• Title/Summary/Keyword: AKD

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Sizing Efficiency of AKD in Causticizing Calcium Carbonate Filled Paper

  • Wang, Jian;Liu, Ling;Xu, Yong-Jian
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.2
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    • pp.1-7
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    • 2014
  • Causticizing calcium carbonate (CCC) is produced as a by-product in the causticization step of the kraft pulping process. It is often calcined in a rotary lime kiln after being dewatered and reused in the causticizing process. But for the China mill, the conventional recycled way is difficult because the CCC is mainly obtained from non-wood pulping materials, which higher silicon content led to serious silicon obstacle. So it is often discarded as solid waste or used in landfill after dewatering and secondary pollution is brought. In order to prevent its secondary pollution, recent years, the CCC is used as a filler in China papermaking industry. In mill trials, the CCC can be used to replace an amount of precipitated calcium carbonate (PCC). Unfortunately, the application scope and dosage of CCC have been limited due to its lower sizing efficiency than PCC. In this study, the reason for the lower sizing efficiency of alkyl ketene dimer (AKD) when CCC was used as a filler was investigated. The results showed that the materials in green liquid, such as insoluble matter in green liquid, silicon and metal ions, were a little influence on the sizing efficiency of AKD. The higher BET and BJH pore volume of the CCC were the main reason for lower sizing efficiency of AKD when it was used as filler.

Studies on the Printability Improvement of Hanji by Surface Sizing with Mixed Agents

  • Seo, Seung-Man;Kang, Jin-Ha;Lim, Hyun-A
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.5 s.118
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    • pp.38-46
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    • 2006
  • Many researches for extensive uses of Hanji have been performed. With the advent of an information-oriented age, the development of Hanji which is printable has been considered as a new field of study. Since Hanji has many drawbacks in comparison with common printing papers, that is, rougher surface, huger absorption of ink and lower physical properties and printabilities. Improving the properties and printabilities of Hanji is therefore the most important work to deal with. This study was conducted to find out useful mixed agents for surface sizing suitable for printable Hanji. Four surface sizing agents (CMC, corn starch, PYA, AKD) were applied for mixture in this study. The physical properties of surface sized Hanji were measured. Results obtained were as follows. Based on designated agents according to concentration, each of the mixed agents was prepared. The kinds of mixture were corn starch (3%) and PVA (5%), corn starch (3%) and AKD (0.1%), corn starch (3%) and CMC (1%), AKD (0.1%) and CMC (1%), AKD (0.1%) and PVA (5%), CMC (1%) and PVA (5%). Each mixed surface sizing agents was included with these ratios (100:0, 90:10, 70:30, 50:50, 30:70, 10:90, 0:100) respectively. All the mixed agents improved the physical properties and printabilities of Hanji. Among them, mixed agent of CMC (1%) and corn starch (3%) with 90:10 ratio is superior to the others for not only smoothness but also ink printability. In view of the result achieved, it is regarded that it can be fit for using Hanji as a printing paper and turned out to be a good contribution to Hanji industry.

Changes in the Water Absorption Properties of Pulp Mold manufactured with Oil Palm EFB by surface treatments (표면처리에 의한 오일팜 EFB 기반 펄프몰드의 흡수특성 변화)

  • Kim, Dong-Sung;Sung, Yong Joo;Kim, Chul-Hwan;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.1
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    • pp.75-83
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    • 2015
  • The applicability of oil palm biomass, EFB(Empty Fruit Bunch) as raw materials for environmental friendly packaging material, pulp mold, was evaluated in this study. The changes in the water absorption properties of pulp mold by the addition of EFB and the surface treatments with PVA and AKD were analyzed by measuring the changes in the water absorption rate and the water contact angle. The each pulp mold sample was prepared by using laboratory wet pulp molder. And the water absorption rate of each samples were evaluated by measuring times for the absorption of a 0.1 ml water drop on the pulp mold sample surface. The addition of EFB to the pulp mold made of OCC resulted in the decrease of water absorption rate and the increase in the water contact angle. The surface treatments with PVA and AKD on the OCC pulp mold showed the significant reduction in the water absorption rate. However, in case of ONP pulp mold, the addition of EFB and the surface treatments with PVA and AKD showed no big changes in water absorption times. Those might be come from the finer surface structure of ONP pulp mold which were made of more finer and flexible fibers and more hydrophilic fibers. The results of this study showed the functional properties such as water absorption rate, could be controlled by the application of EFB and the treatments with AKD or PVA, especially in case of the OCC pulp mold.

