• 한국재료학회지
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• 제23권6호
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• pp.329-333
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• 2013

The structural phase transformations of $0.7Pb(Mg_{1/3}Nb_{2/3})O_3-0.3PbTiO_3$ (PMN-0.3PT) were studied using high resolution x-ray diffraction (HRXRD) as a function of temperature and electric field. A phase transformational sequence of cubic (C)${\rightarrow}$tetragonal (T)${\rightarrow}$rhombohedral (R) phase was observed in zero-field-cooled conditions; and a $C{\rightarrow}T{\rightarrow}$monoclinic $(M_C){\rightarrow}$ monoclinic ($M_A$) phase was observed in the field-cooled conditions. The transformation of T to $M_A$ phase was realized through an intermediate $M_C$ phase. The results also represent conclusive and direct evidence of a $M_C$ to $M_A$ phase transformation in field-cooled conditions. Beginning from the zero-field-cooled condition, a $R{\rightarrow}M_A{\rightarrow}M_C{\rightarrow}T$ phase transformational sequence was found with an increasing electric field at a fixed temperature. Upon removal of the field, the $M_A$ phase was stable at room temperature. With increasing the field, the transformation temperature from T to $M_C$ and from $M_C$ to $M_A$ phase decreased, and the phase stability ranges of both T and $M_C$ phases increased. Upon removal of the field, the phase transformation from R to $M_A$ phase was irreversible, but from $M_A$ to $M_C$ was reversible, which means that $M_A$ is the dominant phase under the electric field. In the M phase region, the results confirmed that lattice parameters and tilt angles were weakly temperature dependent over the range of investigated temperatures.

• Advances in environmental research
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• 제6권3호
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• pp.189-202
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• 2017

This study examines the concentrations of particulate-phase polycyclic aromatic hydrocarbons (PAHs) and gas-phase PAHs in sidestream cigarette smoke. Sixteen PAHs were determined for four brands of cigarettes. The volume of the experimental room is approximately $66m^3$. The air samples in the room were collected before and after smoking. The median total of particulate-phase and gas-phase PAH concentrations before smoking $3.13ng/m^3$and $48.0ng/m^3$, respectively. The median concentrations of them after smoking were $10.0ng/m^3$ and $79.6ng/m^3$. The median increases in the total of 16 PAH concentrations per cigarette during smoking were 271 ng for the particulate-phase PAHs and 1960 ng for the gas-phase PAHs. According to the relationship between particulate-phase and gas-phase PAHs after smoking, the two- to four-ring gas-phase PAHs and the higher molecular weight particulate-phase PAHs were probably formed from similar precursors. The relationship between the total suspended particulate (TSP) concentration and the increase in the total particulate-phase concentration of the 16 PAHs per cigarette during smoking were significantly positive. The increase in the total gas-phase concentration of the 16 PAHs tended to increase as the TSP concentration increased. This may indicates that decreasing the amount of TSP produced inhibit the production of PAHs during smoking.

• 열처리공학회지
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• 제12권1호
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• pp.21-30
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• 1999

The present study were investigated changes of precipitation behaviour of laves phase in ferrite single phase and ferrite-martensite dual phase and precipitation of laves phase under stress. Hardness changes in ferrite phase appeared two hardness peaks by precipitation of initial fine precipitator and laves phase in 3Mo-0.3Si and 3Mo-0.3Si-C specimens, respectively. Hardness changes in martensite phase of 3Mo-0.3Si-C specimen was lower in the initial stage of aging by carbide precipitation and after this, increased by re-hardening due to precipitation of laves phase. In the ferrite phase, laves phase was mainly precipitated, whereas in the martensite phase, carbide was preferentially formed during the initial stage of aging and with increasing aging time, laves phase and carbide were simultaneously precipitated by precipitation of laves phase at around carbide. In the ferrite-martensite interface, laves phase was mainly precipitated and carbide was mainly formed at boundary of lath martensite than grain boundary. Adding the stress in aging, fine precipitator of inital precipitation of laves phase precipitated in (100) of perpendicular to tensile direction and has grown to only followed<010>direction and also, volume fraction of laves phase increased. Consequently, the stress added was accelerated initial precipitation of laves phase.

• 조명전기설비학회논문지
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• 제26권11호
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• pp.54-61
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• 2012

This study investigated the relationship between the response time of DVR (Dynamic Voltage Restorer) and the possible compensation range for voltage dips by the DVR system which protects the 3-phase phase-controlled rectifier from said dips. As a result, the permissible range of voltage dip is presented in a 3-phase phase-controlled rectifier. When the DVR compensates for voltage dip, the range of voltage dip can be compensated according to the DVR's response time. Using the proposed method, DVR response time can be determined from the parameters of the 3-phase phase-controlled rectifier and the possible compensatory range of voltage dip, while at the same time it is possible to use a control system having an appropriate speed. Therefore, the use of excessively fast equipment can be avoided, improving the stability of the overall system. The reliability of the DVR concerning the 3-phase phase-controlled rectifier can be verified by simulation.

