• 제목/요약/키워드: AKD

검색결과 68건 처리시간 0.029초

PVAm 용액 종이 두께 방향 침투 kinetics에 영향하는 인자들 (Factors influencing the penetration kinetics of PVAm solution in z-direction of paper)

  • 조병욱;원종명;문은식;최도침
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2011년도 춘계학술발표회 논문집
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    • pp.31-35
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    • 2011
  • Factors influencing penetration kinetics of PVAm solution into paper were investigated with ultrasonic Penetration Evenness Analyzer (PEA). Paper structure was varied by changing basis weight, freeness of pulp, calendering, number of plies and filler addition and hydrophobicity of paper was varied by adding AKD. Important factors affecting liquid penetration are found to be pore structure and hydrophobicity of paper. Pore structure of paper can be designed by controlling refining degree and filler addition. Hydrophobicity of paper can be controlled by internal sizing.

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사이즈도 자동 측정 시스템 개발을 위한 기초연구 I (Automatic Measurement System for Sizing Test I)

  • 김경철;김철환;이지영;;박현진;김성호;심성웅;조후승
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2011년도 추계학술발표회 논문집
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    • pp.327-333
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    • 2011
  • This study investigated the prime difference between different methods for measuring a sizing degree. Based on the results coming from the study, a new type of the automatic measuring system of a sizing degree. The system includes synchronized devices for measuring contact angle and St$\ddot{o}$ckigt sizing degree at the same time.

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제지공정 침착이물질 및 종이내 불순물 성분의 기기분석 (Instrumental Analysis of Deposits on Paper Machine and Holes/Spots in Paper)

  • 마금자;이복진
    • 공업화학
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    • 제9권1호
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    • pp.135-140
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    • 1998
  • 제지공정 트러블을 일으키는 침착물과 제품의 품질을 저하시키는 종이내 불순물들의 성분을 기기분석하였다. 우선적으로 퓨리에변환 적외선분광기(FT-IR spectrometer)를 이용하여 이물질의 원형 그대로를 측정하여 예비정보를 얻은 뒤 열분해-가스크로마토그래피-질량분석기(Py-Gc/MS)를 이용해서 불순물들의 유기성분을 분석하였으며, $590^{\circ}C$에서 열분해시키고 난 ash는 에너지분산분광법(EDS)을 이용하여 무기성분을 분석하였다. 초지기 건조부에 침착된 성분은 지방산 에스테르 및 전분 등의 유기 이물질과 탈크, 크레이, 탄산칼슘 등의 무기 이물질로 이루어진 복합적인 피치형태로써 재사용 도공파지 성분에 의한 것이며, 심사이저 메터링로드에 끼인 침착물은 불안정한 alkyl keten dimer(AKD) 성분이 탄산칼슘과 상호작용하여 침착을 일으킨 것으로 분석되었다. 종이내 구멍 성분은 주원료로 사용되는 펄프에서 혼입된 것으로 판단되는 PE및 PP 성분과 초지공정에 사용된 주 부원료들간의 불안정한 상호작용에 의해 응집된 복합적인 피치성분으로 확인되었다. 작업상의 부주의로 완정공정에서 사용되는 hot melt 및 파렛트 받침대로 사용되는 가소제를 첨가하여 유연하게 만든 PVC 성분이 재사용 파지와 함께 혼입되어 종이내 얼룩 및 반점 등을 발생시키기도 하며, 초지기 용구로 사용되는 고분자 물질(와이어 또는 펠트)의 일부가 사고 등에 의해 공정중에 혼입되어 도공시 스트리크를 발생시킬 수도 있음을 알 수 있었다.

