Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Portable Amperometric Glucose Detection based on NiS/CuS Nanorods Integrated with a Smartphone Device

  • Heyu Zhao (Wenzhou Institute of Hangzhou Dianzi University) ;
  • Kaige Qu (Wenzhou Institute of Hangzhou Dianzi University) ;
  • Haoyong Yin (Wenzhou Institute of Hangzhou Dianzi University) ;
  • Ling Wang (Department of Chemistry, Zhejiang Sci-Tech University) ;
  • Yifan Zheng (Research Center of Analysis and Measurement, Zhejiang University of Technology) ;
  • Shumin Zhao (Wenzhou Institute of Hangzhou Dianzi University) ;
  • Shengji Wu (College of Engineering, Huzhou University)
  • Received : 2023.02.03
  • Accepted : 2023.03.25
  • Published : 2023.08.31
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Abstract

Glucose detection is particularly important for clinical diagnosis and personal prevention and control. Herein, the smartphone-based amperometric glucose sensors were constructed using the NiS/CuS nanorods (NRs) as sensing electrodes. The NiS/CuS NRs were prepared through a facile hydrothermal process accompanied by the subsequent vulcanization treatment. The morphological and structural properties of NiS/CuS NRs were characterized with SEM, EDS, XRD, and XPS. Electrochemical measurements including cyclic voltammetry, chronoamperometry, and electrochemical impedance spectroscopy display that NiS/CuS NRs can act as highly efficient electrocatalyst for glucose detection. The NiS/CuS NRs electrodes present a wide detection range of 1-8000 µM for glucose sensing with the sensitivity of 956.38 µA·mM-1·cm-2. The detection limit was 0.35 µM (S/N=3). When employed in smartphone-based glucose sensing device, they also display a high sensitivity of 738.09 µA·mM-1·cm-2 and low detection limit of 1.67 µM. Moreover, the smartphone-based glucose sensing device also presents favorable feasibility in determination of glucose in serum samples with the recoveries ranging between 99.5 and 105.8%. The results may provide a promising viewpoint to design other new portable glucose sensors.

Keywords

Acknowledgement

This work is financially supported by National Nature Science Foundation of Zhejiang Province (No. Y19E060021).

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