• 한국세라믹학회지
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• 제33권4호
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• pp.448-454
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• 1996

BaTiO3 세라믹스의 입방정과 육방정간의 상전이에 따른 미세조직 변화를 관찰하였다. 입방정을 육방정영역에서 열처리하는 경우, 시편 표면부터 육방정상이 생성되었고 반대로 육방정을 입방정역에서 열처리하여 상전이 시킬때는 입방정상이 시편이 중심부에서부터 생성되었다. 또한 이러한 상전이 과정 중에는 빠른 입성장과 더불어 불규칙적인 입계형태를 나타내었다. 그 외 낮은 성형압으로 소결체의 밀도가 낮은 육방정 시편을 제조한 경우에는 상대적으로 입방정으로의 상전이가 억제되었다. 이러한 결과들은 육방정의 표면에너지가 입방정보다 상대적으로 낮기 때문으로 해석되었다.

• 한국세라믹학회지
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• 제28권2호
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• pp.160-166
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• 1991

Microstructure and phase changes during the sintering of ZnO varistors were studied in ZnO-Bi2O3-CoO-Sb2O3 and ZnO-Bi2O3-CoO-Sb2O3-Cr2O3 systems using acanning electron microscopy (SEM) with an energy dispersive X-ray analysis (EDAX), X-ray diffraction (XRD) and differential thermal analysis (DTA). The spinel phase and the Bi2O3 phase were formed by the decomposition of the pyrochlore phase during heating. The spinel particles (2-4$\mu\textrm{m}$), which were formed both along ther grain boundaries and within the ZnO grain, were always found near the pyrochlore phase. Intergranular phases (Bi2O3 and pyrochlore) were precipitated from the liquid phase during cooling. The Bi2O3 phases were located at the triple (or multiple) point of the ZnO grains. Cr2O3 played a role in decreasing the formation temperature of the spinel phase and Bi2O3 phase during sintering, and inhibited the grain growth.

• 전기의세계
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• 제28권3호
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• pp.51-56
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• 1979

The purpose of this paper is to study the conversion of single phase to three phase. In the proceeding of phase conversion, it is very convinence to convert two-phase from single phase using cycloconverter before and then two to three phase by scott connection transformer. There are also systematized zero-crossing, mono vibrator and ring counter circuit for the gate trigger circuits of cycloconverter. The wave forms of three phase by experimental results are analyzed and discussed the relation of phase difference among them.

• 한국재료학회지
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• 제21권7호
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• pp.391-395
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• 2011

The structure and dielectric properties of poled <001>-oriented 0.7Pb($Mg_{1/3}Nb_{2/3})O_3-0.3PbTiO_3$ (PMN-0.3PT) crystals have been investigated for orientations both parallel and perpendicular to the [001] poling direction. An electric field induced monoclinic phase was observed for the initial poled sample. The phase remained stable after the field was removed. A quite different temperature dependence of dielectric constant has been observed between heating and cooling due to an irreversible phase transformation. The results of mesh scans and temperature dependence of the dielectric constant demonstrate that the initial monoclinic phase changes to a single domain tetragonal phase at 370K and to a paraelectric cubic phase at 405K upon heating. However, upon subsequent cooling from the unpoled state, the cubic phase changes to a poly domain tetragonal phase and to a rhombohedral phase. In the ferroelectric tetragonal phase with a single domain state, the dielectric constant measured perpendicular to the poling direction was dramatically higher than that of the parallel direction. A large dielectric constant implies easier polarization rotation away from the polar axis. This enhancement is believed to be related to dielectric softening close to the morphotropic phase boundary and at the phase transition temperature.

• 한국세라믹학회지
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• 제32권8호
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• pp.915-921
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• 1995

The morphotropic phase boundary and phase transitions of the solid solutiion system, (1-x)(Na1/2Bi1/2)TiO3-PbTiO3＋xPbTiO3 were studied by investigating changes in crystal structure, variations in permittivity with temperature, and calorimetric behavior. It was observed that the morphotropic phase boundary (MPB) of this solid solutiion system was at near 14 mol% of PbTiO3. Compositions containing less than 10mol% PbTiO3 (x<0.1) exhibited a phase transition, i.e. ferroelectric rhombohedrallongrightarrowparaelectric paraelectric cubic, with increasing temperature. Composition containing more than 14 mol% PbTiO3 (x 0.14) showed a phase transition from ferroelectric tetragonal to paraelectric cubic. In the composition range of 0.1$\varepsilon$ (T) curve, which coincided with a phase transition from ferroelectric rhombohedral to an intermediate phase, was also found.

• 조명전기설비학회논문지
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• 제27권2호
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• pp.45-53
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• 2013

In this paper, we analyze the typical phase voltage and line current waveform characteristics of the distribution system with 3 phase small synchronous generation source in case with load and non-load group, in order to investigate the power quality for end load connected of generation source. As demonstrated by our experimental results, the distortion and power quality of phase voltage and line current waveform were relatively good for low voltage 3 phase model grids connected of 3 phase small synchronous generation source in case with non-load group. However, distortion and power quality of voltage and current waveform was poor for low voltage 3 phase model grids connected to 3 phase small synchronous generation source in the load group with some phase voltage and frequency difference. From the above results, we conclude that the phase voltage and frequency of 3 phase generation source must be identical to that of distribution system source to maximize the power quality. Also, special attention is required in case of having load group or non-load group to 3 phase generation source.