Soil and groundwater contamination by petroleum hydrocarbon products is only one of many environmental problems in Korea. However, many environmental consulting companies have been targeted their business on this subject because the petroleum-oil-lubricant (POL) products have been widely used product and accidental releases of the products from storages resulted numerous small and large contaminated sites throughout Korea. Therefore, many small and large companies are actively participating in environmental assessment and remediation projects for the POL contaminated sites. Remedial technologies for the POL contaminated sites have been developed for many years by government and private institutions throughout the world. Development of a new decontamination technology for the POL contaminated sites is no longer attractive issue in research community because scientific bases of most cost-effective remedial technologies are well understood and have been used in the field by commercial sector. Numerous sites contaminated by underground tanks at gas stations have been remediated by relatively small companies in this country. We should appreciate their noticeable contributions as a frontier under very difficult market environment in Korea. We heard many successful stories as well as a few failure stories. Soil-groundwater remediation of POL contaminated site is not a simple task as shown in the text books or protocols. Therefore, failure risk is always with us, which requires continuous efforts for improvement of the technologies by the users and developers. In this presentation, author will discuss technical problems encountered and improvement made during implementation of several remedial technologies applied by Samsung Environmental Team. This is not a presentation about research or case study. We want to share our thought and experience with environmental engineers actively engaged in soil and groundwater remediation projects in Korea.

This paper presents the results of laboratory investigation performed to study the role of different air sparging system parameters on the removal of benzene from saturated soils and groundwater. A series of one-dimensional experiments was conducted with predetermined contaminant concentrations and predetermined injected airflow rates and pressures to investigate the effect of soil type and the use of pulsed air injection on air sparging removal efficiency. On the basis of these studies, two-dimensional air sparging remediation systems were investigated to determine the effect of soil heterogeneity on the removal of benzene from three different homogeneous and heterogeneous soil profiles. This study demonstrated that the grain size of the soils affects the air sparging removal efficiency. Additionally, it was observed that pulsed air injection did not offer any appreciable enhancement to contaminant removal for the coarse sand; however, substantial reduction in system operating time was observed for fine sand. The 2-D experiments showed that air injected in coarse sand profiles traveled in channels within a parabolic zone. In well-graded sand the zone of influence was found to be wider due to high permeability and increased tortuosity of this soil type. The influence zone of heterogeneous soil (well-graded sand between coarse sand) showed the hybrid airflow patterns of the individual soil test. Overall, the mechanism of contaminant removal using air sparging from different soil conditions have been determined and discussed.

학회는 학술지식정보자원의 최신정보에 대한 접근 점이지만, 대규모 학회를 제외하고는 정보 수집과 서비스 면에서 재래식 방법을 벗어나지 못하고 있다. 더구나, 최근에는 각 학회 자체 업무 중 발생하는 회원관리, 논문투고, 심사와 같은 제반업무와, 발간되는 학술정보에 대한 정보화를 수행하고자 하는 학회의 열의가 급격히 증가하고 있는 추세이나, 학회의 재정상 적극적으로 이행하지 못하고 있는 실정이다. 이에 KISTI는 한국과학기술정보연구원은 국가차원의 학회 정보화 사업의 일환으로 학회정보 유통체제 전 과정을 온라인화하고 쉽게 관리할 수 있도록 한 $\boxDr$KISTI-ACOMS(KISTI-Article Contribution Management System: KISTI-학회논문투고관리시스템) $\boxDr$KISTI-ACOMS(KISTI-Article Contribution Management System)$\boxUl$ 을 개발하여 2001년부터 학회에 무상으로 보급하여 왔다. 최근에는 학회의 KISTI-ACOMS를 이용하고자 하는 요청이 더욱 확대되고 있어, KISTI는 많은 학회 특성을 의견수렴하여, KISTI-ACOMS의 표준화를 목표로 보완해 나가고 있다.

본 연구는 용도별 토양에 대찬 중금속 및 불소 농도 특성을 알아보기 위하여 비교적 오염 개연성이 구분될 것으로 판단되는 도로, 공장, 학교운동장, 적환장, 공원, 약수터 주변 등, 그동안 비교적 조사 자료가 부족하였던 토양을 대상으로 한강 남쪽에 위치한 11개 구청(양천구, 강서구, 구로구, 영등포구, 관악구, 동작구, 강남구, 강동구, 서초구)에서 6개의 용도별로 시료를 채취하여 pH, Cd, Cu, Pb, Hg, F 항목을 분석하였다. 조사 결과 용도별 토양의 pH는 4.7~9.5의 범위로 나타났으며, 중금속 및 불소 평균 농도는 Cd 0,391mg/kg, Cu 12.354mg/kg, Pb 13.04mg/kg, Hg 0.0866mg/kg, F 206.8mg/kg이었다. 용도별 토양에 대한 최대, 최저 농도는 Cd이 잡종지 0.632mg/kg, 학교용지 0.079mg/kg, Cu는 도로용지 21.354mg/kg, 학교용지 2.159mg/kg, Pb은 도로용지 24.70mg/kg, 학교용지 1.03mg/kg, Hg은 잡종지 0.1780mg/kg, 학교용지 0.0087mg/kg, F의 경우 임야 282.0mg/kg, 학교용지164.9mg/kg로 나타나서 전체적으로 Cd, Cu, Hg은 대부분 적환장으로 이용되고 있는 잡종지가, Pb은 도로용지에서 각각 높은 농도를 나타내었고, F는 임야 지역을 대상으로 한 토양에서 높은 농도를 보였다. 그러나 학교용지는 Cd, Cu Pb, Hg, F등에서 상대적으로 다른 용도별 토양보다 낮은 농도를 나타내었다.

The objective of this study is to investigate the vertical variation of heavy metals in tailings from the Sangdong W mine. Tailings samples were taken at 6 drilling sites with 50cm intervals up to 21meters in depth and dried at room temperature. The pH value, loss-on-ignition and water contents were measured. In addition, chemical compositions of the samples were determined by AAS after 0.1N HC1 leaching and ICP-AES after aqua regia leaching. The pH values were in the range of 7.2 to 8.5 due to chemical reactions of carbonate minerals. The ranges of heavy metals (mg/kg) extracted by 0.1N HC1 were from 0.17 to 0.93 for Cd, 0.04 to 4.39 for Cu, 0.03 to 10.9 for Pb and 0.06 to 14.1 for Zn and those extracted by aqua regia were 3.10~10.5, 23.61 ~251, 63.7~337 and 42.6~134 for Cd, Cu, Pb and Zn, respectively. Generally, the metal concentrations in tailings do not change with depth, with they have a tendency to decrease with depth in some case.

Fractional composition and mobility of sediments some heavy metals in Okdong stream are investigated. The fractional scheme for sediment heavy metal was made for five chemically defined heavy metal forms as adsorbed fraction, carbonate fraction, reducible fraction, organic fraction, and residual fraction (Tessier et at., 1979). The most abundant fraction of the sediment heavy metal is reducible and secondly abundant organic fraction. Adsorbed fraction is minor part of the total heavy metals. Mobilization of sediment heavy metals in stream Okdong is occur 19.8∼56.7% of total cadmium concentrate. The most abundant fraction of the sediment metal is organic fraction in Cu, Pb metals investigated. Labile fraction of sediment metals are 0.5%∼48.5% of total Zn, 2.6%∼48.1% of total Pb, 0.2∼36.9% of total Cu respectively, Most of labile fraction consists of reducible fraction for Cd, Zn, adsorbed fraction for Pb, reducible fraction for Cu, adsorbed fraction for Ni. The Mobilization of Zn and Cu is most likely to occur when oxygen depletes and that of Pb and Ni occurs when physical impact, oxygen depletion and pH reduction.

The purpose of the study is to compare the efficiency of protection as a liner protective material for geosynthetics. A series of tests were conducted in this study to analyze the effects of geosynthetics against puncture loads. Various types of geosynthetics are used as a protective material. Non-woven, Geo-composite, NaBento GCL, GCL are used to create puncture failure that caused by vertically applied loads. The results indicated that combination of geosynthetics and a protective material can be subjected to bigger loads than geosynthetics and a protective material separated each other do.

The purpose of this study is the development of hybrid horizontal electrokinetic(EK) remediation system on rifle range soil under unsaturated conditions. In order to remediate soil polluted by multi-species heavy metals, in pi]of scale, a series of EK remediation tests are carried out. PVC and PDB(Plastic Drain Board) electrode systems that connected with the power supply of constant voltage and vacuum pressure of 0.5kgf/$\textrm{cm}^2$ are installed, The test results showed that the pH distribution in the sample is below 8, which is maintained until the test is finished, because of the injection of flushing solution. The final concentration, which is normalized by initial concentration, is ranged about 50 to 90%.

Red mud is a waste material formed during the production of alumina when the bauxite ore is subjected to caustic leaching. It is a brick-red colored highly alkaline (pH 10-12) sludge containing mostly oxides of iron, aluminum, titanium, and silica. Red mud, due to its high aluminum, iron, and calcium contents, has been suggested as a cheap adsorbent for removal of toxic metals (e.g., As, Cr, Pb, Cd) as well as for water or wastewater treatment. The basic advantage of red mud is its versatility in application. This study was conducted to evaluate the effect of red mud on stabilization and fixation of heavy metals (such as Pb, Cu, C $r^{6+}$, Cd, Zn) contained in the Al-coating sludge and soil. The results showed that the concentration of heavy metals leached from the treated sludge and soil was low, meeting the regulatory permit level.

Development of hematite-coated sand was evaluated for the application of the PRB (permeable reactive barrier) in the arsenic-contaminated subsurface of the metal mining areas. The removal efficiency of As(III) and As(V), the effect of anion competition and the capability of arsenic removal in the flow system were investigated through the experiments of adsorption isotherm, arsenic removal kinetics against anion competition and column removal. Hematite-coated sand followed a linear adsorption isotherm with high adsorption capacity at low level concentrations of arsenic (< 1.0 mg/l). When As(III) and As(V) underwent adsorption reactions in the presence of anions (sulfate, nitrate and bicarbonate), sulfate caused strong inhibition of arsenic removal, and bicarbonate and nitrate caused weak inhibition due to specific and nonspecific adsorption onto hematite, respectively. In the column experiments, high content of hematite-coated sand enhance the arsenic removal, but the amount of the arsenic removal decreased due to the higher affinity of As(V) than As(III) and reduced adsorption kinetics in the flow system, Therefore, the amount of hematite-coated sand, the adsorption affinity of arsenic species and removal kinetics determined the removal efficiency of arsenic in the flow system. arsenic, hematite-coated sand, permeable reactive barrier, anion competition, adsorption.

Soil Aquifer Treatment (SAT) is a technique in which secondary- or tertiary-treated wastewater is infiltrated through unsaturated soil and stored in the saturated zone. In SAT, contaminants are removed by physical and biochemical reactions taking place in soils. In this study, a numerical model was developed to predict changes in water quality during SAT operations. The contaminant species considered in the model were ammonium, nitrate, dissolved organic carbon, and dissolved oxygen. The model was calibrated against experimental data obtained from one dimensional soil column tests conducted for 84 days. The calibrated model will be used to find out optimum conditions for the pilot- and regional-scale SAT operations to be scheduled for the next phase of this project.

This research examines the feasibility of using laboratory-synthesized nano scale zero-valent iron particles to remove arsenic from aqueous phase. Batch experiments were performed to determine arsenic sorption rates as a function of the nano scale zero-valent iron solution concentration. Rapid adsorption of arsenic was achieved with the nano scale zero-valent iron. Typically 1 mg $L^{-1}$ arsenic (III) was adsorbed by 5 g $L^{-1}$ nano scale zero-valent iron below the 0.01 g $L^{-1}$ concentration within 7min. The kinetics of the arsenic sorption followed pseudo-first-order reaction kinetics. Observed reaction rate constants ( $K_{obs}$) varied between 11.4 to 129.0 $h^{-1}$ with respect to different concentrations of nano scale zero-valent iron. A variety of analytical techniques were used to study the reaction products including HGAAS (hydride generator atomic adsorption spectrophotometer), SEM (scanning electron microscopy) and TEM (transmission electron microscopy). Our experimental results suggest novel method for efficient removal of arsenic Iron groundwater.r.

A field pilot-scale demonstration of an enhanced SVE using hot air injection and extraction was conducted to remove diesel range compounds from subsurface soils at a site in J-city, Korea. The objective of demonstration was to evaluate field ISR by intrinsic microorganism after an application study of hot air-SVE technology and to calculate each first-order kinetic with soil temperature. TPH concentration of contaminated soil at the site was approximately 2, 000~11, 000 mg/kg (average 6, 900 mg/kg) with depths greater than 5 m bgs. The 1st-order reaction rate constants, k were 0.0438(@about5$0^{\circ}C$), 0.0564(@4$0^{\circ}C$), and 0.0685(@33$^{\circ}C$) d-1 respectively.

Waste lime is produced as by-products in chemical industry, Reuse of waste lime mixed with soil for banking and backfill material in civil works was analysed in this study. For this purpose, environmental effect of waste lime admixtures was tested. Thus, this study presents the leaching characterization of waste lime in laboratory batch and column tests. Countermeasure for reduction of environmental effects was suggested from the test results.

Unsaturated hydraulic conductivity models have been widely used for the numerical modeling of water flow and contaminant transport in soils. In this study, a simple hydraulic conductivity model is developed by using information of particle-size distribution from the lognormal distribution model and its results are compared with those from the Kosugi-Mualem (KM) model. The accuracy of the proposed model is verified for observed data chosen from the international UNSODA database. Results showed that the proposed model produces adequate predictions of hydraulic conductivities. Performance of this model is generally better than the KM function.

