• Title/Summary/Keyword: %24H_3BO_3%24

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Reactivity and Preparation of Perovskite-Type Mixed Oxides LaBO3(B = Mn, Fe, Co) by Citrate Sol-Gel Method (Citrate Sol-Gel법에 의한 Perovskite형 복합 산화물 LaBO3(B = Mn, Fe, Co)의 생성 및 환원 반응성)

  • Hwang, Ho Sun;Park, Il Hyeon
    • Journal of the Korean Chemical Society
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    • v.38 no.4
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    • pp.276-282
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    • 1994
  • Perovskite-type mixed oxides LaBO$_3$(B = Mn, Fe, Co) were prepared by citrate sol-gel method in $air(850^{\circ}C$, 24h). The oxygen stoichiometries and structures of these oxides were determined by XRD and TPR results as followings; LaMnO$_{3.16}$(a = 5.507, c = 13.329 $\AA$, hexagonal), LaFeO$_{3.17}$(a = 5.554, b = 5.555, c = 7.863 $\AA$, orthorhomibic), LaCoO$_{3.0}$(a = 5.436, c = 13.095 $\AA$, hexagonal). The temperature programmed reduction(TPR) experiments in static 300 torr H$_2$ atmosphere shows that the reduction reaction of LaBO$_3$(B = Mn, Fe, Co) proceeds into two stages, and thermal stabilities of these oxides decreased in the order of LaMnO$_3$ > LaFeO$_3$ > LaCoO$_3$. According to the kinetic analysis the lowest activation energy was obtained for LaCoO$_3$.

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Median Lethal Concentration ($LC_{50}$) for 24 Hours of Formalin to Eel, Anguilla japonica (뱀장어에 대한 포르말린의 24시간 반수치사농도 ($LC_{50}$))

  • Jung, Sung-Hee;Lee, Joo-Seok;Jee, Bo-Young;Seo, Jung-Soo;Kim, Jin-Woo;Kim, Eung-Oh
    • Journal of fish pathology
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    • v.20 no.2
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    • pp.161-167
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    • 2007
  • Acute toxicity of formalin (37% formaldehyde) was conducted to determine the median lethal concentration (LC50) on eel (avarage weight 96 ± 3.6 g, average total length 43 cm), Anguilla japonica at concentrations ranging from 0 to 500 ppm. In particular, this study was designed to estimate the safety concentrations of formalin in testing eels to eradicate Pseudodactylogyrus. All fish died after 10 hours and 24 hours at 500 ppm and 400 ppm, respectively. After 24 hours, cumulative mortality was 96.6% and 13.3% at 300 ppm and 200 ppm formalin, respectively. However, all experimental fish were alive after 24 hours at 100 ppm. The lethal concentration values were computed by using non-linear least square method. At the start of the test, water temperature, pH and dissolved oxygen level were 27~28℃, 7.4 and 5.55 ppm, respectively. The 24 hr-LC50 were 269 ppm.

Histopathological effects caused by formalin bath on gill and liver of Eel (Anguilla japonica) (포르말린 약욕이 뱀장어 (Anguilla japonica)의 아가미 및 간에 미치는 병리조직학적 효과)

  • Jung, Sung-Hee;Lee, Nam-Sil;Lee, Joo-Seok;Jee, Bo-Young;Kim, Jin-Woo;Kim, Eung-Oh
    • Journal of fish pathology
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    • v.20 no.3
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    • pp.315-325
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    • 2007
  • Histological changes in gill and liver of eel, Anguilla japonica (average weight 96±3.6 g) were examined with formalin bath at 0~500 ppm for 1, 6 and 24 h. Hyperplasia, hypertrophy, cell fusion, desquamation and necrosis of epithelial cells at gill lamella and gill filament were observed from 6 h at 200 ppm, 1 h at 300 ppm, 1 h at 400 ppm and 1 h at 500 ppm. In the exposure of formalin 100 ppm for 24 h, epithelial cells arrangement of gill filament and gill lamella showed thinner and more regular order than the control. trophy and pyknosis of hepatocytes, congestion at sinus or central vein, degeneration of cytoplasm were observed in the liver from 24 h at 100 ppm and 200 ppm, 6 h at 300 ppm, 1 h at 400 ppm and 500 ppm. However, there were not any histological changes at liver of 100 ppm-1, 6 h, 200 ppm-1, 6 h and 300 ppm-1 h compared with the tissue of control.