Evaluation of Water Resistance Properties of Pulp Mold depending on the Types of Raw Materials and the Additives (원료종류 및 첨가제 처리에 따른 펄프몰드의 수분 저항성 평가)

  • Sung, Yong Joo;Kim, Hyung Min;Kim, Dong Sung;Lee, Ji Young
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.112-119
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    • 2015
  • The pulp mold attract the increasing concern as recyclable, biodegradable, and eco-friendly packaging materials. In order to broaden the applicability of the pulp mold as substitutes of the expanded styrofoam, the properties of various raw materials for the pulp mold were evaluated and the way for improving water resistance properties of the pulp mold were also tested by applying some additives. The higher value in the fines contents and in the water retention value were shown for the TMP (thermomechanical pulp), which resulted in the bulkier pulp mold with the higher moisture absorption property. In case of water resistance properties, the pulp mold made of white ledger stock showed the higher value in water contact angle and very slow water absorption rate. The addition of oil palm EFB fiber showed the improvement in the water resistance of the pulp mold made of UBKP. The effects of various additives on the improvement in the water resistance properties of the pulp mold were tested by using AKD, PVAm, epoxy resin. The application of AKD leaded to the higher increase in the water resistance. The results in this study showed the effects of AKD for the pulp mold could be improved and optimized by the application with fixing agent and by the ageing treatment after production.

Studies on the Physical Properties of Molded Packaging Material Using Rice-Straw Pulp (볏짚펄프를 이용한 성형포장재의 물성에 관한 연구)

  • Oh, Seung-Won;Kang, Chin-Ha
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.1
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    • pp.79-87
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    • 1999
  • To use the agricultural residues as the raw material of molded packaging material, the packaging trays were manufactured from rice-straw pulp. The physical properties were measured to compare non-treated trays with the addition trays, such as the addition of starch, rosin size, carboxymethyl cellulose(CMC), polyethylene glycol(PEG), alkylketene dimer(AKD), polyacryl amide(PAM). The results were as follows : 1. In the addition of starch, air permeability at addition of 5% was highest. Bursting strength and tensile strength were smaller than non-treated trays. 2. In the addition of rosin size, air permeability, bursting strength and tensile strength were smaller than non-treated trays. 3. In the addition of CMC, air permeability was higher than non-treated trays. Bursting strength and tensile strength were similar to non-treated trays. 4. In the addition of PEG, air permeability was higher than non-treated trays. Bursting strength at addition of 3% was the highest and tensile strength was smaller than non-treated trays. 5. In the addition of AKD, air permeability at addition of 1% and 5% was higher than non-treated trays. Bursting strength and tensile strength were smaller than non-treated trays. 6. In the addition of PAM, air permeability at addition of 0.01% was the highest. Tensile strength at addition of 0.01% were higher than non-treated trays. 7. The water absorption of the trays decreased with increasing adding of natural additives.

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A Basic Study on the Marine Anti-Fouling Coating Using Cellulose Nanofiber (셀룰로오스 나노섬유를 활용한 해양 방오 코팅제에 관한 기초 연구)

  • Jang, Nag-Seop;Kim, Tae-Kyun;Oh, Hong-Seob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.469-477
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    • 2021
  • In this study, the mechanical property of anti-fouling coating using CNF was evaluated to prevent the durability and stability of structure exposed the marine environment. Anti-fouling coating using CNF was prepared by CNF, AKD and waste glass powder, and contact angle test, drying time, viscosity analysis and microstructure were performed. When coating on one number of times, It was showed to relatively high hydrophobic performance in steel. And It was confirmed that the contact angle increased as the content of AKD increased in cement mortar. When coating on three number of times, the surface was confirmed super-hydrophobic at maximum of 151.6°. When mixing waste glass powder, the surface was showed to relatively high hydrophobic. It is pseudo plastic fluid when CNF and distilled water were prepared in a ratio of 1:1, And Anti fouling coating is judged to be suitable for use as coating on marine structure.

Studies on the Physical Properties of Base Paper for the Manufacture of Mulching Mat for Afforestation Seedling (조림묘목 mulching mat 제조용 base paper의 물리적 특성 연구)

  • Kim, Hyoung-Jin;Oh, Dong-Geun;Yoo, Yeong-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.1
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    • pp.37-43
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    • 2009
  • In this study, the physical properties of base paper for the manufacture of mulching mat for afforestation seedling were investigated. The base paper for mulching mat was prepared by stock conditions of PAE and AKD addition into the screened slurry of KOCC for the strengthening effects of wet tensile and burst strength. The optimum additions of PAE and AKD were considered at 2% and 0.5%, respectively. The accelerated aging by ISO 5630-1 and wet heat aging method under hot water for 2 kinds of commercial mulching and wet strength paper were compared with the base paper prepared for mulching mat manufacture. The accelerated aging test for the base paper prepared for mulching mat manufacture resulted in the same tendency of physical properties as two kinds of commercial products. However, the results of wet heat aging test under hot water indicated that the physical strength for base paper prepared was much higher than others. In addition, the opacity behavior for base paper prepared was enough effects to obstruct weeds growth by isolating transmission of sunlight.