The uptake of $^{14}C$-2, 4, 6-trinitrotoluene (TNT) in hydroponics was studied using onion plants. Of the total TNT mass (5 $\mu\textrm{M}$ concentration), 75% was in the roots, 4.4% in the leaves, and 21% in the external solution at 2 days, The percent distribution in roots was lower with higher concentration in the external solution, but in leaves it was comparable at all concentrations (5-500 $\mu\textrm{M}$). Root concentration factor (RCF) in hydroponics was more than 85 in constant hydroponic experiment (CHE) at 5 $\mu\textrm{M}$ and 150 in non-constant hydroponic experiment (NHE) at 5 $\mu\textrm{M}$. The maximum RCF values in the hydroponic system were greater with lower solution concentration. Transpiration stream concentration factor (TSCF) values in the present study (NHE only: 0.31-0.56) were relatively similar to the values with predicted values (0.43-0.78), increasing with higher external TNT concentration. For phytotoxicity tested in hydroponics and wet paper method, 500 $\mu\textrm{M}$ was toxic to onion plant, 50 $\mu\textrm{M}$ was non-toxic for plant growth but limited the transpiration rate, and 5 $\mu\textrm{M}$ was non-toxic as control.

Estuary of Nakdong river area is composed of unconsolidated sediments including clays that are deposited varying from 40 to 70m thick. The purpose of research is the knowledge of the correlation between engineering properties and mineralogy of clay sediments. The correlation analysis carry out multiple regression that have independent variables (Engineering properties) and dependent variables (mineralogy, geochemistry). Engineering properties of clay are correlated with the mineral compositions and geochemical characteristics. The result of the analysis is Wn=-0.6 Feldspar ＋ 1.1 pH ＋ 0.01 TDS ＋ 27.5, Ip=0.36 Clay ＋ 1.44 Vermiculite ＋ 0.94 clay mineral-22.88, P$_{L}$=0.005 TDS - 0.31 Feldspar ＋ 22.43, e$_{o}$=0.02 Vermiculite - 0.01 Quartz ＋ TDS ＋ 0.93, E$_{50}$=1.94 Vermiculite-0.96 Kaolinite -0.53 silt ＋ 49.64, SR=-0.25 Kaolinite ＋ 1.5 pH - 2.3 Conductivity, CC = 0.03 pH ＋ TDS - 0.2, LL = 0.5 Clay ＋ 1.3 Vermiculite ＋ 5.5 Conductivity ＋ 0.8 Caly mineral-20.4.4.4.4

쓰레기매립장의 침출수 누출 탐지를 위한 물리탐사법은 침출수의 전기전도도를 대상으로 한 전기탐사법이 주로 적용되어 왔다. 이 연구는 제주도에 위치한 비위생매립지를 대상으로 주변 수리지질환경 파악을 위한 전기비저항 탐사와 더불어 매립장 경계부와 토양층을 통한 침출수 누출 영역을 효율적으로 규명하기 위하여 다중주파수를 이용한 소형루프 전자탐사를 병행하여 수행하였으며, 아울러 오염지역의 천부 지하수 유동 방향을 추정하기 위하여 침출수의 유동에 의해 발생될 수 있는 자연전위를 모니터링 하였다. 전기비저항 탐사 및 자연전위 모니터링 결과 매립지 주변을 통한 침출수의 누출 가능성은 거의 없는 것으로 나타났으며, 이는 주변 하천에서 정기적으로 실시한 수질 분석 결과와 일치된다. 또한 소형루프 전자탐사 자료에 대하여 공간 필터링 및 1차원 역산법을 적용한 결과 매립장 경계부의 위치 및 매립장 내부의 심도별 매립물에 의한 저비저항 이상대를 효과적으로 도출 할 수 있었다.

본 연구는 전기비저항 탐사법을 이용한 실내실험의 결과를 활용하여 토양의 수리특성별 지층비저항계수를 산출하여 소유역에 대하여 대략적인 수리지질 특성을 규명하는 방안을 제시하는 것이다. 연구결과, 모래로 구성된 토양층의 경우는 본 실내시험에서 얻어진 지층비저항계수에 따른 공극율 및 수리전도도의 관계를 활용할 수 있으며, 점토가 포함된 토양층의 경우는 표면전도도의 영향으로 측정되는 전기비저항이 실제 측정값보다 낮게 나타나므로 향후 전기이중층 효과를 고려하여 개발하는 경험식의 활용이 가능할 것으로 판단된다.

Changes in pyrene partitioning due to mineral surface adsorptive fractionation processes of humic substances (HS) were examined in model environmental systems. For purified Aldrich humic acid(PAHA), carbon-normalized pyrene binding coefficients ( $K_{oc}$ ) for the residual (i.e., nonadsorbed and dissolved) PAHA components were different from the original dissolved PAHA $K_{oc}$ , value prior to contact with mineral suspensions. A positive correlation between the extent of pyrene binding and weight-average molecular weight (M $W_{w}$) of residual PAHA components was observed, which appeared to be unaffected by the specific mineral adsorbents use and fractionation mechanisms. A similar positive correlation was not observed with the adsorbed PAHA components, suggesting that conformational changes occurred for the mineral-associated components upon adsorption. Nonlinear pyrene sorption to mineral-associated PAHA was observed, and the degree of nonlinearity is hypothesized to be dependent on adsorptive fractionation effects and/or structural rearrangement of the adsorbed PAHA components.s.

To clarify the effect of soil property on the EK-Fenton remediation of the soil contaminated with phenanthrene, this research had been conducted. In the experiments using EPK kaolinite, the $H_2O$$_2$ stability and effect of phenanthrene treatment improved more than that in the experiments using Hadong clayey soil. The results signify that Fe oxide content and acid buffer capacity significantly affected the fate of $H_2O$$_2$ and phenanthrene during the EK-Fenton process.

Solution chemistry, sorbate chemistry, and sorbent chemistry were widely investigated to find important factors that affect PAH sorption on mineral surfaces and to elucidate its microscopic mechanism. The solution chemistry, pH and ionic strength caused measurable change of HOC sorption reaction to minerals. The detectable change of Ka occurred at a pH region crossing the PZC (Point of Zero Charge) of each mineral. The PAH hydrophobicity, one of sorbate chemistry, was observed to have a strong correlation with PAM sorption to mineral. Mineral surface area was not found to be a predominant factor controlling PAH sorption. The mineral type might be more likely to play a crucial role in controlling the PAH sorption behavior. The CEC (Cation Exchange Capacity) of mineral, representing surface charge density, has meaningful correlation with regression slope of sorption coefficients (log $K_{d}$) versus aqueous activity coefficients (log Υ$_{w}$).).).

The combined effect of bioaugmentation of dechlorinating bacterial cultures and addition of iron powder (Fe$^{0}$ ) on reductive dechlorination of tetrachloroethylene (PCE) and other chlorinated ethylenes in a artificially contaminated soil slurry (60$\mu$mo1es PCE/kg soil) were tested. Two different anaerobic bacterial cultures, a pure bacterial culture of Desulfitobacterium sp. strain Y-51 capable of dechlorinating PCE to cis-1, 2-dechloroethylene (cis-DCE) and the other enrichment culture PE-1 capable of dechlorinating PCE completely to ethylene, were used for the bioaugmentation test. Both treatments introduced with the strain Y-51 and PE-1 culture (3mg dry cell weight/kg soil) showed conversion of PCE to cis-DCE within 40 days. The treatments added with Fe$^{0}$ (0.1 -1.0 %(w/w)) alone to the soil slurry resulted in extended PCE dechlorination to ethylene and ethane and the, dechlorination rate depended on the amount of Fe$^{0}$ added. The combined use of the bacterial cultures with Fe$^{0}$ (0.1-1.0%) showed the higher PCE dechlorination rate than the separated application and the pattern of PCE dechlorination and end-product formation was different from those of the separated application. These results suggested that the combined application of Fe$^{0}$ and the bactrial culture, specially the complete dechlorinating enrichment culture such as PE-1 culture, would be practically effective for remediation of PCE contaminated soil.

Air permeabilities in unsaturated fractured tuff at the Apache Leap Research Site (ALRS) near Superior, Arizona, exhibit a self-affine behavior, thus renders a field random fractal. Based up fractal scaling, the observed scale effect has been interpreted [Hyun et al., 2002]. Recently, Frantziskonis and Hansen [2000] presented that fractal scaling can be represented based on wavelets. This study deals with the way of using wavelets for fractal scaling. A numerical study is presented to examine the applicability of wavelet-based approach to determining upscaled air permeability values on various data supports at the site. To characterize the scaling property of self-affine fields generated based upon wavelets, Hurst coefficient, H. was inferred by applying the average wavelet coefficient (AWC) method. The result yielded H = 0.24, which is very close to the result of geostatistical analysis using a power variogram (H = 0.22). The study concludes that wavelet-based scaling is a useful way of determining parameter values on different data supports, which is an essential task for modeling of subsurface flow and mass transport in a numeric grid with different resolutions (grid size).

In this study, the mass transfer behaviors of phenanthrene, anthracene, and pyrene in soil slurry reactor (SSR) using two-liquid phase (TLP) system were investigated. The mass transfer ratio and rate of PAH in the TLP system using light paraffine oil, which has the highest solubility of PAH, were influenced by the amount of light paraffine oil and mixing speed. When the amount of light paraffine oil decreased from 15 % to 2.5 % (v/v), the mass transfer ratio of anthracene decreased significantly compared with that of phenanthrene and pyrene. As mixing speed increased, the initial mass transfer rate of PAH within 1 day was enhanced. However, each final mass transfer ratio of three PAHs after 5 day was similar irrespective of mixing speed.

Soil washing was applied as a supplementary step of soil remediation at a petroleum oil contaminated site. A soil washing system was designed, assembled, and operated at the site. A field screening method with PetroFlagTM was adopted at the site to find the exact boundary of contaminated area as soil excavation progressed and to verify the concentration of treated soil. The system operation showed the cleanup efficiency of 90% at the compatible cost compared to other methods.

Diesel-contaminated soils were ozonated for different times (0 - 900 min) and incubated for 9 wk to monitor petroleum hydrocarbons (PH)-degradative potential of indigenous microorganisms in the soils. Increased ozonation time decreased not only concentration of PH but also number of microorganisms in the soils. Microorganisms in the ozonated soils increased during 9-wk incubation as monitored by culture- and nonculture-based methods. Higher (1-2 orders of magnitude) cell number was observed by quantitative analysis of soil DNA using probes detecting genes encoding 165 rRNA(rrn), naphthalene dioxygenase (nahA), toluene dioxygenase (todC), and alkane hydroxylase (alkB) than microbial abundance estimated by culture-based methods. Such PH-degraders were relatively a few or under detection limit in 900-min ozonated soil. Further PH-removal observed during the incubation period supported the presence of PH-degraders in ozonated soils. Highest reduction (25.4%) of total PH (TPH) was observed in 180-min ozonated soil white negligible reduction was shown in 900-min ozonated soil during the period, resulting in lowest TPH-concentration in 180-min ozonated soil among the ozonated soils. Microbial community composition in 9-wk incubated soils revealed slight difference between 900-min ozonated and unozonated soils as analyzed by whole cell hybridization using group-specific rRNA-targeted oligonucleotides. Results of this study suggest that appropriate ozonation and subsequent biodegradation by indigenous microorganisms may be a cost-effective and successful remediation strategy for PH-contaminated soils.

Removal of phenanthrene by electrokinetic method combined with Fenton-like process was studied in a model system. The scale of reactor was 100cm in length, 100cm in width, and 70cm in height. The distance between electrodes was 70cm. Indonesia kaoline was selected as a model soil. When constant voltage of 100 V was applied to this system, current decreased from 200 mA to 100 mA for 14 days. Total accumulated EOF was about 55,000 mL. The concentration of phenanthrene near anode was very low because direction of electroosmosis was from anode to cathode and hydrogen peroxide was supplied to anode reservoir. Phenanthrene concentration was increased as the location was far from anode because hydrogen peroxide was gradually decomposed and then the rate of hydroxyl radical production was decreased.

최근 수년간 유선 시뮬레이션은 연산 속도의 효율성과 수치 분산으로 인한 오차를 감소시킬 수 있는 장점으로 인해 많은 연구가 이루어졌으며 오염물의 거동을 모사 하는데 많이 사용되고 있다. 이 연구에서는 유선 시뮬레이션의 기법을 이용하여 1차의 비평형 흡착을 고려한 오염물 거동 수치 모사를 수행하였다. 1차의 비평형 흡착의 경우 흡착 계수에 따라 오염물의 이동 속도가 민감하게 반응하는 것을 확인할 수 있었고 흡착 계수의 값이 커질수록 오염의 전파 지연 효과가 크게 나타남을 알 수 있었다. 1차의 비평형 흡착의 경우에 평형 흡착과는 달리 오염이 진행되면서 오염물의 농도를 감소시키는 영향을 나타내었으며 이로 인하여 오염물이 더 이상 진행하지 못하는 제로라인을 형성하게 하였다. 이 제로라인은 흡착 계수의 값이 클수록 탈착 계수의 값이 작을수록 오염원에 가깝게 형성되었다.

This research was conducted to assess the performance of the mixed reactive materials with sand, iron filings, and HDTMA-bentonite for trichloroethylene (TCE) and chromate removal under controlled groundwater flow conditions. TCE and chromate removal rates with the mixtures of iron filing/HDTMA-bentonite were highest among four columns due to reduction by iron filings and sorption by HDTMA-bentonite. The greater capacity of the mixed iron filing/HDTMA-bentonite compared HDTMA-bentonite was due to an enhanced chromate reduction in addition to chromate sorption. The presence of chromate caused greater inhibition of TCE removal in the column with iron filings, while the presence of TCE caused less inhibition of TCE. Also, nitrate caused the decrease in TCE removal relative to chloride. Nitrate ions may also significantly affect TCE reduction rates by competing for electrons with the chlorinated compounds. The anion and co-existed contaminants competing effects should be considered when designed permeable reactive barriers (PRBs) composed of zero valent iron for field applications to remediate TCE and chromate.

Field scale application of in-situ ozonation were carried out for remediation of variably saturated soils contaminated with diesel fuel with 3 dimensional test cell (3m$\times$2m$\times$2m). After 20 days of ozone injection, more than 90% of removal rate was observed through the 3-D test cell. This result might be caused by uniform distribution, relatively low oxidant demand, and low water content of soils, as well as high oxidation potential of ozone. However, less than 50 % of injected ozone was monitored through the 3-D test cell even after 20 days of injection.

