한국전기전자재료학회논문지 (Journal of the Korean Institute of Electrical and Electronic Material Engineers)

  • 제36권2호
  • /
  • Pages.175-185
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  • 2023
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  • 1226-7945(pISSN)
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  • 2288-3258(eISSN)
한국전기전자재료학회 (The Korean Institute of Electrical and Electronic Material Engineers)
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Self-Supporting 3D-Graphene/MnO2 Composite Supercapacitors with High Stability

  • Zhaoyang Han (Department of System Semiconductor Engineering, Cheongju University) ;
  • Sang-Hee Son (Department of System Semiconductor Engineering, Cheongju University)
  • 투고 : 2022.11.24
  • 심사 : 2023.01.11
  • 발행 : 2023.03.01
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초록

A hybrid supercapacitor is a promising energy storage device in view of its excellent capacitive performance. Commercial three-dimensional foam nickel (Ni) can be used as an ideal framework due to an interconnected network structure. However, its application as an electrode material for supercapacitors is limited due to its low specific capacity. Herein, we report a successful growth of MnO2 on the surface of graphene by a one-step hydrothermal method; thus, forming a three-dimensional MnO2-graphene-Ni hybrid foam. Our results show that the mixed structure of MnO2 with nanoflowers and nanorods grown on the graphene/Ni foam as a hybrid electrode delivers the maximum specific capacitance of 193 F·g-1 at a current density 0.1 A·g-1. More importantly, the hybrid electrode retains 104% of its initial capacitance after 1,000 charge-discharge cycles at 1 A·g-1; thus, showing the potential application as a stable supercapacitor electrode.

키워드

과제정보

This paper was supported by Korea Institute for Advancement of Technology (KIAT) grant funded by the Korea Government (MOTIE) (P0017011, HRD Program for Industrial Innovation).

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