• Title/Summary/Keyword: Accelerated thermal aging

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A Study on the Properties of CSPE According to Accelerated Thermal Aging Years

  • Lee, Jung-Hoon;Kang, Myeong-Kyun;Jeon, Jun-Soo;Lee, Seung-Hoon;Kim, In-Yong;Park, Hyun-Shin;Shin, Yong-Deok
    • Journal of Electrical Engineering and Technology
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    • v.9 no.2
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    • pp.643-648
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    • 2014
  • The accelerated thermal aging of CSPE (chlorosulfonated polyethylene) was carried out for 40.41, 121.22, and 202.04 days at $100^{\circ}C$, which are equivalent to 20, 60, and 100years of aging at $50^{\circ}C$, respectively. The volume electrical resistivities of the accelerated thermally aged CSPE samples for 0, 40.41, 121.22, and 202.04 days were $1.107{\times}10^{14}-2.097{\times}10^{14}$, $7.752{\times}10^{13}-1.556{\times}10^{14}$, $7.693{\times}10^{13}-1.521{\times}10^{14}$, and $7.380{\times}10^{13}-1.304{\times}10^{14}{\Omega}{\cdot}cm$, respectively, at room temperature. The permittivities of the accelerated thermally aged CSPE samples for 0, 40.41, 121.22, and 202.04 days were $2.89{\times}10^{-11}-3.65{\times}10^{-11}$, $3.40{\times}10^{-11}-3.70{\times}10^{-11}$, $3.50{\times}10^{-11}-3.82{\times}10^{-11}$, and $3.76{\times}10^{-11}-4.13{\times}10^{-11}$ F/m, respectively, at room temperature. The EAB (elongation at break) of the accelerated thermally aged CSPE samples for 0, 40.41, 121.22, and 202.04 days were 98.8-101.3, 59.5-60.3, 37.8-39.2, and 41.8-44.3%, respectively, at room temperature. The apparent densities of the accelerated thermally aged CSPE samples for 0, 40.41, 121.22, and 202.04 days were 1.603-1.614, 1.611-1.613, 1.622-1.628, and $1.618-1.620g/cm^3$, respectively, at room temperature. The measured currents of the accelerated thermally aged CSPE and the standard sample were almost constant after 5 min of applying a 300-V/mm electric field to the CSPE. The V-I slope of the accelerated thermally aged CSPE sample was increased if the applied electric field was increased at room temperature, and the V-I slope of the accelerated thermally aged CSPE was higher than that of standard CSPE.

Natural Aging Properties Analysis of HTPB Propellant (HTPB계 고체추진제의 자연노화 물성 분석)

  • Park, Jung-Ho;Ryu, Nam-Sun;Park, Jae-Beom;Jung, Gyoo-Dong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.9-14
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    • 2019
  • Hydroxy-terminated polybutadiene (HTPB) propellants of solid rocket motors age differently under different storage temperatures. The shelf life of a solid rocket motor depends on the aging ratio of the HTPB propellant; it can be estimated through the viscoelastic properties by an aging test. This study analyzed the initial and natural aging properties during long-term storage. The initial properties were obtained from characterization and accelerated test results. The test results were obtained by analyzing the strain on cylindrical grains when a thermal load was applied.

A Study on the Age Degradation Kinetics of Pole Transformer Oil (주상변압기 절연유의 경년열화반응 속도론에 관한 연구)

  • 남영우
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.1
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    • pp.99-105
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    • 1997
  • In the paper, aging of insulating oil in pole transformer has been studied by performing accelerated thermal aging test. Dissolved gases were extracted by air bubbling method. Concentration of dissolved gases were modified by extraction ratio of each gases in insulating oil. Aging of insulating materials were proceeded by thermal degradation and oxidation reaction. Both of the reactions followed zeroch order kinetics. Formation rate equations for hydrocarbons, carbon oxides, and hydrogen were derived. It was conformed by gas analysis and UV-Visible spectrophotometric method that iron core and copper coil in pole transformer act as catalyst during the aging process.