The objective of this study was to investigate reductive dechlorination of aromatic hydrocarbons using zero valent metals (ZVMs) and catalysts as reactive materials for permeable reactive barriers (PRBs). A group of small aromatic hydrocarbons such as monochlorophenols, phenol, benzene were readily reduced with palladium catalyst and zero valent iron. Poly-aromatic hydrocarbons (PAHs) were also tested with the catalysts and zero valent metal combinations. The aromatic rings were reduced and partly reduced PAHs were found as the daughter compounds. Current preliminary study implicate that ZVMs and modified catalysts can be successfully applied for PRBs which currently applicable for halogenated organic compounds and some inorganic contaminants including chromium(Ⅵ) and nitrate.

제주지역 하수종말처리장에서 발생하는 방류수(2차 처리수)를 재이용함으로써 지하수에 편중된 제주도의 용수 이용패턴을 다원화하는 대체수자원으로 활용하기 위하여 2001년 6월부터 하수처리장 방류수 재이용 방안연구를 실시하였다. 제주도내에서 운영 중인 3개 하수종말처리장의 방류수에 대한 장기적인 수질검사 결과, 염소이온 함량이 높아 재처리를 하지 않은 상태로 재이용 하기는 곤란한 것으로 파악되었다. 따라서, 재처리를 위한 최적의 공정을 선정하기 위해 pilot test를 실시한 결과, 방류수를 MF(정밀여과)막 전처리 ＋ RO(역삼투)막 처리의 재처리 공정으로부터 재처리된 물(3차 처리수)의 수질은 먹는물로 사용하더라도 전혀 문제가 없을 만큼 깨끗하게 처리되었다. 따라서 방류수 배출량이 많은 제주시 도두 하수처리장과 서귀포 보목 하수처리장의 방류수를 재처리하여 비음용 생활용수, 골프장 관개 수용수, 농업용수, 지하수 인공 함양용수 등으로 재이용하는 방안을 제시하였다.

To solve the problems of operating passive mine drainage treatment systems, the In Adit Sulfate Reducing System(IASRS) was suggested. By placing the SAPS inside the adit, the condition of constant temperature of 10~15$^{\circ}C$ can be maintained. The experiments using the models made up by four sections showd good efficiencies in pH control and metal removal rate, but showed still low sulfate removal rate of about 30% with high COB in the begining of the operation.

Soil and ground water environments around closed landfill is very important to estimate a environmental stabilization of landfill. In this study, geoenvironmental investigation was carried out for closed unsanitary landfill in Gyeonggido. Geotechnical and environmental characteristics of ground water and soil around this landfill site was evaluated for analysis of its environmental situation.

The hight density sludge process (HDS) is a process that has been developed to achieve greatly increased sludge densities compared to those resulting from conventional pH modification systems. This study was carried out to apprehend variation of sludge properties and removal of metals during recycling of the sludge. The principal neutralization and settlement took place in neutralization beaker and mass cylinder. Sludge was recycled, as a volumetric ratios of 20%, 40% and 60%. The pH was controlled in neutralization tanks near 9.5. The average lime consumption rate was about 10g per L of AMD. The increment of sludge density was correlated with the volumetric ratios of recycled sludge.

The monitoring effectiveness not only depends on the effectiveness of the network, but also the costs of the network. Generally the costs of the monitoring network are mainly on the equipment and personnel; the implementation and maintenance; the observation and sample connection; the sample analysis; and the data storage and processing. The cost of the monitoring network can be expressed as a function of monitoring frequency because the monitoring method can be an automatic or a manual measurement. To determine the sampling frequency of subsidiary groundwater monitoring stations, time series data of national groundwater monitoring stations were used. The proposed optimal sampling frequency for subsidiary groundwater monitoring station is about 7 to 20 days and the average frequency is about 2 weeks.

하천과 지하수위의 변동양상을 알아보기 위하여 갑천변에 깊이별로 관정을 설치하여 지하수위와 하천수위를 비교하여 본 결과, 하천과 지하수위는 서로 손실과 이득을 반복하면서 상호작용을 하며, 지하수위는 강수에 비하여, 하천의 수위와 보다 밀접한 상관성이 나타나는 것으로 나타났다. 대상지에서의 하천은 평상시에 이득하천이었다가 홍수위 때 순간적으로 손실하천으로 변한다. 따라서 지하수가 하천으로 지속적으로 유출되기보다는 하천과 지하수위의 변동에 치하여 그 공급원 역할이 수시로 변화하며, 제방저류지의 발달에 따른 하천의 홍수위가 어느 정도 조절되게 된다.

hillslope에서 하천주위에 수리적으로 연관된 대수층의 지하수 수위와 하천수위는 그 수리경사의 방향에 따라서 이득하천과 손실하천으로 구분되며 이득하천이라도 홍수 시 손실하천으로 역전될 수 있다. 이러한 현상은 hillslope에서 기저유출의 발생여부를 좌우한다. 시간에 따른 하천의 수리경사 변화곡선으로 기저유출의 기여도와 지하수-하천수 수위곡선을 이용하여 그 양상을 비교하였다. 전라남도 곡성군 삼기천 소유역에서 연구기간 중 지하수관측지점에서 기저유출의 기여도는 37.4%이며 지하수-하천 수위곡선의 변화양상은 시계방향이다.

동위원소희석법에 의한 열이온화 질량분석법(ID-TIMS)을 이용하여 한국지질자원연구원과 에너지기술연구 원내 지하수와 강우 희토류원소의 함량을 측정/해석하였다. 분석결과를 토대로 지하수의 희토류원소 함량은 강우의 함량과 비교해 볼 때, 상대적으로 낮은 값을 보여준다. 그리고 굴착 심도가 더 깊은 한국지질자원연구원의 지하수내 희토류원소 함량이 한국에너지기술연구원의 지하수내 함량보다 더 낮은 값을 보여준다. 이는 강우가 지하로 흘러들어 가면서, 희토류원소와 대수층 구성암석과의 흡착반응에 의해 심부로 갈수록 함량이 낮아졌을 가능성이 크다고 판단된다. 뿐만 아니라, 강우의 경우, 희토류원소의 W형-테트라드 효과가 매우 현저하게 나타나고, 지하수에서는 M형과 W형의 테트라드 효과가 동시에 존재하는 특성이 강한데, 이는 희토류원소의 수화수 및 화강암 대수층과의 물-암석 반응에 의한 결과인 것으로 사료된다.

Efforts for better understanding of the interaction between groundwater recharge and thermal regime of the subsurface medium is gaining momentum for its diverse applications in water resources. A numerical model is developed to simulate temperature variations of the subsurface under time varying groundwater recharge. The model utilizes MacCormack scheme for finite difference approximation of the partial differential equation describing the conductive and advective heat transport. For the estimation of recharge rate, optimization of the model is realized by searching for the unknown parameters which minimize the root-mean-square error between simulated and measured temperatures. Simulation results for 22-year time series data of temperature measurements reveal that the proposed model can accurately simulate subsurface temperature variations resulting from the redistribution of the heat due to the movement of water and it can also estimate temporal variations of recharge. Seasonal variations of recharge and a linear relationship between precipitation and recharge are clearly reflected in the simulated results.

Variation of decision variables for optimal remediation using the pump-and-treat method is examined to estimate the effect of the degree of concentration constraint. Simulation-optimization method using genetic algorithm is applied to minimize the total pumping volume. In total volume minimization strategy, the remediation time increases rapidly prior to significant increase in pumping rates. When the concentration constraint is set severer, the more wells are required and the well on the down-gradient direction from the plume hot-spot gives more efficient remediation performance than that on the hot-spot position. These results show that the more profitable strategy for remediation can be achieved by increasing the required remediation time than raising the pumping rate until the time reaches a certain limitation level. So, the remediation time has to be considered as one of the essential decision variables fer optimal remediation design.

경남 밀양지역의 대수층별 지하수위 분포 특성을 파악하기 위하여 2002년 봄에 총 503개 지하수공을 대상으로 지하수위를 측정하였다. 조사된 자료는 수치가 낮은 지점들에 집중되어 있어 정규분포를 이루지 않으나, 대수변환 된 자료는 정규분포를 나타내었다. 표고와 천층 및 심층 지하수위의 회귀 분석을 실시한 결과, 모두 정(＋)의 상관관계가 높은 것으로 나타났다. 베리오그램 분석이나 교차 베리오그램 분석 결과, 원시자료보다 대수변환 된 자료가 반베리오그램이나 교차 반베리오그램의 적합선에 더 잘 맞는 것으로 나타났다. 교차 타당성 분석 결과, 천층 지하수위에 대한 정규크리깅 및 코크리깅 모델링에서 원시 자료가 대수변환 된 자료보다 추정치에 더 가깝게 나타났고, 심층 지하수위에 대한 정규크리깅 및 코크리깅 모델링에서는 원시 자료보다 대수변환 된 자료가 추정치에 더 가깝게 나타났다. 정규크리깅이나 코크리깅을 이용하여 작성된 대수층별 지하수위 등고선도에서 등고선의 분포는 대체로 비슷하지만, 코크리깅에 의해 작성된 지하수위 등고선도가 정규크리깅에 의한 지하수위 등고선도보다 더 정밀한 것으로 나타났다. 이것은 원시 자료뿐만 아니라 대수변환 된 자료를 이용한 지하수위 등고선도에서도 같은 결과가 도출되었다.

시계열 분석 기법을 통하여 창원시 대산면 갈전리 강변여과수 취수지역의 지하수위와 하천수위와의 연관성을 살펴보았다. 연구지역의 6개 관측공의 30분 간격의 지하수위의 자기상관성을 분석한 결과, 세 개의 그룹으로 나타난다. 이 세 그룹은 낙동강으로부터 가까운 거리에 있으며 강한 자기상관성을 보이는 그룹(1그룹), 하천으로부터 비교적 가깝고 양수정으로부터 떨어져 있는 그룹(2그룹), 그리고 약한 자기상관성을 보이는 그룹(3그룹)으로 나타난다. 1그룹이 강한 자기상관성을 보이는 것은 낙동강의 영향 때문인 것으로 판단되며, 3그룹의 약한 자기상관성은 취수정의 양수의 영향으로 판단된다. 6개 관측공 지하수위와 낙동강 수위의 교차상관분석을 실시한 결과, 교차상관함수가 0.1이하의 낮은 교차상관성을 보이고 있다. 이는 취수정의 양수에 의한 관측공의 수위변동에 의해서 낙동강 수위와의 연관성이 잘 나타나지 않기 때문이다.

제주대학교 시험부지에 토양수채수기를 설치하고 2002년 11월부터 2003년 6월까지 토양수의 산소와 수소 동위원소 조성을 관측하였다. 토양수의 산소와 수소 동위원소 조성은 이 지역에 내리는 강수의 동위원소 조성을 반영하고 있음이 확인되었다. 중수소과잉값(d-값)으로 볼 때 연구지역에서 지하 30cm 깊이 토양까지 강수가 도달되는데 약 2개월 그리고 60cm 깊이까지 도달되는데 약 4개월의 겉보기체류시간이 소요되는 것으로 관찰되었다.

Unused well and improperly abandoned wells are a significant threat to groundwater quality. If abandoned wells is not properly filled with material, it can directly channel to flow contaminated and surface water into subsurface and groundwater. The abandonment process is over viewed and the method of filling with impermeable and permeable material is presented for the purpose of proper well abandonment work.

강서구를 제외한 부산 전지역에서 1998년도에 조사된 지하수 수질 중 6개 성분(pH, TS, KMnO$_4$, Cl, SO$_4$, NO$_3$-N)에 대한 일반통계분석 결과 pH 성분을 제외하고는 5개 성분의 중앙값이 평균보다 적은 값을 보이는 양성왜도를 보임으로써, 수질오염정도를 분석하기 위해 지시크리깅이라는 비모수적인 지구통계분석기법을 적용하였다. 6개 수질성분에 대해 음용수 기준치를 적용하여 음용가능은 “1”의 값이, 음용불가능은 “0”의 값이 주어졌다. 이렇게 변환된 자료를 이용하여 각 성분별로 실험적인 베리오그램 분석을 실시한 결과 pH, TS, SO$_4$ 성분은 선형모델이 선정되었으며, KMnO$_4$, Cl, NO$_3$-N 성분은 구상형모델이 선정되었다. 본 연구에서는 지시크리깅을 이용하여 6개 성분의 분포도를 작성하고 부산지역의 오염정도를 분석하였다. 지시크리깅기법은 연구지역 전체의 정량적인 분포를 나타내지는 못하지만, 오염의 유.무와 오염의 크기를 정확하게 파악할 수 있으며 또한, 이상치(outlier)가 크게 영향을 미칠 수 있는 통계학적인 오류를 보완할 수 있다.

Statistical analysis is performed to estimate the correlations between geological or geographical factor and groundwater inflow rates in the Seoul subway system. Correlation analysis shows that among several geological and geographical factors fractures and streams have most strong effects on inflow rate into tunnels. In particular, subway line 5∼8 are affected more by these factors than subway line 1∼4. Time series analysis is carried out to forecast groundwater inflow rate. Time series analysis is a useful empirical method for simulation and forecasts in case that physical model can not be applied to. The time series of groundwater inflow rates is calculated using the observation data. Transfer function-noise model is applied with the precipitation data as input variables. For time series analysis, statistical methods are performed to identify proper model and autoregressive-moving average models are applied to evaluation of inflow rate. Each model is identified to satisfy the lowest value of information criteria. Results show that the values by result equations are well fitted with the actual inflow rate values. The selected models could give a good explanation of inflow rates variation into subway tunnels.

연안지역에서 해수침투대의 평가를 위하여 다양한 물리검층을 수행하였다. 특히, 해수침투대의 정량적인 평가에 활용될 수 있는 지층의 공극측정은 매우 어려운 문제중의 하나이다. 연안지역의 경우, 미고결지층에 대한 불교란 시료 채취가 어렵고 대부분의 관측정은 시추공 붕락방지를 위하여 내경 50mm 의 PVC 케이싱을 설치하는 경우가 많기 때문에 공극의 측정은 현실적으로 많은 어려움이 따른다. 본 연구에서는 전남 영광지역에서 각종 조사목적으로 굴착한 시추공에서 다양한 물리검층을 수행하여 공내수의 높은 전기전도도가 기원하는 지층을 확인하고자 하였다. 전자유도검층과 공극검층을 수행한 시추공(YK-4호공)에 대한 해석결과, 공내수의 높은 전기전도도는 물리검층법으로 추정한 사질층 공극수와 비슷한 범위를 보였다. 물리검층법으로 추정한 공극이나 높은 염수를 보이는 구간에 대한 해석결과는 보완해야할 많은 부분이 있지만 제한된 현장 상황에서 조사결과의 불화실성을 줄이는데 많은 기여를 할 것으로 기대된다.

