• Journal of the Korean Ceramic Society
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• v.32 no.2
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• pp.217-226
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• 1995

Alumina powders were dispersed using crosslinkable organic molecules by electrosteric stabilization and then consolidated by crosslinking of organic molecules. The effect of processing variables such as the physicochemical properties of both solvent media and organic molecules, the proportions of mixed organic media, etc. were studied. FT-IR was used todeduce the mechanism of organic molecules adsorption on the alumina particle surfaces. The adsorption characteristics and the electrokinetic behavior of alumina suspensions were correlated with the stability of particle in alumina suspension using rheological measurements. The green body of alumina consolidated by the chemical crosslinking of the adsorbed organic molecules after the alumina suspension had been stabilized was tough enough for green machining and the sintered alumina fabricated by this proposed process also showed a high bending strength and a homogeneous microstructure.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.4
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• pp.297-302
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• 2009

We have successfully fabricated the alumina thick films using inkjet printing processes without a high temperature sintering process. Alumina suspension as dielectric ink was formulated by combining nano-sized alumina powders with an anionic polymer dispersant in formamide/water as co-solvent. The thickness of the printed alumina thick film was measured at around 5 um by field emission scanning electron microscope. The calculated packing density of 68.5 % from the printed alumina thick film was much higher than the same films fabricated by conventional casting or dip coating processes. Q factor of the dielectrics thick film infiltrated with cyanate ester resin was evaluated by impedance analyzer.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.4
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• pp.390-395
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• 2004

In order to analyze the physical and chemical characteristics of home production porcelain insulators by change of the alumina addition amount, 360001bs ball socket type suspension insulators which were manufactured in 1989, 1995 and 2001 removed in transmission line and an experiment was performed. By the result, 8 wt.％ alumina that influences the mechanical properties and arc resistance properties in case of insulators that were manufactured in 1989 was contained, and the relative density and the fracture toughness of insulators appeared by 94.2％ and 1.4 ㎫$.$ $M^{\frac{1}{2}}$, respectively. However, 12 wt.％ alumina was contained in case of insulators that were manufactured in 1995, and the relative density and the fracture toughness of insulators appeared preferably lower by 92％ and 1.3㎫$.$ $M^{\frac{1}{2}}$, respectively. Amount of alumina was contained most by 17 wt.％ in case of insulators that were manufactured in 2001. It was confirmed that the electrical and mechanical characteristics such as the relative density and the fracture toughness appeared excellently by 96％ and 1.7㎫$.$ $m^{\frac{1}{2}}$, respectively.

• Journal of the Korean Ceramic Society
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• v.33 no.2
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• pp.163-168
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• 1996

Measurements of proton adsorption density have been conducted in preparing alumina suspensions with aqueous solutions of HCL, HNO3, H2SO4 and H3PO4 And effects of anion acid concentration proton adsorption density and solid loading on the viscosity of the alumina suspensions have been investigated. Aqueous solutions of HCl. or HNO3 were suitable for the preparation of highly concentrated suspensions as the generation of surface charge on alumina particles was depressed by the specific adsorption of {{{{ {SO }`_{4 } ^{2- } }} and {{{{ { PO}`_{4 } ^{3- } }} Optimum conditions for maximizing solid loading were dependent upon proton adsorption density and acid concentration.

• Transactions on Electrical and Electronic Materials
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• v.18 no.4
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• pp.207-210
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• 2017