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총 사이징 시스템 (Total sizing system)

  • Proverb, Robert J.;Pawlowska, Lucyna;Komarowska, Kasia;Garro, Gina;Dilts, Kimberly
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2004년도 제30회 국제세미나
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    • pp.19-42
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    • 2004
  • Sizing properties in paper are generally developed through the application of both internal and surface sizes. Rosin, wax, and synthetic sizes including ASA, AKD, and stearic anhydride are and have been used to provide wet-end sizing to paper. In many cases, the use of some of these sizes leads to runnability problems that are inherent in the wet-end operation. Variability in furnish, fines, broke, filler, water chemistry, conductivity, and pH control impacts the wet-end operation. Size press chemicals including starch and polymers such as styrene-acrylic, styrene-maleic, and styrene acrylate emulsions are used in conjunction with internal sizes to improve the paper surface for printing and strength properties, porosity, and opacity improvement. This paper will discuss results from a new, proprietary formulation and process that allows application of sizing chemistry more totally at the size press with reduced emphasis on wet end sizing. Runnability issues are thus minimized at the wet-end, chemical usage is more efficient, and significant cost savings can be realized. Case histories will be presented illustrating the advantages of this new application in commercial trials.

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Characterization of Base Paper Properties on Coating Penetration

  • Kim, Bong-Yang;Douglas W. Bousfield
    • 펄프종이기술
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    • 제35권5호
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    • pp.17-25
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    • 2003
  • The influence of base paper properties and fiber type on coating penetration was studied in terms of characterization of coating holdout using two types of hand sheets as the base paper which were prepared from thermomechanical pulp (TMP) and hardwood bleached kraft pulp(KP) sized internally with alkyl ketene dimmer (AKD). Laboratory rod draw down coater was used for surface sizing and coating application. Characterization of coating penetration was done by measuring the roughness of the backside of coating layer. The backside of the coating was exposed by dissolving the fibers in a solution of cupriethylenedimine (CEO). Data show that internal sizing of base paper is effective and surface sizing is more effective to prevent coating penetration. Comparing between the two types of base papers, backside roughness of coating layer of TMP sheet is much larger and sizing is more effective to reduce coating penetration than those of KP sheet. From the result of water absorption and sizing degree after surface sizing, it seems that internal sizing slows down molecular diffusion much more than capillary penetration, but surface sizing reduces the capillary penetration. Furthermore, predominant mechanism of water into paper of TMP sheet seems to be capillary penetration, but it is molecular diffusion in the case of KP sheet.

지료조성에 따른 종이의 사이징 특성 (The Influence of Paper Stock Type on Characteristics of Sizing)

  • 정상진;김봉용
    • 펄프종이기술
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    • 제37권2호
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    • pp.11-20
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    • 2005
  • This study was carried out to investigate the influence of paper stock type and heat treatment on sizing effect. Various types of pulps were used to make handsheets sized internally with AKD(alkyl ketene dimer) and externally with CMC(carboxyl methyl cellulose). Most of the handsheets were treated with heat by dry oven $(100^{\circ}C,\;30min)$ to evaluate the effect of heat treatment on sizing development. Internal sizing development of newsprint was very bad, but the effect of heat treatment was much higher than those of NBKP, BCTMP. In case of surface sizing, newsprint was more effective compared to the other pulps. Considering above mentioned results, it seems that internal sizing slows down water into paper by molecular diffusion much more than capillary penetration, but surface sizing slows down capillary penetration. With regard to density, a higher thickness sheets showed high heat treatment effect on sizing, therefore it assumed that heat treatment effect on sizing had very close relationship with sheet density.

PVAm 용액의 종이 두께 방향 침투에 영향하는 인자들 (Factors Affecting Z-direction Penetration of PVAm Solution into Paper)

  • 최도침;원종명;조병욱
    • 펄프종이기술
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    • 제47권5호
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    • pp.104-111
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    • 2015
  • Factors influencing penetration of PVAm solution into paper during impregnation were investigated with ultrasonic Penetration Evenness Analyzer (PEA). Paper structure was varied by changing basis weight, freeness of pulp, calendering, and filler addition, and hydrophobicity of paper was varied by adding AKD. In addition, the viscosity of PVAm solution was varied by changing the concentration of PVAm solution. Important factors influencing penetration of PVAm solution into paper were found to be the pore structure and the hydrophobicity of paper, and the viscosity of PVAm solution. Pore structure of paper could be controlled by refining degree and filler addition and hydrophobicity of paper could be controlled by internal sizing. Denser structure of paper, higher hydrophobicity and higher liquid viscosity slowed down the penetration of PVAm solution into paper.

