• Title/Summary/Keyword: Alkali activated

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Microstructural Characteristics of Alkali-Activated Cements Incorporating Fly Ash and Slag (플라이애시와 슬래그 혼합 알칼리 활성 시멘트의 미세구조 특성)

  • Jang, Jeong Gook
    • Journal of Urban Science
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    • v.7 no.1
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    • pp.39-43
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    • 2018
  • This study investigates microstructural characteristics of alkali-activated cements incorporating slag and fly ash. Samples were prepared with four fly ash:slag ratios, i.e., 100:0, 90:10, 70:30 and 50:50, and they were synthesized by using an alkali activator. Microstructural characteristics of the alkali-activated cements were determined by XRD, TGA, SEM, N2 gas adsorption/desorption methods, and compressive strength test. The results showed that properties of alkali-activated fly ash/slag were significantly affected by slag contents. Alkali-activated fly ash/slag with slag content of 30-50% showed higher compressive strength than ordinary Portland cement paste. An increase in slag content resulted in a denser microstructure, which composed of amorphous gel, therefore contributed to strength development of the material.

Porosity of Alkali-Activated Slag-Red Mud Soil Mixed Pavement of Red Mud Substitution Rate (알칼리활성화 슬래그-레드머드 흙포장재의 레드머드 대체율에 따른 기공특성)

  • Kang, Hye Ju;Kim, Byeong gi;Kim, Jae Hwan;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.91-92
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    • 2016
  • Red mud is an inorganic by-product produced from the mineral processing of alumina from Bauxite ores. the development of alkali-activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. This study is to investigate the pore characteristics of alkali-activated slag-red mud soil pavement according to the red mud content. The results showed that the porosity of alkali-activated slag-red mud soil pavement increased but the compressive strength of that decreased as the red mud content increased.

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A Preliminary Study on Alkali Activation of Waste Concrete Powder

  • Sasui, Sasui;Kim, Gyu-Yong;Eu, Ha-Min;Lee, Yae-Chan;Phyeon, Su-Jeong;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.303-304
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    • 2023
  • In this study, the effects of NaOH and KOH alkali activators of various concentrations on the performance of alkali activated waste concrete powder (WCP) was discussed. The samples activated by alkaline solutions were cured for up to 28 days and then compressive strength test was performed. These samples were also characterized using various techniques to explore the phase evolution, and microstructural changes. Results showed superior performance of NaOH-activated WCP. Additionally, activation of WCP by 8M concentrated alkali solutions improved the strength, reactivity and microstructure of alkali activated WCP binder sample.

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Efflorescence Characteristics of Alkali-Activated Slag-Red Mud Soil Mixed Pavement of Red Mud Substitution Rate (알칼리활성화 슬래그-레드머드 흙포장재의 레드머드 대체율에 따른 백화 특성)

  • Kang, Hye Ju;Lee, Yeong;Oh, Du Yeon;Lee, Gyu Yeong;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.153-154
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    • 2015
  • This study is alkali-activated slag-red mud soil mixed pavement of efflorescence characteristics analysis of mitigation measures is drawn to the red mud substitution rate in accordance with the alkali-activated slag-red mud soil mixed pavement of efflorescence characteristics were exhibited. As a result of alkali-activated slag-red mud soil mixed pavement is more substitution rate increases appeared to efflorescence is increased.

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Resistance of Alkali Activated Slag Cement Mortar to Sulfuric Acid Attack (알칼리 활성화 슬래그 시멘트 모르타르의 내황산성)

  • Min, Kyung-San;Lee, Seung-Heun
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.633-638
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    • 2007
  • The setting time of alkali activated slag cement tends to be much faster than ordinary Portland cement, and its compressive strength had been higher from the 1 day but became lower than that of the cement on the 28 days. According to the results of the surface observation, weight loss, compressed strength, and erosion depth tests on the sulphuric acid solution. It has been drawn that alkali activated slag cement has a higher sulphate resistance than ordinary Portland cement, and in particular, the alkali activated slag cement added 5 wt% alumina cement has little deterioration on the sulphuric acid solution. The reason why the alkali activated slag cement has higher sulphate resistance than other hardened cement pastes is that it has no $Ca(OH)_2$ reactive to sulphate ion, and there is little $CaSO_4{\cdot}2H_2O$ production causing volume expansion, unlike other pastes. And it is supposed that $Al(OH)_3$ hydrates with high sulphate resistance, which is produced by adding the alumina cement increases the sulfate resistance.