Efficacy of formalin bath against gill infections with Pseudodactylogyrus spp. in cultured eel Anguilla japonica (포르말린 약욕이 뱀장어 아가미흡충의 구제에 미치는 효과)

  • Jung, Sung-Hee;Jee, Bo-Young;Kim, Jin-Do;Seo, Jung-Soo;Kim, Jin-Woo
    • Journal of fish pathology
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    • v.23 no.3
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    • pp.293-302
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    • 2010
  • Effects of formalin on removal of Pseudodactylogyrus spp. were examined against naturally infected eel, Anguilla japonica (weight 89.9~96g) at a water temperature of $28^{\circ}$. Prior to experiments for removal of the parasite, the hematological toxicity of formalin bath at 0~500 ppm for 30 min~24 h was assessed by hematocrit values (Ht). Based on the results of Ht, appropriate methods of treatment, concentrations and durations, were examined in the main study. There was no significant (P>0.05) change of Ht in 100 to 200 ppm for 24 h. In contrast, Ht increased significantly (P<0.05) at above 300 ppm. This suggests that physiological damage was caused by formalin bath treating with 300 to 500 ppm. Formalin bath with 100 and 200 ppm for 24 h caused significant decreases (P<0.05) in the infection of the parasite. In conclusion, the 100 ppm formalin for 24 hour-bath was found most recommendable for the effective treatment of Pseudodactylogyrus spp. for the gills of the infected eel because of the median lethal concentration ($LC_{50}$) of formalin to eel; cumulative mortalities were found to be 0 and 13.3%, respectively, following 24 h bathing.

Acute viral lower respiratory tract infections in children (소아 급성 바이러스 하기도염)

  • Park, Joon Soo
    • Clinical and Experimental Pediatrics
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    • v.52 no.3
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    • pp.269-276
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    • 2009
  • Viruses are the most common cause of lower respiratory tract infections (LRTIs) in infants and young children and are a major public health problem in this age group. Viruses were identified in 54.9-70.4% of hospitalized infants and children with LRTIs in Korea. The viral pathogens identified included respiratory syncytial virus (RSV) A and RSV B, influenza (Inf) A, Inf B, parainfluenza (PIV)1, PIV2, human bocavirus (hBoV), human rhinovirus (hRV), adenovirus (ADV), human metapneumovirus (hMPV), human coronavirus (hCoV)-OC 43, hCoV-229E, hCoV-NL63, hCoV-HKU1, and human enterovirus (hEV). Coinfections with ${\geq}$2 viruses were observed in 11.5-22.8% of children. The occurrence of LRTIs was the highest in the first year of life. The specific viruses are frequently associated with specific clinical syndromes of LRTIs. LRTIs caused by RSV were predominant among younger infants. hRV accounted for a larger proportion of LRTIs in young infants than ADV and hBoV. hMPV was frequently detected in children >24 months old. The number of hMPV infections peaked between February and May, whereas hRV was detected throughout the year. Thus far, hCoV is a less common respiratory pathogen in cases of ALRI and URI in Korean children.