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전기집진기술의 현황과 장래전망(I)

  • 고명삼;이달우
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.1
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    • pp.24-33
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    • 1997
  • In this paper, aging of insulating oil in pole transformer has been studied by performing accelerated thermal aging test. Dissolved gases were extracted by air bubbling method. Concentration of dissolved gases were modified by extraction ratio of each gases in insulting oil. Aging of insulting materials were proceeded by thermal degradation and oxidation reaction. Both of the reactions followed zeroth order kinetics. Formation rate equations for hydrocarbons, carbon oxides, and hydrogen were derived. It was conformed by gas analysis and UV-visible spectrophotometric method that iron core and copper coil in pole transformer act as catalyst during the aging process.

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Evaluation of Material Properties Considering Thermal Embrittlement for Accelerated aged CF-8M and CF-8A Cast Austenitic Stainless Steel (가속열화된 CF-8M 및 CF-8A 주조 스테인리스강의 열취화 재료물성치 평가)

  • Kim, Cheol;Park, Heung-Bae;Jin, Tae-Eun;Jeong, Ill-Seok
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.118-123
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    • 2004
  • Cast austenitic stainless steel have been widely used for primary coolant piping in light water reactors. This material is subject to thermal embrittlement at reactor operating temperature. CF-8M and CF-8A cast austenitic stainless steel is used for several components, such as primary coolant piping, elbow, pump casing, and valve bodies in light water reactors. Thermal embrittlement results in spinodal decomposition of delta-ferrite leading to decreased fracture toughness. In this study, the specimens were prepared using an accelerated aging method. The measurement of ferrite content, Charpy impact test and J-R test were performed to verify the predicting equation for aged material properties. In case of above 25% ferrite content, predicted result of J-R curve might be non-conservative.

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The Investigation on Thermal Aging Characteristics of Oil-Paper Insulation in Bushing

  • Liao, Rui-jin;Hu, En-de;Yang, Li-jun;Xu, Zuo-ming
    • Journal of Electrical Engineering and Technology
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    • v.10 no.3
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    • pp.1114-1123
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    • 2015
  • Bushing is the key link to connect outer and inner insulating systems and also the essential electric accessory in electric power system, especially in the high voltage engineering (AC 1000kV, DC 800kV). This paper presented the experimental research of thermal aging characteristic of oil-paper insulation used in bushing. A thermally accelerated aging experiment at 90℃ was performed. The bushing models containing five layers of paper were sealed into the aging vessels and further aged for 250 days. Then several important parameters associated with the aging were observed and evaluated. The results showed that the degree of polymerization (DP) of papers gradually decreased. The DP values of outermost layer and middle layer fit well into the second-order kinematic model and first-order kinematic model, respectively. Less deterioration speed of the inter-layer paper than outer layer was confirmed by the variation of DP. Hydrolysis was considered as the main cause to this phenomenon. In addition, the logarithm of the furfural concentrations in insulation oil was found to have good linear relationship with DP of papers. Interestingly, when the aging time is about 250 days and DP is 419, the aging process reaches an inflection point at which the DP approaches the leveling off degree of polymerization (LODP) value. Both tanδ and acid number of oils increased, while surface and volume resistivity of papers decreased. The obtained results demonstrated that thermal aging and moisture absorbed in papers brought great influence to the degradation of insulating paper, leading to rapid decrease of DP and increase of the tanδ. Thus, the bushing should be avoided from damp and real-time monitoring to the variation of tanδ and DP values of paper is an effective way to evaluate the insulation status of bushing.

Effects of Combined Environmental Factors on Mechanical and Thermal Analysis Properties of Graphite/Epoxy Composites (복합적인 환경인자가 탄소섬유강화 복합재의 기계적 및 열분석 특성에 미치는 영향)

  • Lee, Sang-Jin;Lee, Jong-Keun;Yoon, Sung-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.7
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    • pp.1416-1425
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    • 2002
  • In this study, the effects of combined environmental factors on mechanical and thermal analysis properties of graphite/epoxy composites were evaluated by the use of an accelerated aging test. Environmental factors such as temperature, moisture. and ultraviolet were considered. A xenon-arc lamp was utilized for ultraviolet light. and exposure times of up to 3000 hours were applied. Several types of specimens - tensile. bending, and shear specimens those are transverse to the fiber direction, and bending specimens those are parallel to the tiber direction - were used to investigate the effects of environmental factors on mechanical properties of the composites. Also, glass transition temperature, storage shear modulus, loss shear modulus, and tan ${\delta}$ were measured as a function of exposure times through a dynamic mechanical analyzer. In addition. a suitable testing method for determining the effect of environmental factors on mechanical properties is suggested by comparing the results from using two different types of strain measuring sensors. Finally, composite surfaces exposed to environmental factors were examined using a scanning electron microscope.

