• 제목/요약/키워드: Al addition

검색결과 2,614건 처리시간 0.03초

금속 Al분말 첨가 Castable 내화물의 특성 (Properties of Castable REfractories Containing Metallic Al Powder)

  • 김효준;김인술;이상완
    • 한국세라믹학회지
    • /
    • 제27권7호
    • /
    • pp.877-882
    • /
    • 1990
  • Effects of metallic Al powder addition on basic and thermal properties of castable refractories were investigated. Generally, low grade prooperties were obtained by metallic Al powder addition with the increase of temperature, comparing with those of non-addition of Al powder. Especially, Al addtion showed severe shrinkage, corrosiion and low strength above 1000$^{\circ}C$. As a result of Al addition, lower strength of and higher corrosion resistance were shown for 2% addition, but it was reversed for above 4% addition. It was found that Al addition was excellent in the explosive spalling test regardless of Al quantity.

  • PDF

TiAl 금속간화헙물의 공식거동에 미치는 합금원소의 영향 (Effects of Alloying Elements on the Pitting Behavior of Ti-Al Intermetallic Compounds)

  • 이호종;최한철
    • 한국표면공학회지
    • /
    • 제31권3호
    • /
    • pp.157-164
    • /
    • 1998
  • Effects of alloying elements on the pitting behavior of Ti-Al intermetalic compounds in the electrolytic soution containing Cl- were investigated through electrochemical tets and corrosion morphologies. Corrosion potential increased in the case of Cr addition to Ti-48%Al, whereas it decreased in the case of Si and B addition. The simultaneous addition of Cr and Si increased passive current density and decrosion corrosion potential. The passive current density of N addtion was higher than that of B addition in H2SO4 solution. With the addition of alloying elements, The pitting resistance decreased in order of TiAl>TiAlSi>TiAlN>TiAlB>TiAlCr and whin siumultaneous addition, it decreased in order of TiAlCrSi>TiAlCrBN>TiAlCrrN. The surface merohology after pitting test showed that the TiAl coataining Si had for fewer pits than that containing Cr and N simultaneously.

  • PDF

비정질 Nd-Fe-C 자석에 미치는 Al 첨가의 영향 (The effect on small Al addition of the melt-spun Nd-Fe-C magnent)

  • 조대형
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제10권10호
    • /
    • pp.995-999
    • /
    • 1997
  • For melt-spun Fe-Nd-C alloy variation of phase development and magnetic properties with the variety of small Al addition was investigated. As the amount of Al addition increased the amorphization of Fe$_{14}$/Nd$_{2}$/C or $\alpha$-Fe was retarded and the residual Fe$_{14}$/Nd$_{2}$/C or $\alpha$-Fe did not eliminated after heat treatment resulting in poor coercivities of the ribbons. The grain size of Fe$_{14}$/Nd$_{2}$/C increased with the increase of Al addition and the abnormal grain was often found out in the ribbon heat treated for more then 10 min. The enhancement of coercivity was the highest with the addition of 0.5at%Al. As the amount of Al addition increase the coercivities dropped rapidly. The highest coercivity obtained so far is 13.9kOe which about 16% higher than that(11.2kOe) obtained from the Al-free specimen.

  • PDF

과공정 Al-Si 합금의 마모 특성에 미치는 잔류응력의 영향에 관한 연구 (A Study on the Relationship between Residual Stress and Wear Peroperty in Hypereutectic Al-Si Alloys)

