable oils using a DPPH method. Korean J Food Sci Technol, 39, 133-137 (2007)
  14. Li Y, Fabiano-Tixier AS, Tomao V, Cravotto G, Chemat F. Green ultrasound-assisted extraction of carotenoids based on the bio-refinery concept using sunflower oil as an alternative solvent. Ultrason Sonochem, 20, 12-18 (2013) https://doi.org/10.1016/j.ultsonch.2012.07.005
  15. Mudahar GS, Toledo RT, Floros JD, Jen JJ. Optimization of carrot dehydration process using response surface methodology. Journal of Food Science, 54, 714-719 (1989)
  16. Nour V, Corbu AR, Rotaru P, Karageorgou I, Lalas S. Effect of carotenoids, extracted from dry tomato waste, on the stability and characteristics of various vegetable oils. Grasas Aceites, 69, e238 (2018)
  17. Oh SL, Cha WS, Park JH, Cho YJ, Hong JH, Lee WY. Carotenoids pigment extraction from a wasted persimmon peel. Korean J Postharvest Sci Technol, 8, 456-461 (2001)
  18. Pradal D, Vauchel P, Decossin S, Dhulster P, Dimitrov K. Kinetics of ultrasound-assisted extraction of antioxidant polyphenols from food by-products: Extraction and energy consumption optimization. Ultrason Sonochem, 32, 137-146 (2016) https://doi.org/10.1016/j.ultsonch.2016.03.001
  19. Sachindra NM, Mahendrakar NS. Process optimization for extraction of carotenoids from shrimp waste with vegetable oils. Bioresour Technol, 96, 1195-1200 (2005) https://doi.org/10.1016/j.biortech.2004.09.018
  20. Takahashi M, Watanabe H, Kikkawa J, Ota M, Watanabe M, Sato Y, Inomata H, Sato N. Carotenoids extraction from Japanese persimmon (Hachiyakaki) peels by supercritical CO2 with ethanol. Anal Sci, 22, 1441-1447 (2006) https://doi.org/10.2116/analsci.22.1441