Effects of Thermal Aging on the Fracture Characteristic in the Dissimilar Welds (CF8M과 SA508 용접재의 열화에 따른 파괴특성 평가)

  • Woo, Seung-Wan;Kwon, Jae-Do;Choi, Sung-Jong;Choi, Young-Hwan
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.72-77
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    • 2004
  • In a primary reactor cooling system(RCS), a dissimilar weld zone exists between cast stainless steel(CF8M) in a pipe and low-alloy steel(SA508 cl.3) in a nozzle. Thermal aging is observed in CF8M as the RCS is exposed for a long period of time to a reactor operating temperature between 290 and $330^{\circ}C$, while no effect is observed in SA508 cl.3. The specimens are prepared by an artificially accelerated aging technique maintained for 300, 1800 and 3600 hrs at $430^{\circ}C$, respectively. The specimens for elastic-plastic fracture toughness tests are prepared one type, which notch is created in the heat affected zone(HAZ) of CF8M. And, the specimens for fatigue crack growth tests are prepared in three classes, which notches are created at the center of deposited zone, the HAZ of CF8M, and the HAZ of SA508 cl.3. From the experiments, the J-integral values with the increase of aging time decrease, and the differences of the fatigue crack growth behaviors are relatively small in the three classes specimens.

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DC Accelerated Aging Characteristics of Dy2O3-Doped ZPCCD-Based Varistors (Dy2O3가 첨가된 ZPCCD계 바리스터의 DC 가속열화 특성)

  • 남춘우;박종아;김명준
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12
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    • pp.1071-1076
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    • 2003
  • The nonlinear properties and their stability of ZPCCD- based varistors, which are composed of ZnO P $r_{6}$ $O_{ll}$ - CoO-C $r_2$ $O_3$-D $y_2$ $O_3$-based ceramics, were investigated in the D $y_2$ $O_3$ content range of 0.0∼2.0 mol%. The incorporation of D $y_2$ $O_3$ greatly affected the nonlinear properties and the best nonlinearity was obtained from 0.5 mol% D $y_2$ $O_3$ with nonlinear exponent of 66.6 and leakage current of 1.2 $\mu$A. Further addition of D $y_2$ $O_3$ deteriorated the nonlinear properties. In stability against DC accelerated aging stress state: 0.95 $V_{1mA}$/15$0^{\circ}C$/24 h, the 0.5 mol% D $y_2$ $O_3$-doped varistor exhibited the highest stability, in which the variation rate of varistor voltage and nonlinear exponent are -1.9% and 10.5%, respectively. The remainder varistors resulted in thermal runaway due to low density of ceramics.s.s.

DC Accelerated Aging Characteristics of Zn-Pr-Co-Cr-La Oxides-Based Varistors with Sintering Temperature (소결온도에 따른 Zn-Pr-Co-Cr-La 산화물계 바리스터의 DC 가속열화 특성)

  • Kim, Myung-Jun;Yoo, Dae-Hoon;Park, Jong-Ah;Nahm, Choon-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.383-386
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    • 2004
  • DC accelerated aging characteristics of Zn-Pr-Co-Cr-La oxides-based varistors were investigated with various sintering temperatures. The varistors sintered at $1240^{\circ}C$ exhibited the highest nonlinearity, with a nonlinear exponent of 79.3 and a leakage current of $0.3\;{\mu}A$, whereas completely degraded because of thermal runaway owing to low sintered density. The varistors sintered at $1250^{\circ}C$ exhibited not only a high nonlinearity with the nonlinear exponent 61.4 and the leakage current 0.7 ${\mu}A$, but also a high stability with the variation rates of varistor voltage and nonlinear exponent are -1.01% and -10.67%, respectively, under DC stress condition such as $(0.85\;V_{1mA}/115^{\circ}C/24\;h)+(0.90\;V_{1mA}/120^{\circ}C/24\;h)+(0.95\;V_{1mA}/125^{\circ}C/24\;h)+(0.95\;V_{1mA}/150^{\circ}C/24\;h)$.

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