균열암반내의 수리적 유동 특성을 파악하기 위하여 다양한 물리검층을 수행하였다. 물리검층법은 시추공 주변 지층이나 공내수의 물리적 또는 유동 특성의 연속적인 측정이 가능한 장점을 지니고 있어 최근 지하수 조사나 환경오염 분야에 활용이 점점 증가하는 추세이다. 본 연구는 균열 암반내에서 지하수의 유동 특성 파악에 효과적인 Heat-pulse type의 유향ㆍ유속검층을 이용하여 시추공과 교차하는 파쇄대의 수리적인 연결 특성을 파악하였다. 특히, 양수를 병행하면서 취득한 유향ㆍ유속검층 자료는 시추공내로 지하수가 유입 또는 유출되는 구간을 정확하게 파악할 수 있었다. 이들 결과는 지하수 수치모델 설정, 각종 공내 수리시험 등에 중요한 정보를 제공할 수 있을 것으로 기대된다.

대수층 저장 및 회수(Aquifer Storage and Recovery, 이하 ASR) 기법은 지표수가 여유가 있는 기간동안 지하 대수층에 정수된 물을 주입하여 두었다가, 첨두 수요(peak demand)가 필요한 한시적인 기간동안 대수층 내에 저장되어 있던 물을 양수하여 공급하는 새로운 개념의 수자원 공급 체계의 일환이다. 본 발표에서는 미국 Oregon 주의 대표적인 3개 도시에서 수행된 수자원 공급 사업과 이 수자원 공급사업에서 ASR 기법이 어떻게 적용되었는지를 살펴보았다. 이들 도시에서 수행된 ASR 기법을 활용한 수자원 공급은, 기존 지표 저류조 저장 방식에 비해 월등히 경제적이며, 다양한 이점을 가지고 있는 것으로 드러났다. 또한 이들 도시에서의 ASR 기법 적용에 따른 효율성이 2001년도 및 2002년도에 분명하게 나타나 현재 이들 도시는 ASR 시설에 대한 확충 계획을 수립, 진행하고 있다. 한편, 이들 지역의 ASR 기법 활용 용수 공급 사례는, 국내의 경우에도 투수성이 우수한 화산암 지역, 제3기 지층 및 석회암 지역 등에서 활용될 경우, 충분한 효과를 발휘 할 수 있을 것으로 기대된다.

본 연구는 제주지역 지하수의 수질 특성 중 pH에 주목하여 공간적 분포특성을 파악하였다. 먹는 물 수질기준의 경우 pH는 5.8∼8.5의 범위를 요구하고 있다. 제주지하수의 대부분은 이 범위 내에 속하나 특정지역의 경우 상한선을 초과하는 경우도 있다. 이의 원인을 규명키 위한 기초적 조사로서 우선 공간적 분포 특성을 조사하였고 조사결과 지하수위 구성암질 및 오염원과의 명확한 상관성은 판단하기 어려우나 추후 연속적인 측정과 자료분석을 토대로 검토예정이다.

This study is intended to give information on agricultural nonpoint source pollution and transport related to fertilizer application and irrigation practice. Field-simulated soil columns were set up and leaching studies on fertilizer components such as nitrogen and phosphorus were performed. Nitrogen and phosphorus in the leachate showed different trends in each column and nonpoint source pollution in agricultural areas may be expected to depend on planted crops, soil conditions, and climate as well as irrigation and fertilizing management.

Multi-phase extraction of LNAPLs not only floating on groundwater but also captured in soil pores was studied in a simulated soil system. The extraction rate of LNAPL under the MPE conditions was much higher than the rate under usual hydraulic gradient conditions. The WE might be especially useful for recovery of oils in fine-textured soils such as clay-dominant soils. The vacuum-enhanced transport of LNAPL in soils also depended on the properties of LNAPL such as viscosity and density as well as soil textures.

When the soil vapor extraction as a remediation method of contaminated soil and groundwater has been used, the effects of curtain wall, mode of pump operation were examined by numerical simulation. Consequently, it was found that the removal rate was enhanced in case that the curtain wall was established around the extraction well with the extraction pumps operated alternatively. It was because that the removal of high density gas around the extraction well was possible.

Laboratory tests were performed to investigate the dielectric property of saturated sands contaminated by heavy metals solution at low frequency. Differences of contamination and the real part of dielectric constant depend on heavy metal concentration was measured at low frequency, 100KHz below. The optimal frequency to develop the detection potentials of monitoring was 1KHz, 10KHz, 100KHz. At this frequency, Heavy metal contamination of saturated sands contamination can be recommended by analysis of complex dielectric constant.

A series of laboratory experiments was conducted to investigate the fixation characteristics of poly(vinylalcohol)-poly(methacrylic acid)(PVA-PMAA) mixed solution on the soluble (equation omitted)-radionuclides. Using the potentiometric titration technique, it was found out that the PVA and PMAA in a solution form intermacromolecular complex. The mobilized portion of each radionuclide by water from sand surface treated with a fixative was measured by ${\gamma}$-ray spectroscopy, The mobilized portion of minor radionuclides such as $^{241}$ Am, $^{154}$ Eu, $^{155}$ Eu and $^{144}$ Ce were higher than those of $^{134}$ Cs and $^{137}$ Cs. The capability of PVA-PMAA system was better among the candidate solutions for the fixation of total (equation omitted)-radioactivity, $^{134,137}$Cs which is composed of more than 85 % of total ${\gamma}$-radioactivity could be fixed effectively by the PVA-PMAA solution.

생물학적 토양오염 복원기술은 산소와 영양염류를 오염토양에 공급하여 호기성 미생물의 대사작용을 자극함으로써 유류를 생분해 하는 방법으로 널리 사용되고 있다. 유류에 오염된 토양은 혐기성 상태인 경우가 대부분이기 때문에, 호기성 미생물을 이용하기 위해서는 충분한 산소를 공급하여야 하므로 운전비가 많이 드는 단점이 있다. 최근에는 혐기성 미생물을 이용하여 유류오염 토양을 정화하는 방법이 보고되고 있다. 혐기성 생분해 방법은 다소 분해 속도는 느리지만 산소를 공급하지 않기 때문에 경제적인 유류오염토양 복원 방법으로 주목받고 있다. 본 연구에서는 디젤을 사용하여 인위적으로 10000 mg/kg.TPH soil의 농도로 오염시킨 토양 50g을 100$m\ell$ 용적의 vial에 주입하고 하수처리장의 혐기성 소화조 슬러지를 15$m\ell$, 30$m\ell$을 주입하여 배양하였으며 TPH의 분해량과 CH$_4$ 및 $CO_2$ 발생량을 측정하였다. vial의 기상을 $N_2$가스로 치환함으로써 혐기성 상태가 되도록 하였으며, 35$^{\circ}C$에서 90일간 배양하였다. 그 결과, 슬러지를 주입하지 않은 대조군의 경우에는 TPH의 분해가 거의 없었지만, 슬러지를 주입한 경우에는 TPH(Total Petroleum Hydrocarbon)농도가 55% 제거된 것으로 나타났다. TPH의 분해는 CH$_4$ 및 $CO_2$ 발생량과 밀접한 상관관계를 보였다. 본 연구의 결과로부터 하수처리장의 혐기성 소화조 슬러지를 이용한 유류오염 토양의 복원 가능성을 확인할 수 있었다.양에서 유동 가능성이 있는 중금속만을 추출하였다. 분석실험은 토양의 Cd2+ 와 Pb2+를 대상으로 행하여졌으며, 여러 토양에서 추출 분석한 결과를 EDTA분석결과와 비교하였다. 실험결과, 중금속은 매우 신속하게 고분자 자성체와 결합하였고, 그 후 자성체를 외부 자장으로 모은 후 산으로 용해시키고, 결합된 중금속은 Graphite furnace AAS로 분석함으로써 빠르고 효율적으로 분석실험을 수행할 수 있음을 알 수 있었다. 한편, 실험에서 나타난 수치들을 비교 검토한 결과 토양 분석시 sandy soil에서는 자성체를 이용한 분석이 EDTA에 의한 방법보다 더 높은 추출도를 보인 반면, silt 함량이 많은 토양의 경우에서 EDTA분석에서 더 높은 중금속 추출도를 보였다.s 중에서 490nm와 555nm의 복합밴드를 포함하는 OC2 알고리즘(ocean color chlorophyll 2 algorithm)을 사용하는 것이 OC2 series 및 OC4 알고리즘보다 좋은 추정 값을 도출할 수 있을 것으로 기대된다.환경에서는 5일에서 7월에 주로 이 충체의 유충이 발육되고 전파되는 것으로 추측되었다.러 가지 방법들을 적극 적용하여 금후 검토해볼 필요가 있을 것이다.잡은 전혀 삭과가 형성되지 않았다. 이 결과는 종간 교잡종을 자방친으로 하고 그 자방친의 화분친을 사용할 때만 교잡이 이루어지고 있음을 나타내고 있다. 따라서 여교잡을 통한 종간잡종 품종육성 활용방안을 금후 적극 확대 검토해야 할 것이다하였다.함을 보이고 있다.X> , ZnCl$_{3}$$^{-}$같은 이온과 MgCl$^{+}$, MgCl$_{2}$같은 이온종을 형성하기 때문인것 같다. 한편 어떠한 용리액에서

The electrokinetic remediation tests for natural soil contaminated by lead are performed on unsaturated conditions, in which the degree of saturation is controlled through the changes in water content and the constant unit weight. At the degree of saturation of 70% the small acid range and electrical potential is developed. The changes in the water content are little above the saturation of 90%. But it is increased by 1.7 times at the degree of saturation of 70%. Finally, the efficiency of extraction is improved at 70% than 100%.

The natural soil containing organic matter and ferrous is used in the Electrokinetic-Flushing Remediation(EFR) tests. A series of tests are carried out through controlling the concentration of acetic acid in the EFR cell. The test results showed that the electrical potential in X/L=0.9 is increased with the increasing of the concentration, and pH in the sample is the similar at all of the region because of the buffer capacity of natural soil. Finally, the efficiency of EFR is enhanced at acetic acid of 1mM. But it may not be not strongly affected by the concentration of acetic acid.

The precipitation of heavy metals within the region of pH jump is inevitable in the conventional electrokinetic remediation technology. This study prevents the interest species from precipitating through the injection of flushing solutions in which HCl, acetic acid, citric acid, EDTA and SDS dissolved. The cumulative flow resulted from electroosmosis appear in order of Citric acid

Plants may enhance the remediation of munitions at contaminated soils using various natural processes. A computer model can be used as a valuable tool for assisting phytoremediation by predicting the transport and fate of target contaminants at remediation sites. For this research, modeling of phytoremediation and bioremediation of soil contaminated with 2, 4, 6-trinitrotoluene (TNT) was studied. Indian mallow (Abutilion avicennae) was grown in columns packed with 126mg TNT/kg contaminated soils for 50 days and a simulation model was developed to simulate the transport and fate of TNT and its breakdown products interacting with plant roots in a partially saturated soil. The column test showed the substantially enhanced reduction of TNT and greater soil microbial activity in Indian mallow planted soil compared to unplanted soil. The model successfully simulated the fate of TNT and by-products in phytoremediation. The results suggested that plants could provide favorable environments for reduction of TNT.

비소로 오염된 토양, 하천 퇴적물 및 광미의 복원할 때, 토양 세척 공정에서 중요한 인자인 비소의 화학적 결합형태와 세척제에 따른 용출특성과 고효율 세척 및 세척액의 재활용도를 높이기 위한 공정을 바탕으로 토양세척장비를 설계하였다. 화학적 결합형태에 있어서 토양은 잔류 결합형태가 주되고, 퇴적물의 경우는 철산화물과의 결합형태가 강하며, 광미는 황화물과의 결합에 따른 잔류형태와 철산화물과의 결합형태가 상당부분을 차지한다. 세척제에 따른 용출특성으로부터, 철산화물과 황화물과 결합하고 있는 비소의 화학적 결합형태를 파괴하면서 비소를 추출할 수 있는 용제로 HCl, Oxalate, EDTA, M$_2$O$_2$를 사용하였다. 추출 결과, 비소가 철산화물과 결합한 형태가 비중이 높을수록 EDTA 나 Oxalate가 효율이 높으며, 황화물에 대해서는 HCl과 $H_2O$$_2$이 상대적으로 높은 추출 효율을 보였다. 구성된 세척조는 밀폐실린더형과 스크류이송형 세척조로 구성되어 각각 혼합교반에 의한 세척과 토양입자 분급에 따른 세척이 가능하다. 세척 공정중 최적 산도 조절이 중요한 인자가 되며, 세척액의 재활용도를 높일때, 세척수에 용해되어 있는 비소 및 중금속과 미립자의 동시 제거를 위한 응집 침전조에서 응집제에 의해서 미립자와 함께 제거하는 응집, 침전 및 분리공정을 배치하였다.

본 연구에서는 경유와 윤활유로 오염된 토양에서 유류분해능이 우수한 분해균주 5종을 분리하여 동정하였고. 분리된 미생물을 이용하여 실험실 및 현장 Pilot Test 수행으로 현장 복원에 필요한 설계인자를 도출하여 실제 현장 토양복원에 적용하였다. 미생물의 투입량은 2.0 $\times$ $10^{6}$ CFU/g 이상으로 투입하고, 투입 영양분의 조성은 오염된 탄소원의 몰비 농도와 비교하여 질소원으로는 황산암모늄, 요소, 질산암모늄 등을 질소 몰수로 첨가하구 인산원으로는 인산칼륨, 이인산칼륨 등을 인산 몰수로 공급하여 토양의 C/N/P 비율이 100:10:1~ 100:1:0.5 범위 이내로 조절되도록 오염 토양에 영양분을 공급하였으며, 경작 횟수는 3회/주 이상으로 수행하여 오염토양 TPH 5,000ppm을 40일 동안 2,000ppm 이하로 복원하였으며, 이때 생분해상수 k는 0.0229/day로 확인되었다.