  • 김헌주;김창규
    • 한국주조공학회지
    • /
    • 제20권2호
    • /
    • pp.89-96
    • /
    • 2000
  • The effects of modification processing on the refinement of primary Si and the wear behavior of hyper-eutectic Al-Si alloys have been mainly investigated. Refining effects of primary Si in Al-17%Si alloy was more efficient than that of B.390 alloy. Optimum condition of getting the finest primary Si microstructure was when AlCuP modifier is added into the melt at $750^{\circ}C$ and held it at $700^{\circ}C$ for 30 minutes. Wear loss in the specimens of as-cast condition decreases as the size of primary Si decreases, in the order of B.390 alloy, B.390 alloy with AlCuP addition, Al-17%Si alloy and Al-17%Si alloy with AlCuP addition. Wear loss in the aged condition of Al-17%Si alloy, B.390 alloy and B.390 alloy with AlCuP addition decreased due to the increase of compressive residual stress in the matrix by the aging treatment. While, wear loss increased in the aged specimens of Al-17%Si alloy with AlCuP addition and Hepworth addition in which compressive residual stress decreases by the aging treatment. Therefore, it is assumed that higher compressive residual stress in the matrix can reduce the wear loss in composite materials such as hyper-eutectic Al-Si alloys.

  • PDF

Zn-0.18Al 도금욕에서 Ni첨가에 따른 아연 도금강의 계면반응 (Interfacial Reaction of Galvanized Steel in Ni Added Zn-0.18Al Bath)

  • 이경구;기회봉;이도재
    • 한국표면공학회지
    • /
    • 제32권4호
    • /
    • pp.547-554
    • /
    • 1999
  • The interfacial reaction, spangle and coating thickness of galvanized steel in Ni added Zn-0.18Al bath have been investigated. The size of spangle and thickness of reaction layer were observed under an optical microscope, SEM and EDS. Analysing the experimental results concerning spangle size of galvanized steel it was found that Ni addition in Zn-0.18Al bath tended to be minimized spangle size. For Zn-0.18Al bath, addition of 0.1Ni suppressed the formation of Fe-Zn intermetallic compounds but increased with Ni content above 0.1%. The coating thickness of galvanized steel was reduced with Ni addition in Zn-0.18Al bath, especially in Zn-0.18Al-0.05Ni bath. Addition of Al in Ni containing bath resulted in forming the Al-Ni intermetallic compounds such as $Al_3$Ni$_2$ and $Al_2$Ni which consist most of top precipitates.

  • PDF

Enhancement of Porosity and Strength of Porous Al2O3 Ceramics by Al(H2PO4)3 Addition

  • Bai, Jiahai;Piao, Jiasi;Gao, Jie;He, Jing;Du, Qingyang;Li, Chengfeng
    • 한국세라믹학회지
    • /
    • 제56권4호
    • /
    • pp.350-353
    • /
    • 2019
  • Porous alumina ceramics with addition of 0, 5, 10, 15, and 20 wt% Al(H2PO4)3 were sintered at 1300, 1350, and 1400℃. The effects of the Al(H2PO4)3 addition on crystal phases, water absorption, open porosity, pore size distribution, microstructures, and flexural strength were studied extensively. The experimental results revealed that only characteristic peaks of corundum were indexed in the XRD patterns of the as-prepared porous ceramics. The water absorption and open porosity of the porous Al2O3 ceramics increased remarkably with an increase in Al(H2PO4)3 addition. The flexural strength first increased to a maximum value when 5 wt% Al(H2PO4)3 was added and then decreased as additional Al(H2PO4)3 was further added. SEM images showed that the average Al2O3 grain size in the porous ceramics changed in an opposite way as the flexural strength. The porous Al2O3 ceramics with 10 wt% Al(H2PO4)3 addition exhibited comparable flexural strength to the ceramics without Al(H2PO4)3 addition, although the latter had much higher porosity.

Ti-B 첨가(添加)에 의한 Al 의 응고조직(凝固組織)에 관(關)한 연구(硏究) (The Effects of Ti-B Addition on the Unidirectional Solidification of Al)

  • 성연수;이계완
    • 한국주조공학회지
    • /
    • 제7권4호
    • /
    • pp.358-365
    • /
    • 1987
  • To investigate the grain refining mechanism of Al by the addition of Ti-B, the unidirectional solidifications of 99.9%Al and 99.7%Al were performed under the condition of varing the pouring temperature. The solidification modes of Al were studied by the cooling curve analyses, metallographic and microprobe examinations. The results were as follows: 1) Grains were most refined with an addition of 0.15wt.%Ti-0.021wt.%B but the grain size with 0.2wt.%Ti-0.028wt.%B was increased. 2) The grain size of 99.7wt.%Al was even more refined than that of 99.9wt.%Al with the same amount of Ti-B. 3) As the pouring temperature increased, the grain size of pure Al and an alloy with 0.lwt.%Ti-0.014wt.%B was increased. However, an alloy with 0.2wt.%Ti-0.028wt.%B did not show any effects of temperature. 4) TiC(Al-Ti) and (Al-Ti-C) were identified as nucleants for Al.

