• Environmental Engineering Research
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• 제12권2호
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• pp.72-80
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• 2007

Experiments were conducted to identify the emissions from the car air freshener and to identify the formation of ultra-fine particles and secondary gaseous compounds during the ozone-initiated oxidations with emitted VOCs. The identified primary constituents emitted from the car air freshener in this study were $\alpha$-pinene, $\beta$-pinene, $\rho$-cymene and limonene. Formation of ultra-fine particles (4.4-160 nm) was observed when ozone was injected into the chamber containing emitted monoterpenes from the air freshener. Particle number concentrations, particle mass concentrations, and surface concentrations were measured in time dependent experiments to describe the particle formation and growth within the chamber. The irritating secondary gaseous products formed during the ozone-initiated reactions include formaldehyde, acetaldehyde, acrolein, acetone, and propionaldehyde. Ozone concentration (50 and 100 ppb) and temperature (30 and $40^{\circ}C$) significantly affect the formation of particles and gaseous products during the ozone-initiated reactions. The results obtained in this study provided an insight on the potential exposure of particles and irritating secondary products formed during the ozone-initiated reaction to passengers in confined spaces.

• Asian Journal of Atmospheric Environment
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• 제5권1호
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• pp.21-28
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• 2011

Occupational nanomaterial exposure is an important issue in the manufacture of such products. People are also exposed to various nanoparticles in their living environments. In this study, we investigated nanoparticle formation during the reaction of ozone and volatile organic compounds (VOCs) emitted from a commercial air freshener, one of many widely used consumer products, in a $1-m^3$ reaction chamber. The air freshener contained various VOCs, particularly terpenes. A petri dish containing 0.5 mL of the air freshener specimen was placed in the bottom of the chamber, and ozone was continuously injected into the center of the chamber at a flow rate of 4 L/min with an ozone concentration of either 50, 100 or 200 ppb. Each test was conducted over a period of about 4 h. The higher ozone concentrations produced larger secondary nanoparticles at a faster rate. The amount of ozone reacted was highly correlated with the amount of aerosol formation. Ratios of reacted ozone concentration and of formed particle mass concentration for the three injected ozone concentrations of 50, 100 and 200 ppb were similar to one other; 4.6 : 1.9 : 1.0 and 4.7 : 2.2 : 1.0 for ozone and aerosol mass, respectively.

• 대한환경공학회지
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• 제33권3호
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• pp.183-190
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• 2011

소형방출챔버를 이용하여 반응조건(시료량, 온도, 환기횟수)에 따라 방향제에서 방출되는 휘발성 유기화합물의 배출특성을 조사하였다. 시료부하량($1.4{\sim}551.0g/m^2$)에 따라 방향제에서 방출되는 TVOC 방출량은 방출시험 5시간 후 $0.7{\sim}64.4mg/m^2{\cdot}hr$로 나타났다. Limonene, ${\alpha}$-pinene과 linalool 등 방향제에서 방출된 주요 휘발성 유기화합물은 온도와 환기횟수가 클수록 방출량이 증가한 것으로 나타났다. 이들 연구결과는 방향제와 같은 생활용품의 오염물질 방출시험방법 및 방출기준을 정립하기 위한 기초자료로 활용될 것으로 생각된다.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2008년도 추계학술대회 논문집
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• pp.460-461
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• 2008

• Journal of Korean Society for Atmospheric Environment
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• 제23권E2호
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• pp.39-46
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• 2007

In order to present the scientific information of organic emissions from consumer products available, the current study examined the emissions composition for three different types of consumer products being used in Korea in an environmental chamber: air freshener (AF), mosquito repellents (MSQR), and moth repellents (MTHR). Emission rates were evaluated by determining emission rates of the target compound from the selected products using an electropolished stainless steel (SS) test chamber $(40{\times}25{\times}50cm^3)$. A time-dependent empirical relationship developed in this study agreed well with the test results. As same with the emission concentrations, MSQR exhibited the highest emission rate for all target compounds except for limonene and naphthalene. MTHR ($9,200\;{\mu}g\;h^{-1}$) showed the highest emission rate of naphthalene followed by MSQR ($8,300\;{\mu}g\;h^{-1}$). Moreover, the concentrations in residential bedroom conditions for target compounds emitted from three types of consumer products were estimated. This estimation suggests that the uses of consumer products can elevate indoor levels of target compounds. In particular, any types of the consumer products may increase the indoor level of m, p-xylene.