When an electrokinetic process is applied to a HOC-contaminated soil, hybrid types combined with soil flushing, chemical oxidation, and bioremediation are generally used. Especially when the electrokinetic process is combined with bioremediation, the hybrid technology can solve several limits of bioremediation such as low microbial mobility, low soil temperature, and shortage of nutrients in subsurface circumstance. Because microbial surface is charged negatively, the microorganism moves from cathode to anode under electrical field. In this study, mixed culture mainly-consisted by Pseudomonas sp. was applied to remediate pentadecane-contaminated kaolinite with particle size less than 300${\mu}{\textrm}{m}$. This remediation system was named ‘electrokinetic bioaugmentation’ and consisted of model aquifer, electrode reservoirs, bioreactor, power supply, and pump. The mixed culture above 0.5 of optical density in bioreactor was supplied to two reservoirs and penetrated soil when the electric current was applied. To enhance the removal efficiency, the optimal medium composition, electric current, and voltage were investigated.

Recently electrokinetic process is known to be a promising remediation technology for the contaminated soils with heavy metals, radionuclides, organic matters, and so on. The contaminants in electrokinetic technology are removed mainly by three mechanisms; electroosmosis, electromigration, and electrophoresis. When direct current is introduced between two electrodes planted in soil, a large amount of hydrogen ions is formed and moves from anode to cathode with the other cations contained in electrolyte. The water flow caused by tile movement of cations is called as electroosmosis. Especially for non-ionic pollutants, the electroosmotic flow(EOF) is the most important removal mechanism among them and transports contaminants from anode to cathode along the water flow. In this study, characteristics of electroosmotic flow was investigated according to the resistance state of soil. The decrease, maintenance, and increase of soil resistance could be obtained by controlling ions in soil. When the resistance of soil was decreasing or maintained, the EOF is proportional to electric current and voltage, respectively and when the resistance was increasing, the EOF is proportional to only electric current not voltage.

This study was carried out to investigate the effect of soil properties, such as soil organic matter(SOM) content and water content on die-off and regrowth of indigenous microbes due to in-situ ozonation. Four different soils were collected and the soil samples applied to different ozonation time(0-360 min) were incubated during 4 weeks. Population of the indigenous microbes was monitored during incubation period. The number of indigenous microbes in all samples dramatically decreased (more than 90%) within 30 minutes of ozone injection. With increased ozonation time by 360 minutes, the number of the indigenous microbes decreased by 99.99% in all samples. Die-off of the indigenous microbes due to ozone treatment was inversely proportional to SOM and water content. Especially, sample 3 and Sample 4 containing relatively high SOM content and water content showed high regrowth rate, and this resulted from the increase of water soluble and biodegradable organic fraction in soil water after ozone treatment. Soil sample ozonated for 360 minutes showed minor increase in microbial population during 4 weeks of incubation period.

유기염소계 농약 중 대표적인 살충제 $\delta$-BHC(hexachlorocyclohexane)와 1, 2-DCB (1, 2-dichlorobenzene)에 대한 논, 밭 토양 및 풍화 토에 흡착 배치실험을 통하여 토양 특성과 유기오염물간의 흡착 관계를 규명하였다. 13개의 토양시료에 대하여 pH, CEC, 유기물 함량, 비표면적, 입도분석, 원소조성분석을 통하여 토양의 물리ㆍ화학적 특징이 토양 흡착에 미치는 영향을 규명하고자 하였다. 유기염소계 농약의 흡착량을 Freundlich isotherm으로 나타내어 흡착분배계수(K$_{d}$)를 산출하였다. $\delta$-BHC는 유기물 함량이 높은 soil-4$_{d}$에서 가장 높은 $K_{d}$ 값을 보였으며, 1,2-DCB의 경우 CEC, 비표면적이 가장 낮은 soil-5에서 낮은 $K_{d}$ 값을 보여 토양 내 유기물 함량과 비표면적이 유기오염물 흡착량에 중요한 요소로 작용함을 알 수 있었다.

비소로 오염된 폐광산주변 하천 퇴적토 오염 복원을 위한 토양세척법의 복원효율을 규명하였다. 세척액에 대한 비소제거 효율을 규명하기 위해 오염된 3종류의 하천 퇴적토에 대하여 초산, 구연산, 염산 각 0.01, 0.05, 0.1, 0.5, 1N 수용액과 증류수(pH 5.41)에 대한 세척실험을 실시하였다. 실험결과 세척 효율은 염산과 구연산 용액의 경우 0.05N 이상에서 저농도의 구연산을 제외하고 99.9% 이상의 제거효과를 나타내었다. 초산의 경우 1N의 경우에도 36%와 71%의 낮은 세척 효율을 보였으며, 증류수로 세척한 경우에는 20% 내외의 세척 효율을 나타내었다. 이러한 세척 효율은 본 오염지역의 복원목표를 토양오염 우려기준의 40% 농도(2.4mg/kg)로 설정하여 하천퇴적토를 복원할 수 있음을 나타내고 있으며, 결론적으로 오염 퇴적토의 농도 분포에 따라 적절한 세척액을 선택한다면 세척 효과를 훨씬 증대시킬 수 있으리라 사료된다. 본 연구를 통한 세척효율 결과는 연구지역을 포함한 전국 각지의 폐광산 복원공정 설계에 중요한 자료로 활용될 수 있을 것으로 판단된다.

광산 및 폐광산으로부터의 오염 및 유해영향에 대한 보고와 관심이 대두되면서 휴ㆍ폐광산에 대한 연구가 활발히 진행되고 있다. 본 연구는 경북 군위군의 고로 폐광산 주변 중 광미 및 광폐석으로 오염된 것으로 생각되어지는 하천 및 농경지에 대한 오염 정도와 분포를 규명하기 위하여 토양정밀조사를 실시하였다. 토양 오염 정밀조사 지침에 따라 총 741개의 토양 시료 분석 결과 Cu, Cd, Pb은 토양오염 우려 기준에 훨씬 미치지 못하였지만 As는 표토 및 심토 구간(0-30cm)에서 토양 오염 우려 기준 농도를 상당 수 초과하여 하천 및 농경지의 복원이 필수적임을 알 수 있었다. 합리적인 복원물량을 산출하기 위하여 배경치 농도(1.23mg/kg), 토양오염우려기준 40%농도(2.4mg/kg), 토양오염우려기준농도(6mg/kg), 토양오염대책기준농도(15mg/kg)별로 오염 등급을 나누어 오염 지도를 작성하고 각 등급별 복원목표에 따라 복원이 필요한 면적과 복원대상물량을 산출하였다. 본 연구는 오염토양의 복원을 목적으로 국내에서 최초로 실시된 대규모의 토양정밀조사라는 점에서 의미가 있으며, 이 결과는 실제 고로 폐광산지역의 복원 사업설계에 중요한 자료로 사용될 수 있다.

본 연구에서는 비소로 오염된 토양 정화를 위한 수산화나트륨의 적용성에 관한 실험을 수행하였다. 수산화나트륨과 함께, 중금속 제거에 효율적이라고 알려진 염산과 citric acid를 50mM과 100mM로 적용하여 비교 세척실험을 실시하였다. 선정한 비소로 오염된 토양 중 광미와 밭 토양에 대해서는 수산화나트륨에 의한 세척이 보다 효율적이었으며, 하천퇴적 토양의 경우에는 수산화나트륨이 citric acid와 비슷한 효율을 보였다. 수산화나트륨을 이용한 시간에 따른 용출실험 결과, 3가지 토양 모두 적용농도 범위 내에서는 6시간 이후부터 90%이상의 비소 용출효율을 보였다. 수산화나트륨의 최적 농도 선정을 위해 각기 다른 농도 (50, 200, 300, 500, 750, 1000 mM)를 이용하여 각각의 토양을 세척한 결과, 3가지 토양 모두 200mM이 최적 농도임을 알 수 있었다.

In this study, a risk-based cleanup approach using the leaching potential was suggested for the soil vapor extraction (SVE) process. A multi-component model was adopted with local equilibrium assumption (LEA), and Raoult's law was applied to estimate the leaching potential for BTEX. Finally, a risk analysis was conducted based on the leaching pontential calculated. To complete the feasibility of this approach, more investigations and discussions will be required in future.

Polycyclic aromatic hydrocarbons (PAHs) are representative hydrophobic organic carbons (HOCs). Surfactant-enhanced electrokinetic (EK) remediation is an innovative in-situ technology that can effectively remove HOCs from low-permeability soils. In this study, the electrokinetic remediation using Tergitol 15-S-12, a nonionic surfactant, was conducted for the removal of phenanthrene from kaolinite. Tergitol 15-S-12 was used at concentrations of 1.5, 2.0, 2.5 and 7.5 g/L to enhance the solubility of phenanthrene. When the surfactant solution was applied to EK system, high electrical potential gradient was maintained and the amount of electroosmotic flow decreased. Removal efficiency of phenanthrene was proportional to the concentration of Tergitol 15-S-12 because the solubility and mobility of phenanthrene was enhanced by surfactant micelle. Therefore, the suitable concentration of nonionic surfactant Tergitol 15-S-12 is expected to improve the removal efficiency of PAHs in EK remediation.

The adhesion of hydrocarbon degrading bacteria(HDB) differing in surface hydrophobicity was investigated. Cell wall hydrophobicity was modified chemically and physiologically. Modified adhesion deficient mutant of HDB was selected in a soil column assay Physiologically and chemical modification increased cell surface hydrophobicity. Cell surface charcteristis including BATH and zeta potential were measured. Physiological modification using ampicillin was not stable, but chemical modification was stabel. Hydrocarbon degrading potential was measured for modified and unmodifed HDB.

Batch experiments were performed to determine optimum conditions for biopile. The batch experiments results showed that 12.5 to 17.9% of moisture content was effective to biodegradation of petroleum hydrocarbon regardless of soil texture. Total heterotrophic bacteria populations in the inoculum-treated soil were greater than of the control and nutrient-amended soil in the early stage, but the populations in the inoculum and nutrient-amended soil were not different significantly from those in the latter stage regardless of soil texture. The same trend was observed for petroleum hydrocarbon degrading bacteria populations. The results of the biodegradation capacity experiments showed that there was a decline in the TPH concentrations during the experiments and no significant difference on the biodegradation was observed by treatment in silt soil. Changes of n-C17/pristane and n-C18/phytane ratios in all treated soil were significantly more than those of control. This is a strong indication of biodegradation. The TPH removal rate was calculated at 60% in all treated soil.

Accidental release of petroleum products from underground storage tank(USTs) is one of the most common causes of groundwater contamination. BTEX is the major components of fuel oils, which are hazardous substances regulated by many nations. In addition to BTEX, other gasoline consituents such as MTBE(methyl-t-buthyl ether), anphthalene are also toxic to humans. Natual attenuation processes include physic, chemical, and biological trasformation. Aerobic and anaerobic biodegradation are believed to be the major processes that account for both containment of the petroleum-hydrocarbon plum and reduction of the contaminant concentrations. Aerobic bioremediation has been highly effective in the remediation of many fuel releases. However, Bioremediation of aromatic hydrocarbons in groundwater and sediments is ofen limited by the inability to provide sufficient oxygen to the contaminated zones due to the low water solubility of oxygen. Anaerobic processes refer to a variety of biodegradation mechanisms that use nitrate, ferric iron, sulfate, and carbon dioxide as terminal electron accepters. The objectives of this study was to conduct laboratory-scale microcosm studies in assessing enhanced bioremediation potential of BTEX and MTBE under various electron accepters(aerobic, nitrate, ferric iron, sulfate) in contaminated Soil. these results suggest that, presents evidence and a variety pattern of the biological removal of aromatic compounds under enhanced nitrate-, Fe(III)-, sulfate-reducing conditions.

비위생폐기물매립지 8개소에 대해 주변토양과 지하수에 대해 분석을 실시하였다. 토양환경보전법과 지하수의수질보전등에관한규칙에 규정된 전항목을 분석하여 얻은 결과 주변토양의 경우 휘발성유기화합물질 등은 검출되지 않았으며 중금속류는 대부분 토양오염우려기준치를 만족하였으나 D매립지 주변토양에서 Cu가 기준치를 초과하였다. 지하수의 경우 COD가 일부 매립지를 제외한 나머지 매립지에서 모두 생활용수기준치를 초과하였으며, 페놀도 기준치 이상의 농도가 검출되었고 J매립지 지하수시료에서는 NO$_3$-N이 기준치를 약 20배나 초과하였다.

Metal sorption onto the ICS (Iron oxide coated sand) was studied in batch experiments. Heavy metal cations such as Cd, Pb, and Cu, and a metal anion, As, which sporadically exist in mine sites, were tested for the sorptive removal by ICS. In low pH conditions As showed the highest removal efficiency compared to the other metal cations. And the sorption removal of As was apparently pH-independent reaction. However, removal of metal cations increased with pH and above pH 7 most metal cations showed very low soluble concentrations after treatment. Such a high removal ratio of metal cations above the neutral pH appeared predominantly due to precipitation.

QAMDI(Quantified Acid Mine Drainage Index) was developed for more synthesised, qualified and quantified assessment index which can be applied to both coal and metal mine drainage. QAMDI is calculated using three parameter groups i.e. acidity, sulfate contents and toxic metal contents. Since QAMDI expressed in terms of concentration. It reveals the different status of each mine drainage more clearly. QAMDI can be converted to the quantity of pollutant loading by being multiplied by the water flux.

To evaluate the potential capacity of mine wastes in the production of heavy metal containing acid water, samples from depths of 0, 30 and 60cm were collected and analyzed. The waste from surface showed the lowest pH which indicates the oxidation of wastes and the capacity of contamination of the area around the waste file. And the lower pH values of leachate of the wastes through the leaching tests with pH controlled water(3, 4, 5) may indicate that minerals producing the acidity still exist. Reduction of sulfur contents in wastes after the leaching test well fit to the increased contents of iron oxide.

