Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Degradation Study of Lithium-Ion Batteries Using Lithium Plating/Stripping Model

리튬 플레이팅/스트리핑 모델을 이용한 리튬 이온 배터리의 열화 연구

  • Received : 2024.09.09
  • Accepted : 2024.10.07
  • Published : 2024.12.10
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Abstract

We predicted the degradation and long-term cycle life of lithium-ion batteries using an electrochemical-based lithium plating/stripping model. We did not consider the complex degradation mechanism of lithium-ion batteries; we only applied the lithium plating/stripping model to perform numerical analysis and calculated the capacity fade during cycling, loss of lithium inventory, and charge/discharge performance. The results showed that a higher capacity fade was observed at lower temperatures, higher C-rates, and higher lithium plating kinetic rates. In addition, the more aged cell tended to be the greater the initial voltage increase during charging, and the shorter the charging time in CC mode.

전기화학 기반의 리튬 플레이팅/스트리핑 모델을 이용하여 리튬이온 배터리의 열화 및 장기 수명을 예측하였다. 리튬 이온 배터리의 복잡한 열화 메커니즘은 고려하지 않았고, 리튬 플레이팅/스트리핑 모델만을 적용하여 수치해석이 이루어졌고, 사이클링 동안의 용량 감소, 리튬 재고 손실, 충방전 성능을 계산하였다. 수치해석 결과, 낮은 온도, 높은 C-rate, 그리고 리튬 플레이팅 운동 속도가 클 때 높은 용량 감소를 보였다. 또한, 열화가 많이 진행된 셀일수록 충전 시 초기 전압 상승폭이 크고, CC 모드에서의 충전시간이 짧아지는 경향을 보였다.

Keywords

Acknowledgement

본 연구는 2024년도 산업통산자원부의 재원으로 산업집적지경쟁력 강화사업(HUKB2305), 그리고 2024년 동국대학교 토대연구지원금 지원에 의하여 이루어졌음.

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