• Environmental Analysis Health and Toxicology
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• 제24권2호
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• pp.137-148
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• 2009

This study quantitatively investigated the emissions of indoor air pollutants associated with the utilization of air fresheners indoors, and evaluated individual exposure to five specified indoor air pollutants, which were chosen on the basis of selection criteria. An electrically-polished stainless steel chamber (50L) was employed to achieve this purpose. Test air fresheners were selected through three steps: first, on the basis of market sales; second, on the basis on a preliminary head-space study; and lastly, on the basis of emissions of toxic compounds (benzene, ethyl benzene, limonene, toluene, and xylene). The empirical mathematical model fitted well with the time-series concentrations in the environmental chamber (in most cases, determination coefficient, $R^2{\gtrsim}$0.9), thereby suggesting that the empirical model was suitable for testing emissions. The concentration equilibrium appeared 180 min after the introduction of sample air fresheners into the chamber. Both the chamber concentrations of emission rates or factors varied greatly according to air freshener type. It is noteworthy that although benzene, ethyl benzene, toluene, and xylene were emitted from all test air fresheners, their exposure levels were not significant enough to result in any significant health risk. However, certain type of air fresheners were observed to emit significant amount of limonene, which is potentially reactive with ozone to generate secondary pollutants with oxidants such as ozone, hydroxyl radicals, and nitrogen oxides. The exposure levels to limonene associated with the utilization of three air fresheners were estimated to be 13 to 175 times higher than that of other air fresheners. This information can help consumers to select low-pollutant-emitting air fresheners.

• 한국환경보건학회지
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• 제44권3호
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• pp.275-282
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• 2018

Objective: Since certain chemicals are widely applied in a variety of consumer products, exposure via simultaneous use of multiple consumer products can put human health at risk. For this reason, use patterns of consumer products are an important factor inhuman health risk assessment. The aim of this study is to investigate co-use patterns of air-fresheners and deodorizers in Korea in order to estimate potential cumulative exposure. Methods: To collect the information on use patterns of air-fresheners and deodorizers, ten air-fresheners and 14 deodorizers were selected. A total of 3,000 participants were recruited and asked through on line questionnaires whether they had simultaneously used the selected air-fresheners and deodorant products in their daily lives. Results: Among the 3,000 participants, 45.6% had used more than two air fresheners and 46.3% used more than two deodorizers. The most common types of air fresheners used concurrently include liquid and candle types for indoor environments, while those of deodorizers were fabric trigger sprays and refrigerator gels. In addition, 73.7% used more than two products without product categories. Fabric trigger sprays were contained in all of the high-ranking product combinations. Conclusions: This study showed that many consumers concurrently used air-fresheners and deodorizers in their daily routines. For accurate exposure assessment, co-use patterns of consumer products should be further investigated.

• 실내환경 및 냄새 학회지
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• 제17권4호
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• pp.315-321
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• 2018

Phthalate is an endocrine disruptor that interferes with homeostasis and developmental regulation. It is highly toxic to the environment and is associated with various diseases of the human body. Using biological samples from 140 adult subjects, to evaluate the influencing factors which are related to contaminant concentration levels, we used correlation analysis and multiple regression analysis. Lastly, in order to analyze the health effects related to exposure to phthalates, we conducted a risk assessment by estimating acceptable daily intake exposure according to the influential factors. When we compared the concentration level according to influential factors, in general, the subjects who had engaged in home remodeling work had higher urinary phthalate metabolite concentrations levels than the subjects who had not engaged in home remodeling work. We can confirm statistically significant differences in DBP metabolites. In addition, we can confirm the concentration appeared higher in the categories such as using air freshener, sofa and foods. Through conducting a risk assessment of DEHP, BBzP, DiBP, and DnBP by using data on phthalate metabolite concentration in urine, it was found that the average concentration of all metabolites did not exceed TDI.