The applicability of in situ microbial filter or biobarrier technology for the remediation of soil and groundwater contaminated with chlorinated solvents was investigated. The efficiency and rates of reductive dechlorination of chlorinated solvents are known to be highly dependent on hydrogen concentration. In this study, the effect of electron donors on the reductive dechlorination of PCE was investigated using vermicompost (worm casting) and peat as permeable reactive barrier medium The effect of organic acids (lactate, butyrate and benzoate), yeast extract and vitamin $B_{l2}$ on the reductive dechlorination was investigated. Compared to the control (no electron donor added), addition of electron donors stimulated the dechlorinated rate. Among the electron donor treatments, lactate/benzoate amendment exhibited the highest dechlorination rate. Since vermicompost and peat are inexpensive and biodegradable and have high sorption capacity, they could be successfully used as biobarrier media, especially when electron donors (for example, lactate/benzoate) are added.d.

Geosynthetic Clay Liners(GCLs) have been widely used as hydraulic barrier in landfills and remediation projects of contaminated sites. The aim of this research is to modify GCLs for effective removal of contaminants. We perform the free swell test, hydraulic conductivity test, and contaminants (TCE, hexavalent chromium, and nitrate) removal test on the bentonite-ZVI mixture with various ZVI content. As the ZVI content increased, contaminants removal efficiencies and swell volume increased, and hydraulic conductivity decreased.

해안의 연약지반에 건설되는 폐기물 매립지는 매립지의 안정성 평가를 위하여 하부기초지반의 침하거동 특성에 대한 분석이 필요하다. 본 연구에서는 현장 침하계측자료를 이용하여 현장 간극비와 현장 압축지수를 역산하여 그 특성을 분석하였다. 그 결과 매립초기에는 상부하중에 의한 유효응력증가가 미소하여 하부기초지반은 과압밀 특성을 나타내고 현장 압축지수 변화가 미소하였으나, 매립이 진행될수록 상부하중이 선행압밀하중을 초과하여 정규압밀영역으로 변화함에 따라 큰 폭의 증가를 보였다.

In this study, we examined the influences of pH and total concentration on the speciation of heavy metals (Cd, Cu, Zn) in acid mine drainage. Their labile concentrations were analyzed by Anodic Stripping Voltammetry (ASV) at both natural pH and adjusted pHs (from 2 to 8). We obtained regression equations for predicting labile concentrations as a function of the water pH and contamination level (total dissolved metal concentration). Our data show that labile Cu depends on both the total concentration and pH, while labile Cd and Zn concentrations are controlled mainly by their total concentration rather than pH. Therefore, the pH variation of AMD may significantly change the toxicity and bioavailability especially of Cu, owing to its speciation change.

Total extraction of stream sediments in the Kwangyang mine area shows their significant pollution with most trace metals such as Cr, Co, Fe, Pb, Cu, Ni, Zn and Cd, due to sulfide oxidation in waste dumps. Calculations of enrichment factor shows that Chonam-ri creek sediments are more severely contaminated than Sagok-ri sediments. Using the weak acid (0.1N HCl) extraction and sequential extraction techniques, the transport and sediment-water partitioning of heavy metals in mine drainage were examined for contaminated sediments in the Chonam-ri and Sagok-ri creeks of the Kwangyang Au-Ag mine area. Calculated distribution coefficient (Kd) generally decreases in the order of Pb $\geq$Al > Cu > Mn > Zn > Co > Ni $\geq$ Cd. Sequential extraction of Chonam-ri creek sediments shows that among non-residual fractions the Fe-Mn oxide fraction is most abundant for most of the metals. This indicates that precipitation of Fe hydroxides plays an important role in regulating heavy metal concentrations in water, as shown by field observations.

Micellar enhanced ultrafiltration(MEUF) is a surfactant-based separtaion technique which can remove dissolved organics or multivalent ions from water. In this study, trichloroethylene(TCE) and chromate were simultaneouly removed using MEUF and cetyltrimethylammoniun chloride (CPC) was used as a surfactant. The removal efficiency of chromate was 99% and that of TCE was more than 80%. The presence of TCE or chromate did not affect removal efficiency of each pollutants because the predominat mechanism of TCE and chromate are different.

Three kinds of surfactant systems - cationic surfactant (system 1), combinition of two cationic surfactants (system 2), and combination of two cationic surfactant and non-ionic surfactant (system 3) - for the simultaneous removal of nitrate and phosphate by micellar-enhanced ultrafiltration (MEUF) were investigated. The highest removal efficiencies of nitrate and phosphate were observed in system 2, which were 90 % of nitrate and 72 % of phosphate. The COD of permeate in system 3 was the lowest, because the added non-ionic surfactant made critical micelle concentration (CMC) lower than that of other surfactant systems. In all systems, the flux decline was similar.

This study was carried out to apprehend the variation of quality of mine drainage in the abandoned Samtan coal mine. After closure of coal mine, although still pumping, water level in underground was raised to loom and the concentration of some elements such as Fe and Mn was elevated. At present, the worst pollution source in this area is too the acidic leachate drained from uncovered mine waste impoundment. The flow rate of mine drainage from the adit is ave. about 20,000t/d. If water were flooded and deteriorated due to stopping pumping, the impact of the mine drainage on the stream around the abandoned mine would be more severe. Therefore, It is considered that the prediction of water quality of mine drainage from the adit after stopping pumping will be very important with a view to establishing countermeasures.

Subsurface biobarrier technology has potential applications to contain contaminated groundwater and/or to degrade toxic pollutants in groundwater. Effective biobarrier formation is need to assess of hydrogeologic characteristics and to conduct practical operation strategies and design based on this prior to design biobarrier. Thus, in this study, we examined hydrogeologic characteristics in biobarrier construction site. Hydraulic conductivities which calculated from slug test data have shown difference with each well as 1.20$\times$10$^{-3}$ -6.00$\times$10$^{-5}$ cm/sec. Tracer test is a method in which concentration of tracer solution during withdrawal in each well by vacuum extraction system is measured with time. Tracer solution was continuously injected by constant head tank. Measured tracer concentration versus time data were fitted to analytical solution of convection dispersion equation (CDE). The fitting data of CDE to the measured data at each extraction well yielded were 0.61cm/min(pore velocity), 5.38$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.47 1/min and 1.75cm/min(pore velocity), 36.34$\textrm{cm}^2$/min(dispersion coefficient) for discharge rate of 0.93 1/min. As a result, we acquired fundamental parameters which need to design biobarrier and operation strategies.

Environmental pollution problems due to the wastes from various industrial facilities and activities have become a serious issue. The specific problem associated with heavy metals in the environment is their accumulation in the food chain and their persistence in nature. Present work investigates the possible uses of by-products for the removal of heavy metal ions. Heavy metals used in these studies were cadmium, lead and copper. Experiments were conducted with by-products such as oyster shell and fly ash to evaluate their sorption characteristics. The results of the study indicate that oyster shell can be properly used as an adsorbent for heavy metals because of its outstanding removal rate.

In order to investigate processes and factors controlling the chemical and isotopic compositions of the Han River, seasonal studies were carried out. The North Han River was much lower in the concentrations of total dissolved solids (TDS), dissolved inorganic carbon (DIC) and major ions than the South Han River, but higher in $SiO_2$ concentration, $\delta$$^{34}$ $S_{so4}$ value and $^{87}$ Sr/$^{86}$ Sr ratio. This indicates that the chemical and isotopic compositions of the Han River were strongly controlled by the geology of their drainage basins: silicate rocks in the North Han River and carbonate rocks in the South Han River. The $\delta$$^{34}$ $S_{so4}$ values were relatively higher in the North Han River (5.90$\pm$1.46$\textperthousand$)) than in the South Han River (3.48$\pm$0.73$\textperthousand$). This implies that dissolved S $O_{4}$$^{2-}$ in the North Han River might be mostly derived from deposition of atmospheric sulfates, whereas in the South Han River from oxidation of sulfide minerals in the abandoned poly-metallic deposits and the coal-bearing sedimentary rocks distributed over the upstream as well as deposition of atmospheric sulfates. The $^{87}$ S $r^{86}$ Sr ratios in the North Han River were distinctly higher than those in the South Han River, reflecting water-rock interaction with different rock types.pes.

The present study reports the novel physiological function of dissimilatory perchlorate reduction by two strains JB101 and JB109 isolated from a sewage treatment facility in Incheon, South Korea. The physiological data of the isolates showed good correspondence with the members of the family Enterobacteriaceae. The partial 16S rRNA and 16S rDNA sequence of strains JB101 and JB109 showed similarity of 99.8% to Citrobacter amalonaticus and 98% to Citrobacter farmari, respectively. The study infers toward possibility of Citrobacter spp. to form an important group of dissimilatory perchlorate reducers within the (equation omitted) subclass of Proteobacteria because the majority of the known. members belong to two monophyletic groups namely Dechloromonas and Dechlorosoma in $\beta$ subclass of Proteobacteria.

연약지반으로 분류되는 조간대 퇴적층의 연구는 제한적인 시추자료에 의존하고 있다. 비파괴 지반조사 방법은 시추자료에서 획득할 수 없는 지층의 측방변화와 지질 이상대를 확인할 수 있는 대안이 될 수 있다. 지구물리탐사 방법은 현장 토질조사와 같이 직접적인 지반조사 방법과 병행할 경우 지반을 이해하는데 있어 한층 나은 결과를 얻을 수 있다. 부산신항 배후부지 조성지역에서 매질의 상이한 특성에 기초한 비파괴 지반조사 방법으로 이용되는 지구물리탐사를 실시하였다. 각 탐사의 결과는 서로 유사한 지층경계를 나타내며, 시추와 매립공사의 결과와도 일치한다. 또한 계측을 위해 매설된 침하판이나 매설관로의 탐지, 압밀차이에 의한 부등 침하의 측방변화 등과 같이 시추조사에서 인지하기 어려운 부분에 대한 정보를 제공하고 있다.

연구지역은 경남 양산시 상북면 삼삼리 일원으로 양산단층과 인접하며 급한 경사의 자연사면으로 이루어져 있다. 수치지형자료를 이용하여 고도값을 갖는 자료층을 추출한 후 10m$\times$10m 크기의 격자별로 DEM으로 변환하고, 이로부터 단위 격자의 경사도, 경사방향도, 음영도를 작성하고 흐름분배 알고리즘을 이용하여 설정된 격자별로 상부사면의 기여면적과 습윤지수를 산정하였다. 높은 습윤지수를 보이는 지역은 북서-남동 방향의 선형구조로 나타나며, 국소지역의 전단단열 특성과 일치한다. 한편 연구지역에서 전기비저항 탐사를 실시하여 높은 습윤지수를 나타내는 지역과 저비저항 이상대의 분포를 비교한 결과 습윤지수가 높은 지역은 모두 낮은 전기비저항 이상대로 관찰된다. 즉 습윤지수는 암석의 화학적 풍화를 수반하는 파쇄대의 분포와 일치하며 이를 토대로 국소지역에서 파쇄대의 예측과 암석의 안정성을 예측하는 방법으로 이용될 수 있다.

A new approach for groundwater treatment combines a permeable Fe(0) barrier to breakdown higher chlorinated solvents like PCE and TCE with a downgradient aerobic biological treatment system to biotransform less chlorinated solvents, such as DCE and vinyl chloride (VC). The expected bacterial performance downgradient of an Fe(0) barrier was evaluated through laboratory batch experiments with a toluene-degrading mixed culture that cometabolically transforms cis-1,2-DCE and VC. The amount of cis-1,2-DCE (initially at 2,000 ppb) and VC (initially at 2,000 ppb) transformed was controlled by the initial toluene (20,000 ppb) concentration. VC was removed much more effectively than Cis-1,2-DCE, and a higher toluene concentration in comparison to the co-substrate concentrations was needed for complete co-substrate removal. Overall, the coupling of an Fe(0) barrier and subsequent biodegradation appears feasible for remediation of complex mixtures of chlorinated solvents and petroleum hydrocarbons in groundwater

Solid-phase microextraction (SPME) and gas chromatography/headspace techniques(HS) and flame ionization detection (GC/FID) have been combined for determination of very polar compounds in water, including the widely used gasoline oxygenates and by-products. A relatively simple extraction method using a CAR/PDMS(75${\mu}{\textrm}{m}$) SPME fiber was optimized for the routine analysis of gasoline oxygenates and by-products in groundwater and reagent water. A sodium chloride concentration of 25%(w/w) combined with an extraction time of 20 min provided the greatest sensitivity while maintaining analytical efficiency Replicate analyses in fortified reagent and groundwater spiked with microgram per liter concentrations of gasoline oxygenates and by-products indicate quantitative and reproducible recovery of these and related oxygenate compounds. Method dynamic range was 50$\mu\textrm{g}$ L-1 to 3000$\mu\textrm{g}$ L-1 for gasoline oxygenates and by-products.

This study was conducted to examine the potential of biosparging process in removing diesel contaminated soil and groundwater. The experiment was carried out lab-scale biosparging reactor and the biodegradation rate of diesel was evaluated as function of air injection rate and pattern. When renter was operated as air injection rate of 1000$m\ell$/min and pulsed air injection(15min pulse, 15min downtime), DO concentration in the renter was higher than another operating condition. The evidence for biodegradation of diesel was the $O_2$ utilization and $CO_2$ product following the cessation of sparging. Especially, air injection rate of 2000$m\ell$/min and pulsed air injection(15min pulse, 15min downtime) enhanced the diesel biodegradation during the operating. After 120day, the biodegradation rate of diesel was decreased as the lack of carbon source.

Leaking underground storage tanks are a major source of groundwater contamination by petroleum hydrocarbons. Aerobic bioremediation has been highly effective in the remediation of many fuel releases. However, Bioremediation of aromatic hydrocarbons in groundwater and sediments is ofen limited by the inability to provide sufficient oxygen to the contaminated zones due to the low water solubility of oxygen. Nitrate can also serve as an electron acceptor and results in anaerobic biodegradation of organic compounds via the processes of nitrate reduction and denitrification. Because nitrate is less expensive and more soluble than oxygen. it may be more economical to restore fuel-contaminated aquifers using nitrate rather than oxygen. And denitrifying bacteria are commonly found in the subsurface and in association with contaminated aquifer materials. These studies have shown that BTEX and MTBE can be degraded by the nitrate-amended microcosms under aerobic and anaerobic conditons. Biodegradation of the toluene and ethylbenzne compounds occurred very quickly under denitrifying conditions. MTBE, benzene and p-xylene were recalcitrant under denitrifying conditions in this study, But finally Biodegradaton was observed for all of the test compounds.