Estimation of Strength and Pore Structure of Alkali-Activated Fire Protection Materials at High Temperature (고온에서의 알칼리 활성화 내화성 결합재의 강도 및 공극구조 평가)

  • Song, Hun;Kim, Young-Ho;Kim, Wan-Ki;So, Hyung-Suk
    • Journal of The Korean Digital Architecture Interior Association
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    • v.12 no.4
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    • pp.59-66
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    • 2012
  • This study is interested in identifying the effectiveness of alkali-activated fire protection material compounds including the alkali-activator such as potassium hydroxide, sodium silicate and fly ash as the fire resistant finishing materials. Also, this paper is concerned with change in compressive strength and pore structure of the alkali-activated fire protection material at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. This study results show that compressive strength is rapidly degraded depending on a rise of heating temperature. Porosity showed a tendency to increase irrespective of specimen types. This is due to both the outbreak of collapse of gel comprising the cement and a micro crack by heating. However, alkali-activated fire protection material composed of potassium hydroxide, sodium silicate and fly ash has the thermal stability of the slight decrease of compressive strength and porosity at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate.

Hydration Mechanism of Alkali Activated Slag Cement

  • Jong Cheol Kim;Keun Ho Auh;Sung Yun Hong
    • The Korean Journal of Ceramics
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    • v.5 no.1
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    • pp.35-39
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    • 1999
  • For many years, alkali activated blast furnace slag cement containing no ordinary portland cement has received much attention in the view of energy saving and its many excellent properties. We examined the structural change of slag glass which was activated by alkali metal compounds using IR spectroscopy. The properties of hydrated products and unhydrated slag grains was characterized by XRD and micro-conduction calorimeter. Ion concentration change in the liquid during the hydration of blast furnace slag was also studied to investigated the hydration mechanism.

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Properties of Alkali-activated Slag-Red Mud Soil Pavement Using Recycled Aggregate (순환골재를 사용한 알칼리활성화 슬래그-레드머드 흙포장재의 특성)

  • Kang, Suk-Pyo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.276-283
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    • 2016
  • Red mud is an inorganic by-product produced from the mineral processing of alumina from Bauxite ores. the development of alkali-activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. This study is to investigate the optimum water content, compressive strength, moisture absorption coefficient and efflorescence of alkali-activated slag-red mud soil pavement according to the recycling fine aggregate content. The results showed that the optimum water content, moisture absorption coefficient and efflorescence area of alkali-activated slag-red mud soil pavement increased but the compressive strength of that decreased as the recycled fine aggregate content increased.

An Experimental Study on the Properties of Drying Shrinkage for Alkali-Activated Slag Mortar (알칼리 자극제를 혼입한 고로슬래그 모르타르의 건조수축 특성에 관한 실험적 연구)

  • Chun Jung-Hwan;Kim Jae-Hun;Jee Nam-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.97-100
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    • 2006
  • This paper report the result of the investigation on the properties of drying shrinkage for alkali-activated slag mortar in different relative humidity Commonly we know that drying shrinkage means lost more moisture but the mechanism of drying shrinkage of alkali activated slag mortar is not entirely due to the quantity of weight loss of water from mortar. pore size distribution and the calcium silicate hydrate gel characteristics have a critical influence on the magnitude of drying shringkage to alkali activated slag mortar. For this investigation, Ca(OH)2, Na2SiO4 were as alkali activator with 5 dosages(6%, 9%, 12%, 15%, 20%) and curing condition were three different relative humidity(35%, 65%, 95%) at $20{\pm}3^{\circ}C$

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Fundamental Properties of Alkali Activated Slag Mortar with Different Activator Type (자극제의 종류에 따른 알칼리 활성화 슬래그 모르타르의 기초 특성)

  • An, Yang-Jin;Mun, Kyoung-Ju;Soh, Seung-Young;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.789-792
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    • 2006
  • The purpose of this study is to investigation the fundamental properties of alkali activated slag of type and concentration of alkali activator. In this paper sodium silicate, sodium carbonate and sodium hydroxide were used as alkaline activator and their concentration were 1, 3, 5 and 7 $Na_2O$ weight percent. The physical properties of alkali activated blast furnace slag cement mortar (AAS) were investigated by flow test and compressive strength. And the hydration properties of AAS characterized by X-ray diffraction and scanning electron microscope. Result show that Alkali activated slag mortar strengths were continuously increased with adding amount and ages. C-S-H were formed to be the main products up to 28days of hydration.

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