The Medium Optimization through Continuous Culture of an Methanol Utilizing Bacterium for SCP Production (SCP 생산용 메탄올 자화균주의 연속배양에 의한 배지 최적화)

  • 김창호;김태진홍석인
    • KSBB Journal
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    • v.5 no.4
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    • pp.355-363
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    • 1990
  • Methanol-utilizing bacterium isolated from sewage samples in Seoul showed optimal temperature and pH of $33^{\circ}C$ and 7.1 for growth, respectively. The maximum specific growth rate was $0.42hr^{-1}$. The minimum medium composition was reconstituted depending on the surplus and the deficit of each component in the basal medium at steady state. The optimal composition was given as(g/l); Methanol 40, $(NH_4)_2\;SO_42, \;KH_2PO_4\;1.5, \;K_2HPO_4\;0.2, \;H_3PO_4\;0.79, \;Na_2HPO_4{\cdot}12H_2O\;0.15, \;MgSO_4{\cdot}7H_2O\;1.5, \;FeSO_4{\cdot}7H_2O\;0.034, \;MnSO_4{\cdot}4H_2O\;0.005, \;CuSO_4{\cdot}5H_2O\;0.0027, \;CaCl_2{\cdot}2H_2O\;0.25, \;ZnSO_4{\cdot}7H_2O\;0.007, \;(NH_4)_6\;Mo_7O_{24}{\cdot}4H_2O\;0.00048, \;H_3BO_3\;0.00068, \;CoCl_2\; 0.00024$ Under the continuous culture with optimum medium the maximum cell productivity was 3.8g/1/hr at dilution rate $0.23hr^{-1}$. Maximum cell concentration and its protein content were 19.5g/l and 70% at dilution rate of $0.1hr^{-1}$, respectively.

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Changes in Isoflavone and Some Characteristics of Chokong of Germinated Soybeans during Pickling in Vinegar (발아콩을 이용한 초콩의 제조 중 Isoflavone 및 특성 변화)

  • Eom, Kwon-Yong;Kim, Joo-Sook;Choi, Hee-Sook;Cha, Bo-Sook;Kim, Woo-Jung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.3
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    • pp.359-365
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    • 2006
  • Changes in isoflavone and oligosaccharides, and some physicochemical properties of Chokong, a pickled and dried soybeans, were investigated during pickling in brewed vinegar at $20^{\circ}C$. The used soybeans were 24 hr germinated soybeans, which was maximumly increased in isoflavone content during germination. The isoflavone contents were significantly increased by approx. 80% in both glycosides and aglycone type of isoflavone after 20 day of pickling at $20^{\circ}C$. The isoflavone values of germinated Chokong were significantly higher than those of ungerminated ones. Pickling the soybeans in vinegar resulted in a rapid initial decrease in oligosaccharides, Particularly in raffinose and stachyose. The pH and soluble solids contents in vinegar increased markedly and L values decreased during initial pickling of 24 hr.

Origin of B, Br and Sr in Groundwater from Bukahn-myeon, Yeongcheon, Gyeongbuk Province, with Emphasis on Hydrochemistry (지하수의 수질화학적 특징과 붕소, 브롬, 스트론튬 성인에 대한 고찰)

  • Choo, Chang-Oh;Lee, Jin-Kook;Lee, Chang-Joo;Park, Ki-Ho;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.19 no.2
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    • pp.235-250
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    • 2009
  • Environmental elements such as B, Br, and Sr in groundwater from Bukahn-myeon, Yeongcheon, Gyeongbuk Province, were investigated in order to know their origin with emphasis on hydrochemistry. pH ranges from 7.37 to 8.39. B content is 0.41${\sim}$4.62 mg/L with an average 1.74 mg/L and Br content is 0${\sim}$3.24 mg/L with an average 2.22 mg/L, and Sr content is 0.93${\sim}$8.64 mg/L with an average 2.76 mg/L. The water types plotted by the Piper diagram are different but mostly $Ca-HCO_3$. Some constituents contributing to EC are Na, $SO_4$, Cl with high determinative coefficients($R^2$) of 0.85, 0.70, 0.90, respectively. The coefficients($R^2$) of Cl to Na, K, $SO_4$ are 0.54, 0.68, 0.53, respectively. It should be noted that there are high cocfficients($R^2$) of B-Sr and $Sr-SO_4$ with 0.65, 0.64, respectively. The Cl/Br ratios are 5.21${\sim}$30.70 due to significant depletion of Cl. The $SO_4/Cl$ ratios are 1.32${\sim}$27.24 with an average of 5.92, ascribed to abundant introduction of $SO_4$ or significant depletion of Cl. Chemical speciation calculated shows that B exists mostly as $H_3BO_3$ with less $H_2BO^-_3$ and Br exists as only $Br^-$. Sr exists mostly as $Sr^2$ with less $SO_4$. Saturation index represents that goundwater is supersaturated with respect to barite, kaolinite, illite, K-mica, and smectite while it is slightly undersaturated with respect to silica, gypsum, anhydrite, talc, chrysotile, feldspar, kaolinite, illite, K-mica, and smectite. The saturation index of celestine is -2.23${\sim}$-0.13 indicating more Sr can be incorporated into groundwater. Groundwater is still much undersaturated to halite. It is likely that the origin of S and Sr was related to the Yucheon volcanic rocks. Br might be originated from the local geological features with introduction of anthropogenic matters.