There has been a steady increase in geoenvironmental engineering projects where geotechnical engineering has been combined with environmental concerns. This study investigate on contaminant around unsanitary landfill situated in urban area and was carried out to evaluate the geoenvironmental characteristics of this site. As a result of this study, groundwater and soil around this landfill site was evaluated for analysis of physical and chemical properties.

A sol-gel fiber-optic biosensor with encapsulated pH-sensitive fluorophore and immobilized genetically modified toluene-o-xylene monooxygenase was developed to detect TCE, which is carcinogenic chlorinate organic compounds prevailing in ground water. The sensitivity was characterized for the composition of sol-gel, and manufacturing procedure.

In this study, the solubilization of dense nonaqueous phase liquid (DNAPL) using oil-based emulsion was investigated for aquifer remediation. The micro-sized oil emulsion has large surface areas and buoyancy force, therefore it can be effective in treating DNAPL pool of the aquifer without downward migration of DNAPLs. The emulsion was prepared using silicone oil and mechanical homogenization. And the prepared emulsion had micro-sized similar distribution: 99 % in number and 80 % in volume were less than 10${\mu}{\textrm}{m}$. As target pollutants, trichloroethylene and 1, 2 dichlorobenzene were selected. All of used DNAPLs were solubilized successfully in oil-based emulsion. Even at low oil percentage, emulsion showed good solubility against pollutants. Therefore, the remediation using oil-based emulsion was considered as an effective alternative in dealing with DNAPLs of the aquifer.

본 연구는 운동장, 주차장, 도로측면, 보도, 기타 주거시설 등의 우수 찻집시설에 사용되는 콘크리트 구조물의 침투능 확보를 위한 투수성 찻집 구조물 개발에 관한 것이다. 투수성을 확보하기 위하여 일반 차집시설의 콘크리트 구조체 벽면에 천공을 하고 천공된 측구 내에 쇄석을 충진시켜 침투되는 우수의 수질도 개선할 수 있다. 본 제작방법은 별도의 침투소재를 사용하는 경우와 비교해 볼 때 경제성이 우수하며 동일시공방법과 규격으로 대체재로서 활용성이 높을 것으로 전망된다, 본 연구에서 개발하고 있는 여재를 이용한 침투시설은 침투능을 충분히 확보할 수 있음을 확인하였고 SS기준으로 27％∼86％의 제거율을 보였으며, COD기준 20％∼68％의 제거율을 나타냈으며, 탁도기준 29％∼88％의 제거율을 볼 수 이었다.

This study is objected to identify the annual variation of shallow groundwater quality in the study area, Hwabong-Jangam, Iljuk-Meon, Kyunggi-Do. The previous study in 2002 shown a wide-spread contamination of shallow groundwater by nitrate mainly originated from wastes of livestock facilities. In the year 2003, groundwater quality of the area has worsened due to the agricultural activities including the application of organic fertilizer and agro-chemicals to improve soil quality. In addition, a leaking septic tank, identified in the previous study, is still expanding its influence on the nearby wells.

이 연구는 우리나라 균열암반 대수층의 수리적 특성을 해석ㆍ평가하기 위하여 양수시험 해석해(Theis, 1935; Cooper-Jacob, 1946; Papadopulos-Cooper, 1967; Hantush, 1962a,b; Moench, 1985; Hantush-Jacob, 1955) 및 일반화 방사상 유동 모델을 이용하여 균열암반 대수층(화강암, 화산암, 변성암, 백악기퇴적암, 제3기 퇴적암에 굴착된 100개 조사공)에서 수행되어진 양수시험으로부터 얻은 122개의 양수시험자료(수위강하 자료)를 분석하였다. AQTESOLV 전산프로그램을 이용한 양수시험자료 분석에 의하면, 122개 자료중 86개(71%)의 자료들이 이 연구에 사용된 해석해와 일치하며, 양수시험자료 해석해 중에 누수(leaky) 및 경계조건(boundary condition)을 고려한 해석해들이 53개(43%)로 가장 많이 나타났다. 그러므로, 양수시험자료의 해석은 균열암반 대수층의 수리지질학적 특성에 적합한 개념모델의 설정이 중요하다. 일반화 방사상 유동(GRF)모델을 적용해보면, 122개의 자료중 77개(63%)의 자료들이 Barker(1988)의 표준곡선에 의한 차원(1.1차원-2.9차원)을 보여준다. 이중 44.2%에 해당하는 39개 자료가 1.1차원과 1.9차원 사이의 분할 유동차원을 보여주는 반면에 26개(6.5%)만이 Theis 이론에 맞는 2차원의 방사상 흐름을 보여주며, 38개(49.3%)는 2.1차원에서 2.9차원에 속한다. 따라서 우리나라 균열암반 대수층에서 지하수 유동은 대부분 분할차원의 유동을 보여주는 것으로 평가된다.

If ground water levels of a confined fractured rock aquifer fluctuate with sea tides, individual values of hydrogeologic parameters can be determined. Tidal efficiency and time lag are first calculated from the water level data recorded at an observation device situated inland from the sea. The tidal efficiency factor of the aquifer at the seacoast is then determined from the observation in monitoring wells and used to calculate storage coefficient. Tidal efficiency factor and the tidal time lag are utilized to calculate storage coefficient and the results are compared. This method is tested in the southeastern coastal area of Busan, Korea. This is a simple and inexpensive way to test confined aquifer but the analysis should be performed according to the coastal environment.

Sulfur isotope composition was used to identify the sources of groundwater contamination near abandonded coal mines. From the analysis of mine adit drainages, tailing seepages, and spring waters near the abandonded Hambaek and Hanchang coal mines in Kangwon Province, it was inferred that it the highly possible source of the contamination of spring water is acid mine drainage(AMD). Sulfur isotope composition showed that seepage from tailings seemed to have more effect on the groundwater contamination than mine adit drainage, which suggests the remediation and anti-contamination methods of tailing seepages not only mine adit drainage are required.

충북 보은읍 지역을 대상으로 계절별 지하수의 변화 양상을 파악하기 위하여 2002년 겨울과 봄에 지하수의 현장수질 성분인 수온, pH, Eh, DO, EC, TDS 등을 측정하고, 지하수를 채취하여 실내에서 유기물 분석을 실시하였다. 지하수 수질을 평가하기 위하여 계절별로 수질자료의 통계분석과 등치선도를 작성하였다. 보은읍의 수질자료에서 정규크리깅을 이용하여 작성된 지하수 수온의 등치선도에 의하면 봄철 조사에서 전반적으로 온도가 3-4$^{\circ}C$ 정도 상승하였고 PH는 겨울철 조사에서는 전반적으로 균등하게 나타나지만, 봄철 조사에서는 북동쪽 지역에 높게 나타나고 있다. 나머지 현장수질 성분들은 계절에 관계없이 일정한 경향을 보여주고 있는데, Eh는 모두 중앙 지역에 높은 수치들이 나타나고 있고, EC 수치는 동쪽 지역이 낮고 서쪽 지역이 높게 나타나고, TDS 수치는 중앙 지역을 중심으로 높게 나타나고, DO 수치는 북쪽 지역이 낮고 남쪽 지역이 높게 나타난다. TCE는 봄철 조사에서는 전 지역에서 비교적 넓게 분포하지만, 겨울철 조사에서는 남쪽 지역이외의 지역에서는 TCE 수치가 나타나지 않았다.

Nowadays, wells tapping the deep aquifers become general because water quality of the shallow groundwater has been gradually degraded over the last 30 years as a result of rapid industrialization and intensive agricultural activities. However, many of the deep wells also suffer problems of water-quality degradation in several years after the well installation, nevertheless those were properly completed and managed. It is believed that the heavy pumping from deep wells causes the doward movement of the contaminated, shallow groundwaters and introduces them into the deep aquifers. In this study, we introduces a shallow capture well system, which could effectively prevent the shallow groundwaters of poor water duality from moving into the deep aquifers by pumping of deep production wells. Even though additional costs are required to apply this system, we believe that this method could be appropriate for the deep wells that are important for the public health.

Groundwater recharge rate can be estimated from groundwater head rebound due to rainfall. Groundwater level changes are monitored for 10 months at Yugu area. Difference between two recharge rates calculated by rainfall and by effective rainfall is 1.1%~1.6%. Since this method ignores soil water percolation during groundwater level regression, the actual recharge rate may be higher than estimated one by cumulative rainfall and groundwater level change.

We performed a hydrochemical study on a total of 89 bedrock groundwaters collected from preexisting wells (30 to 300 m deep) in the Boeun area. Hydrochemical data showed significant variations in the area, due to varying degrees of anthropogenic pollution. The waters were mostly enriched in Ca and HCO$_3$ but locally contained significant concentrations of anthropogenic constituents in the general order of Cl >NO$_3$>SO$_4$. In particular, about 11% of the examined wells exceeded the drinking water standard with respect to nitrate. We consider that aquifers in the area are locally highly susceptible to the contamination related to agricultural activities. Diagrams showing the relationships between the summation of cations (∑cations) and the concentration of several anions with different origin (natural versus anthropogenic) were used to estimate the relative role of anthropogenic contamination. A good correlation was observed for the relationship between ∑cations and bicarbonate, indicating that water-rock interaction (namely, hydrolysis of silicate minerals) is most important to control the water quality. Thus, we made an assumption that the equivalent of dissolved cations for a water should be equal to the alkalinity, if the chemistry were controlled solely by a set of natural weathering reactions. If we excluded the equivalent quantities of cations and bicarbonate (natural origin) from the acquired data for each sample, the remainder therefore could be considered to reflect the degree of anthropogenic contamination. Finally, we performed a multiple regression approach for hydrochemical data using the ∑cations as a dependent variable and the concentration data of each anion (natural or anthropogenic) as an independent variable. Using this approach, we could estimate the relative roles of anthropogenic and natural processes. Rather than the conventional evaluation scheme based on water quality criteria, this approach will be more useful and reasonable for the evaluation of groundwater quality in a specific region and also can be used for planning appropriate protection and remedial actions.

강원도 지역의 대표적인 탄산용출수에 대한 수리지구화학적 연구를 통하여 심부 지열 저장지의 온도와 심부환경을 추정하였다. 탄산용출수는 공통적으로 약산성의 pH와 높은 이온함량으로 특징되지만, 화학적으로는 Na-HCO$_3$형, Ca-Na-HCO$_3$형, 그리고 Ca-HCO$_3$형으로 뚜렷이 구분된다. 심부에서 생성된 탄산용출수가 지표로 상승하는 도중에 수반된 지표수 혼합차이로 인해 이런 화학조성의 차이가 유발된 것으로 판단된다. Na-HCO$_3$형 탄산수는 화학 조성상 ‘mature water’의 특징을 보여주는 반면, 다른 두 유형의 탄산수들은 ‘immature water’에 해당하였다. Na-HCO$_3$ 형 탄산수에 대하여 실리카, Na-K 및 Na-K-Ca 지온계를 적용한 결과, 약 l15-157도의 심부저장지 온도가 산출되었으며, 이 결과는 다성분 평형계를 이용한 추정 온도 (약 140-160도)와도 잘 일치하였다. 반면, Ca-HCO$_3$ 형 탄산수들은 지표수와의 혼합 때문에 상대적으로 낮고 넓은 범위의 추정 온도 (약 60-130도)를 나타내었다. 따라서 연구지역 내 탄산용출수의 심부저장지 온도는 Na-HCO$_3$형에 대해서만 타당하게 적용될 수 있으며, 약 140-160도일 것으로 추정된다.

논 농사 지역에서 지하수 함양량을 산정하기 위해 추적자를 이용한 실험을 실시하였다. 물의 부피와 농도 변화를 측정하였으며 용질의 mass balance와 물수지 균형 식에서 도출한 수치 모델을 이용하여 증발량과 침투량을 계산하고자 하였다. 이를 이용하면 논물의 농도와 부피 변화를 측정함으로서 논 농사지역에서 지하수 함양량을 손쉽게 구할 수 있을 것으로 판단된다.

안산시 단원구 대부동, 보령시 청소면 장곡리와 서천군 비인면 선도리의 해안가 4곳에서 전기비저항 탐사를 이용하여 해수침투 조사용 관측정 주변의 대수층구조와 해수침투여부를 파악하고자 하였다. 공내수의 심도별 전기전도도를 확인 해본 결과, 4개의 조사공에서 180-48,000$\mu$S/cm의 각기 다른 값을 보였으며, 전기비저항 검층의 결과에서는 16인치 Short-Normal 검층 0.5-19.28$\Omega$m, 64인치 Long-Normal 검층 1.36-47.45$\Omega$m 그리고 Lateral 검층에서는 0.16-6.69$\Omega$m의 값의 분포를 보였다. 이를 통해 해수에 의해 지하수 및 주변 지질이 완전히 오염된 관측정과 우려되거나 아직 해수침투가 일어나지 않은 관측정을 구분할 수가 있었다. 또한 시추공-지표간 토모그래피를 통해 관측정 주변의 개략적인 수리지질 구조도 파악할 수 있었다.

새만금 방조제를 통하여 새만금호로 유입되는 해수 침출수량과 새만금 방조제 내부에서의 해수와 담수 사이의 상호작용 등에 대한 연구를 수행하였다. 본 연구에는, 밀도 차이에 의한 흐름을 고려한 지하수 흐름 지배 방정식과 염류의 분산 및 이송 지배 방정식을 결합시킨 수치해석 모델이 이용되었다. 밀도류를 고려한 경우에는 밀도류를 고려하지 않았을 경우보다 해수 침출량은 다르지 않았으나, 해수 침출면의 길이가 축소되고 유속이 증가하였다. 부정류상태의 해수-담수 경계면은 정류 상태의 결과와 매우 달랐으며, 해수 침출면이 방조제의 하부가 아닌 상부에 존재함을 보였다.