  • PDF

Effect of Al2O3 Addition and WO3 Modification on Catalytic Activity of NiO/Al2O3-TiO2/WO3 for Ethylene Dimerization

  • Pae, Young-Il;Sohn, Jong-Rack
    • Bulletin of the Korean Chemical Society
    • /
    • 제28권10호
    • /
    • pp.1763-1770
    • /
    • 2007
  • Strong solid acid catalysts, NiO/Al2O3-TiO2/WO3 for ethylene dimerization were prepared by the addition of Al2O3 and the modification with WO3. The acid sites and acid strength were increased by the inductive effect of WO3 species bonded to the surface of catalysts. The larger the dispersed WO3 amount, the higher both the acidity and catalytic activity for ethylene dimerization. The addition of Al2O3 to TiO2 up to 5 mol% enhanced acidity and catalytic activity gradually due to the interaction between Al2O3 and TiO2 and consequent formation of Al-O-Ti bond.

Fe-38 at.% Al계 금속간화합물의 표면특성에 미치는 합금원소의 영향 (Effects of Alloying Elements on the Surface Characteristics of Fe-38Al Intermetallic Compounds)

  • 최한철
    • 한국표면공학회지
    • /
    • 제37권2호
    • /
    • pp.128-136
    • /
    • 2004
  • Effects of alloying elements on the surface characteristics of Fe-38Al intermetallic compounds were investigated using potentiostat. The specimens were casted by the vacuum arc melting. The subsequent homogenization and the stabilization led to the homogeneous DO$_3$ structure of the specimen. After the corrosion tests, the surface of the tested specimen was observed by the optical microscopy and scanning electron microscopy(SEM). For Fe-38 at.% Al intermetallic compound, the addition of Cr and Mo proved to be beneficial in decreasing the grain boundary attack by decreasing the active current density. Addition of Band Nb resulted in a higher active current density and also a higher passive current density. These results indicated the role of Cr and Mo in improving the pitting corrosion resistance of Fe-38 at.%Al intermetallic compound. Band Nb addition to Fe-38 at.%Al accelerated the granular corrosion. Fe-38 at.%Al containing Cr and Mo showed remarkably improved pitting corrosion resistance in comparison with Band Nb addition to Fe-38 at. %Al.

Sc 첨가된 Al-Zn-Mg-(Cu)계 알루미늄 합금 압출재의 시효 경화 거동과 기계적 성질 (Age Hardening and Mechanical Property of Extruded Al-Zn-Mg-(Cu) Al Alloys with Sc addition)

  • 심성용;임수근
    • 열처리공학회지
    • /
    • 제20권5호
    • /
    • pp.243-249
    • /
    • 2007
  • The age hardening behavior and mechanical properties of an extruded Al-Zn-Mg-(Cu)-0.1 wt.%Sc alloy were investigated with the Sc addition and ageing temperature. The results showed that the $Al_3Sc$ compounds were formed by Sc addition and distributed preferentially along the extrusion direction. The age hardening of Al-Zn-Mg-Cu-0.1 wt.%Sc alloy which was treated by T6 process was more significant than that of Al-Zn-Mg-0.1 wt.%Sc alloy. The tensile property of Al-Zn-Mg-Cu+0.1 wt.%Sc alloy was also higher than that of Al-Zn-Mg-0.1 wt.%Sc alloy, which is 691 MPa and 584 MPa in strength and 9% and 11% in elongation, respectively.