EFFECTS OF OVARY TYPE, OOCYTE GRADE, HORMONE, SPERM CONCENTRATION AND FERTILIZATION MEDIUM ON IN VITRO MATURATION, FERTILIZATION AND DEVELOPMENT OF BOVINE FOLLICULAR OOCYTES

  • Im, K.S.;Kim, H.J.;Chung, K.M.;Kim, H.S.;Park, K.W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.8 no.2
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    • pp.123-127
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    • 1995
  • In vitro embryo production (IVP) is affected by various factors during in vitro maturation, fertilization, and development. In this experiment, the effect of ovary type, quality of follicular oocyte, medium used for fertilization, presence of hormone in medium, sperm concentration on in vitro maturation and fertilization were examined for effective IVP. In vitro maturation was carried out using TCM-199 supplemented with 15% FCS and hormones in 5% $CO_2$ incubator for 24h. In vitro fertilization was performed with frozen-thawed sperm in modified mTALP medium containing 0.3% BSA, $10{\mu}g/ml$ heparin, and 5mM/ml caffeine for 24h. The fertilized embryos were co-cultured on monolayer of cumulus cells in TCM-199. When oocytes were collected from functionally active and inactive ovaries, maturation rate was 76.9 and 7.7%, respectively. When oocytes were classified morphologically to good and poor grades, maturation rate was 75 and 58.8%, respectively. FSH + LH + $E_2$ (86.4%) showed higher maturation rate than control (53.0%) and FSH (73%). The fertilization rate was 28.2, 100 and 91.7% in $1.6{\times}10^5$, $5.0{\times}10^5$ and $10.0{\times}10^5$ sperm concentration per ml. When oocytes were fertilized in mTALP and BO media, fertilization and cleavage rates of oocytes in mTALP were higher (84.3 and 56.9%) than those (67.4 and 23.3%) in BO medium. In this experiment, in vitro maturation, fertilization and development of oocytes were affected by type of ovary, grade of oocyte, hormones, sperm concentration and fertilization medium.

AN EXPERIMENTAL STUDY ON EFFECT OF BLEACHING (표백효과에 관한 실험적 연구)

  • Lee, Myung-Chong;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.2 no.1
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    • pp.11-14
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    • 1976
  • The purpose of this study was to the observe effects of the various bleaching agents on blood clot. Absorbent papers(N9.5) were coated with O type blood and were dried in shadow for 72 hours. Bleaching agents used were 5% NaOCl 30% $H_2O_2$, saturated solutions of $NaBO_3$ $4H_2O$, $Ca(OCl)_2$ and $Na_2O_2$ at $20^{\circ}C$. After the specimens, blood cloted papers were dipped in 10CC of solution for 1 minute, 5 minutes, 30 minutes, 2 hours and 24 hours, specimens were washed with distilled water and dried. Hue Value/Chroma contrived by Munsell was measured in each specimen. The following results were obtained. 1. Superoxol changes 2.5YR 4.5/2 into N9.5 (white) after 24 hours. 2. All bleaching agents except superoxol change YR into Y.

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