This study area has been contaminated by oils. To identify contaminated ranges and to assess the possibility of contamination dispersion, monitoring wells were installed and slug test, field soil permeability test, automatic or manual measurement of groundwater table, and groundwater quality analyses in field and laboratory were performed. In addition, a groundwater modeling program was used to assess the possibility of oil contamination dispersion, based on field data and groundwater quality data. The results showed that concentration of oil contaminants in groundwater have been decreased by dispersion and adsorption.

산을 관통하는 터널은 기존의 지하수위를 낮추어 지하수량 및 수질 변화와 함께 주변 식생에 영향을 미칠 수 있다. 본 연구는 서울시 내부 순환도로 건설에 따라 관악산을 관통할 예정인 터널 건설로 인한 지하수 환경변화를 이해하고자 한다. 즉, 현재 산출되는 지하수, 약수 및 지하수 화학특성을 파악하고 지하수 수문 자료와 연계하여 향 후 수질변화 가능성을 예측하고자 한다. 조사 지역에 분포하는 지하수는 지하수위가 대체로 최대 2m 정도에서 최대 20m를 넘지 않으며 일부 관정은 계절에 따라 수온 변화를 보여 지표수와 연계성을 시사한다. 전반적으로 중성에서 약산성을 띄며 이는 화강암과 화강 편마암으로 이루어진 이 지역의 지질특성에 기인한 것으로 생각된다. piper diagram에 도시하였을 경우 지표수는 지하수에 비하여 Na, K 에 비하여 Ca, Mg, Cl, SO$_4$가 우세한 반면 지하수와 약수의 경우 뚜렷한 특성 차이를 보이지 않으며 넓은 영역에 걸친 분포를 보인다.

We applied the modified invasion percolation (MIP) model to the migration of DNAPL within a two-dimensional random fracture network. The MIP model was verified against laboratory experiments, which was conducted using a two-dimensional random fracture network model. The results showed that the MIP needs modification. To remove TCE trapped in a random fracture network, the density-surfactant-motivated removal method was applied and found very effective to remove TCE from dead-end fractures.

부산 금정산 지역의 지하수위와 강우량과의 관계를 알아보고자 시계열 분석을 통하여 자기상관함수와 상호상관함수를 구하였다. 이를 위하여 금정산 산성마을 주변의 19개 관측공 중 자동수위측정기가 설치된 4개 관측공(KJ2, KJ8, KJ15, KJ19)의 지하수위 자료와 부산지역의 강우량 자료를 이용하였다. 지하수위 및 강수량은 각각 1일 평균, 1일 누적 값을 이용하였다. 자기상관분석의 경우, KJ2와 KJ19의 경우 지연시간이 2일 이내, KJ8의 경우는 3일 이내에 0으로 수렴하며, KJ15의 경우는 지연시간이 8일째에 0으로 수렴한다. 강수량과 지하수위의 교차상관분석결과, KJ2, KJ15, KJ19호 공은 지연시간이 0일 때 교차상관함수가 각각 0.6572, 0.6303, 0.7857이교 KJ8호 공은 지연시간이 1일 때 0.7141이다. 또한 대부분 짧은 지연시간에 교차상관함수가 0으로 수렴한다.

창원시 대산면 갈전리의 강변여과수 취수지역의 8개의 시추공의 시추지료로부터 파악된 지하지질과 물리탐사자료를 비교하여 둘 간의 연관성을 검토하였다. 본 연구에서는 이미 얻어진 시추공 자료와 비교ㆍ검토하기 위하여 지구물리탐사를 실시하였다. 수행된 지구물리탐사는 쌍극자배열 전기비저항 수평탐사, 슐럼버져법배열 전기비저항 수직탐사, 지하투과레이다탐사이다. 전기비저항 수평탐사에 의하면 저비저항치의 두께는 낙동강변에 가까울수록 두꺼워지는 경향성을 보이고 있다. 전기비저항 수직탐사 결과는 시추자료와 비교적 잘 일치하고 있으며 지표로부터 세립질 모래층, 중립질 모래층, 세립질 모래층의 구분이 수직탐사 결과에서 잘 나타나고 있다. 또한 GPR탐사와 전기비저항 수직탐사 결과에 의하면, 지하수면은 6m 부근에 위치하고 있음을 알 수 있다.

어떠한 소유역에서 구하여진 함양율에 대한 영향을 주는 지역화 변수가 있을 때, 이들 변수를 구성하는 인자들에 대한 기여도를 분석하고자 하여 최적화 기법을 이용하였다. 지역화 변수들을 구성하는 각 인자들의 기여도에 면적 가중치를 적용찬 합이 주어진 함양율에 대한 값을 나타낸다고 하면, 함양율이 주어져 있는 여러 개의 소유역에 대하여 방정식을 만들 수 있고, 선형기법(LP)을 이용하여 인자들의 기여도를 계산할 수 있다. 이러한 방법에 의하여 계산된 각각의 지역화 변수들의 인자별 기여도를 통하여 미지의 소유역의 함양율을 추정할 수 있다.

강변여과수 개발 예정지역인 함안군 칠서지역의 수질특성을 알아보기 위해 2003년 4월과 2003년 8월 2회에 걸쳐 강변여과수 양수정, 관측정, 주변지역 지하수 및 낙동강 원수 등 총 38개의 물시료를 채수하여 분석하였다. 용존 이온 분석 결과 연구 지역 지하수의 경우는 Ca-HCO$_3$ 유형 또는 Ca-Cl 유형에 속하며, 조사 지점에 따라 충적층 및 암반 지하수의 특징이 확연히 구분되었다. 조사된 지하수의 경우, 질산성질소와 철, 망간의 농도가 다른 성분에 비해 상대적으로 높은 것으로 나타났으며, 그 외의 중금속의 오염은 미미한 것으로 나타난다. 낙동강 원수의 경우 질산성 질소, 철, 망간은 지하수에 비해 낮은 것으로 나타났으나, 조류의 영향으로 매우 높은 pH 값을 보여주었다. 채수된 전체 시료의 분석 결과, 질산성질소(39.1%), 철(13%), 망간(39.1%)이 주로 먹는 물 수질기준을 초과하는 항목으로 나타났다.

One-year-long groundwater-level data have been collected from 18 wells in Cheon-an area. The result of barometric efficiency, autocorrelation, cross-correlation and statistical distribution evaluated from the measurement data shows that groundwater-level measurements from observation wells are the principal source of information about aquifer characteristics. Data from WA-2 has high barometric efficiency as well as steady decreasing auto-correlation coefficient, which means nonleaky confined aquifer, Most aquifers in this study show the unconfined properties so that barometric efficiencies are mostly low and the coefficients of cross-correlation between groundwater-level and precipitation are commonly high. This study showed that the long-term groundwater-level monitoring data without artificial stress such as pumping would give accurate information about aquifer characteristics.

광산개발로 인한 지하수 유동체계 변형에 따른 주변환경 영향조사의 과정으로 충북 음성군 지역에서 야외 조사를 실시하였다. 조사 과정중 연구지역의 지하수계를 이해하고 개발에 따른 지하수 유동체계 변화를 예측하고자 수행된 모델링의 입력인자 산정을 위해 순간충격시험을 실시하였다. 순간충격시험을 통해 수리전도도, 투수량계수 그리고 저류계수를 산출하였다. 그리고 dummy의 주입과 회수시 다르게 나타나는 수리전도도값의 원인에 대해서도 고찰해 보았다.

There are so many methods to estimate the groundwater recharge. These methods can be categorized into four groups. First groupis related to the water balance analysis, second group is concerned with baseflow/springflow recession, and third group is interested in some types of tracers; environmental tracers and/or temperature profile. The limitation of these types of methods is that the estimated results of recharge are presented in the form of an average over some time period. Forth group has a little different approach. They use the time series data of hydraulic head and specific yield evaluated from field test, and the results of estimation are described in the sequential form. But their approach has a serious problem. The estimated results in forth typeof methods are generally underestimated because they cannot consider the discharge phase of water table fluctuation coupled with the recharge phase. Ketchum el. at. (2000) proposed calibrated method, considering recharge- and discharge-coupled water table fluctuation. But the dischargeis considered just as the areal average with discharge rate. On the other hand, there are many methods to estimate the source wavelet with observed data set in geophysics/signal processing and geophysical methods are rarely applied to the estimation of groundwater recharge. The purpose this study is the evaluation of the applicability of one of the geophysical method in the estimation of sequential recharge rate. The applied geophysical method is called minimum entropy deconvolution (MED). For this purpose, numerical modeling with linearized Boussinesq equation was applied. Using the synthesized hydraulic head through the numerical modeling, the relative sequenceof recharge is calculated inversely. Estimated results are very concordant with the applied recharge sequence. Cross-correlations between applied recharge sequence and the estimated results are above 0.985 in all study cases. Through the numerical test, the availability of MED in the estimation of the recharge sequence to groundwater was investigated

This study is a part of the project to identify water-quality degradation mechanism due to Fe and Mn in the river-bank infiltration system in the Changwon city, Kyungsangnam-Do. Results of hydrogeochemical logging indicated that the matrix of the river bank affects groundwater quality, probably related with the hydraulic conductivities of the different layers of bank deposits. Electric conductivity logging data clearly show various layers of groundwater flows. Further studies are necessary to identify mechanisms of increasing dissolved oxygen contents with depths at some monitoring wells.

부산 동래지역 지열수에 대한 지화학적 진화과정을 밝히기 위하여 지열수, 지하수 및 해수에 대한 수리화학 특성과 이들의 연관성을 고찰하였다. 또한 심부환경에서의 지화학 특성을 규명하기 위하여 각종 이온지질온도계와 다성분 지질온도계를 적용하였으며, 동위원소특성과 함께 지화학 모델링을 통하여 심부환경에서의 온천수의 지화학특성을 밝히고자 하였다. 동래 지열수의 수리화학적 특성은 해수의 영향을 받아 높은 이온함량을 보이며 Na-Cl형을 보여준다. 지열수는 주변 지하수와의 크게 혼합된 양상을 나타낸다. 지화학 모델링에 따르면 지열수는 심부에서 약 5% 영향을 받은 것으로 추정된다. 즉, 심부로 순환하는 지열수가 해수와 혼합되며, 이들이 지열에 의해 가열되면서 광물의 용해 및 침전, 이온 교환반응 등 물-암석 반응을 거치면서 심부지열수를 형성하였으며, 지열수가 천부환경으로 상승하는 과정에서 동래지역 주변 천부지하수와 다양하게 혼합되면서 현재 동래온천수의 화학조성을 갖는 온천수를 형성하는 것으로 지열수의 진화 과정을 설명할 수 있다.

방사성폐기물 처분연구의 일환으로 결정질 암반에서의 지하수의 함양특성을 알아보기 위하여 연구지역의 강수량, 지표유출량 및 지하수위 변동량을 시간별로 일정기간동안 모니터링하였고 채취된 강수, 지표수 및 지하수의 수소동위원소 분석을 수행하였다. 강수사건 (Rainfall event)에 따른 지표유출량과 지하수위는 급격히 증가되며, 지하수위는 약 1일경과 후 최대값을 갖는다. 연구지역 5개 시추공으로부터 모니터링된 지하수위결과는 강수사건에 따라 지하수위의 증감특성을 보여주나, 변화되는 양상은 시추공의 수리특성에 따라 다르게 나타난다. 지표수 및 지하수의 수소동위원소조성은 강수사건에 따라 상응하여 변화되고 있어, 강수, 지표수 및 지하수의 양적변화와 함께 동위원소결과의 해석은 지하수의 함양특성을 정량적으로 추정할 수 있을 것이다.

연구지역에서 설치된 6개의 관정을 대상으로 양수시험을 실시하였다. Neuman method를 이용하여 연구지역의 투수량계수(transmisivity)와 저유계수(storativity) 및 비산출율(specific yield)을 구한결과 투수량계수는 1$\times$$10^{-6}$~9.135$\times$$10^{-6}$ $m^2$/s 이며, 저유계수는 0.0002~0.0085, 비산출율은 0.3~0.4의 값을 보인다. 계산된 투수량 계수를 이용하여 수리전도도(hydraulic conductivity)를 구하였다. 양수정의 심도보다. 깊은 관정에서 계산된 수리상수 값은 큰 값을, 얕은 관정에서는 작은 값을 보여 양수시험시 양수정과 관측정의 깊이에 대해 고려가 필요하다.

용인시 백암취수장 주변 지역의 지하수에 대해 기초적인 지화학적 조사를 수행하였다. 현장측정자료에서는 취수정의 pH와 EC값이 주변지하수보다 지표수와 유사한 값을 보이며, 취수정의 용존산소(DO) 함량이 천층지하수보다 높은 값을 보인다. 더구나 취수정의 경우 NO$_3$함량이 10.5-12.1 mg/L이며 주변 지하수는 7.2-25.3 mg/L, 지표수는 13.1-14.9 mg/L로서 취수정의 설치심도가 70-180m로서 상대적으로 깊은 암반층에 설치되어 있다 하더라도 주변지하수 및 인접 지표수의 혼입에 의해 영향을 받아 오염이 진행되고 있음을 알 수 있다. 이와 같이 연구 지역은 현재 취수정이 모두 청미천변에 위치하고 있어서, 현재 암반 지하수로 개발하고 있는 취수정 지하수가 주변 천부지하수 및 지표수에 의한 혼입 및 오염가능성이 높기 때문에, 앞으로 장기적인 모니터링 및 지화학적 연구가 지속적으로 이루어 져야 할 것으로 사료된다.

방사성폐기물 처분 연구의 일환으로 화강암지역내 500m 심도의 심부시추공이 착정되었으며, 다중패커시스템이 설치되어 장기적으로 심도별 지하수의 수리 및 화학특성이 모니터링 되고 있다. 지하수 수두값의 심도별 특성은 천부에서 심도 250m까지는 대체로 감소하는 경향을 보이며 250m이하에서 500m 심도까지는 증가하는 경향을 보여준다. 각 심도구간에서의 지하수 수두값은 장기적으로 일정한 값을 보여주지만, 장마기간동안 집중적으로 모니터링된 결과에 따르면 심도 370m 상부에서는 지하수 함양변화에 따라 지하수 수두가 변화되는 반면, 심부구간에서는 지하수 함양변화에 대하여 영향을 받지 않음을 보여준다.