• 한국가스학회지
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• 제18권3호
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• pp.38-43
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• 2014

이 논문은 자동차 실내의 인화성 물질과 전기적인 접촉 불량에 의한 화재사례를 분석하고 연구하는 것이다. 첫 번째 사례는 운전자가 에어컨 냄새 탈취제인 방향제를 사용 후 실내의 크래쉬 패드에 두고 내린 것이 외부의 복사열에 의해 폭발하면서 화재가 발생된 것으로 확인되었다. 두 번째 사례는 운전자가 자동차 실내에 전자기기 등을 사용하면서 전기적인 과부하가 걸려 단락현상에 의해 화재가 발생된 것으로 확인되었다. 세 번째 사례는 자동차 내부의 시트를 따뜻하게 하기 위해 열선을 설치하였다. 초기에 설치하였을 때는 화재의 위험성이 약했으나 5,000km를 운행하면서 이 열선의 내구성이 떨어지면서 순간적으로 전기적인 과부하가 발생되었고, 이 열이 시트에 옮겨 붙으면서 자동차 화재가 발생된 것으로 확인되었다. 네 번째 사례는 뒷좌석에 있던 승객이 담배를 피우던 중 완전히 소화하지 않은 상태로 둔 것이 가연성 종이에 옮겨 붙어 자동차가 전소된 것으로 확인되었다. 따라서, 실내의 인화성 물질이나 전기적인 시스템을 추가로 사용할 때는 화재가능성을 최대한 고려하고 이에 대한 세심한 대책을 강구하여야 한다.

• 한국환경보건학회지
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• 제38권3호
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• pp.204-212
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• 2012

Objectives: The purpose of this study was to determine house dust mite concentrations in living rooms and bedding materials in atopic case-control groups. Methods: Fifty four homes with children suffering atopic diseases as cases and fifty one homes without atopic diseases as controls were selected after diagnosis at three elementary schools in Ulsan City. Dust samples were collected from the living rooms and bedding materials in each home during summer and winter with a vacuum cleaner and analyzed for house dust mites using enzyme-linked immunosorbent assay (ELISA). Environmental factors and family history were surveyed during sampling. Results: Both species of house dust mite Dermatophagoides farina (Der f 1) and Dermatophagoides pteronyssinus (Der p 1) were found in all homes. Derf1 concentrations were much higher than Der P1 concentrations, both in atopic homes (1518.9 vs. 27.0 ng/g. dust, respectively) and non-atopic homes (810.8 vs. 44.3 ng/g. dust, respectively). Der f 1 concentrations were significantly higher in the atopic group than in the non-atopic group (atopic: 1518.9 ng/g.dust, non-atopic: 810.8 ng/g.dust, p = 0.035). However, total house dust mite Der p 1 concentrations were significantly higher in the non-atopic group than in the atopic group (atopic: 27.0 ng/g.dust, non-atopic: 44.3 ng/g.dust, p = 0.035). Multiple regression implied that mothers with family history of atopic diseases (OR = 4.79, 95% CI = 1.81-12.69), Der f 1 concentrations (OR = 1.74, 95% CI = 1.07-2.81), and air freshener use (OR = 4.60, 95% CI = 1.72-12.34) had significant associations with atopic children. Conclusion: House dust mite Der f 1 concentrations were associated with atopic children. This study suggests that parents should reduce house dust mite Der f 1 concentrations through environmental controls.