미생물 셀룰로오스를 이용한 한지의 인쇄적성 개선에 관한 연구 (Printability Improvement of Hanji using Microbial Cellulose from Saprolegnia ferax)

  • 강진하;박성철
    • 펄프종이기술
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    • 제40권3호
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    • pp.23-29
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    • 2008
  • This study was performed to improve the printability of Hanji using a microbial cellulose from Saprolegnia ferax through investigating the printability of Hanji sized with the mixture of the microbial cellulose and various kinds of sizing agents. Conclusions obtained from the results of this study were as follows. The proper concentration of a microbial cellulose in sizing a printable Hanji with it was 0.5%. In general, there was no remarkable effect but some effect on the opacity and ink density. Hanji was sized with the mixture(5:5) of microbial cellulose(0.5%) and AKD(1.0%). As a result, ink spread was remarkably improved by the girth reduction of ink spot. There was remarkable effect because the mixture(5:5) of a microbial cellulose(0.5%) and CMC(1.0%) improved not only the gloss but also the density and girth of ink spot. Mixing(7:3) with corn starch(3.0%) showed the smallest girth of ink spot among applied sizing agents. Mixing(7:3) with PVA(5.0%) also showed some effect in the density and girth of ink spot.

액체 침투 특성과 표면 거동 분석을 이용한 사이즈도 자동측정법 (Automatic Test Method of Sizing Degree by Analysis of Liquid Penetration and its Surface Behavior)

  • 이지영;김경철;김철환;;박현진;김성호;심성웅;조후승
    • 펄프종이기술
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    • 제44권2호
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    • pp.18-28
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    • 2012
  • This study was to develop a novel automatic system for measuring St$\ddot{o}$ckigt sizing degree and contact angle at a time. The conventional methods to measure sizing degree had serious problems in obtaining significant differences according to different dosages of a sizing agent, and moreover they disclosed unique limitation due to liquid types used and tester's subjectivity. However, the newly developed system could get reproducible results through total automation of all procedures including liquid dropping, image acquisition and measurement of both St$\ddot{o}$ckigt sizing degree and contact angle. For the St$\ddot{o}$ckigt sizing test, the automatic system could measure sizing degree with more definite differences according to different dosage of AKD, compared to the conventional method. For the contact angle test, the automatic system showed a similar trend to the conventional method but had smaller contact angles due to distortion of an image focus by a sheet curl than the conventional testing machine. The problem from the image out of focus due to specimen curl will be overcome with adopting a new specimen holder for the future system.

아두이노 하드웨어와 안드로이드 ADK 소프트웨어의 결합 (Arduino hardware and Android ADK software combination)

  • 이성진;최철길;이경무;최병윤
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2013년도 춘계학술대회
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    • pp.336-339
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    • 2013
  • 아두이노는 오픈 소스 기반 전자 프로토타이핑 플랫폼으로서, 예술가, 디자이너, 취미 활동가 등 인터랙티브 객체 또는 환경 구축에 관심이 있는 모든 이들을 위해 제작되었다. 아두이노의 강점은 하드웨어에 대한 깊은 지식이 없어도 손쉽게 하드웨어 어플리케이션을 제작할 수 있다. 아두이노의 구성은 AVR 마이크로컨트롤러 ATmega 168을 사용하며 아두이노를 동작시키기 위한 소프트웨어로는 아두이노 프로그램, MATLAB, Processing을 주로 사용하고 있다. 아두이노는 오픈 소스 기반이며 하드웨어를 직접 제작할 수 있거나 실드를 이용하여 추가적으로 아두이노를 결합할 수도 있다. 안드로이드 ADK는 오픈 소스로 공개되어 있으며 안드로이드 스마트폰의 애플리케이션을 제작할 때 사용한다. 그런데 이 안드로이드 ADK에 아두이노 Manifast를 추가하면 서로 호환하여 사용할 수 있다. 아두이노 프로그램을 이용하여 아두이노 브레드보드에 하드웨어를 설계 후 버튼 클릭을 제작하여 서로 연동한 것이다. 본 논문에서는 소프트웨어 부분은 아두이노 프로그램과 안드로이드 ADK를 사용하였고 하드웨어 부분은 아두이노 MegaADK 보드를 사용하였으며 이 소프트웨어와 하드웨어를 이용하여 하나의 앱세서리를 제작한 후 검증하였다.

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