The suspension arrangement of insulators provides flexibility and assists in power transmission in transmission lines. The performance of the insulator string is strongly influenced by the environmental conditions to which it is exposed, its shape and the inherent material properties of suspension-type insulators. The suspension-type insulators are mostly made from glass, porcelain and ceramic material due to their high resistivity. Irregularity in charge distribution throughout the porcelain insulator may lead to accelerated aging and electrical breakdown. A very high and steep lightning impulse voltage may also cause breakdown of suspension-type insulators. We investigated various material characteristics such as alumina addition, surface morphology, x-ray diffraction pattern and relative density of suspension porcelain insulators manufactured in 1989 (36,000 lbs.), 1995 (36,000 lbs.) and 2001 (36,000 lbs.) by the KRI Company for use in 154 kV high power transmission lines. We compared the material characteristics of these porcelain insulators with that of the top-of-the-line porcelain insulators (36,000 lbs.) manufactured by the NGK Company in 2000. These suspension-type porcelain insulators were exposed to arc and flashover tests to examine their electrical and mechanical strength. It was noted that alumina addition (17 wt.%) for K-2001 was one of the major contributors to the enhancement of the performance of the porcelain insulators and to their ability to withstand very high current generation during the arc test. The porcelain insulators manufactured during 2001 also showed the highest relative density of 95.8% as compared to the other insulators manufactured in 1989 and 1995 respectively 94.2% and 91.5%. We also discuss reports of various failure modes of suspension-type porcelain insulators.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.05b
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• pp.146-149
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• 2004

In order to analyze the physical and chemical characteristics of the home production porcelain insulators by change of the alumina addition amount, 36000lbs ball socket type suspension insulators which were manufactured in 1989, 1995 and 2001 removed in transmission line and an experiment was performed. By the result, 8 wt.% alumina that influences the mechanical properties and arc resistance properties in case of insulators that were manufactured in 1989 was contained. Amount of alumina was contained most by 17 wt.% in case of insulators that were manufactured in 2001.

• Journal of the Korean Ceramic Society
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• v.51 no.6
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• pp.560-565
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• 2014

Alumina nano-asperites were grown on plate-like alumina particles of which the surface had been covered with a capping agent to control the asperite formation sites on the particles. Utilized alumina source for asperite was nano sized ${\gamma}$-alumina, which was prepared by calcination of $Al(OH)_3$ at $600^{\circ}C$; silica suspension was used as the capping agent. Plate like alumina particles were covered by silica suspension and continuously heat-treated to $900^{\circ}C$ with nano sized ${\gamma}$-alumina, as the source material, under molten-salt atmosphere. Asperite growing site were controlled by the degree of coating of the capping agent; 10-20 nanosize of ${\theta}$-alumina were formed on the particle surface. On the other hand, alumina particles without capping agent were observed to undergo only step-like crystal growth during heat-treatment.

• Journal of the Korean Ceramic Society
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• v.40 no.7
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• pp.632-636
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• 2003

To prepare the alumina cement free vibrated alumina castable, $\rho$-alumina is employed as a binder material, and nano-sized clay is added to enhance the curing strength and give thixotropic behavior. The rheological behavior of matrix of castable is controlled by investigating the influences of ultrafines, $\rho$-alumina, and nano-sized clay on the viscosity of matrix. The microsilica and ultrafine alumina were added 3 wt% and 4 wt%, respectively to the matrix, which showed that the viscosities tends to be lowest values. The rheological property of the matrix is well established by adding $\rho$-alumina as 8 wt% and clay as 4 wt%. The thixotropic behavior of the $\rho$-alumina bonded castable was appeared by introducing nano-sized clay into the matrix and adjusting the pH near to the PZC of the clay suspension.

• Journal of the Korean Ceramic Society
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• v.39 no.11
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• pp.1011-1016
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• 2002

Colloidal particles of silica (100 nm in size) were electrostatically dispersed and adsorbed on a glass substrate coated with silica sol or alumina sol. Stability of the suspensions and microstructure of the adsorbed particle layers were discussed in terms of total potential energies between the particles and the substrate. Well-dispersed suspension resulted in a layer with densely packed and regularly arranged particles, whereas less stable suspension resulted in a porous layer with loosely packed and irregularly arranged particles. Despite repulsive interactions between the particles and the substrate coated with silica sol, the observed adsorption can be attributed to chemical bonds formed at the interface between the particle and silica sol. In contrast, the adsorption of the particles on the substrate coated with alumina sol formed a layer with strongly adhered and densely packed particles, due to large attractive interactions between the particles and alumina sol.

• Journal of the Korean Ceramic Society
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• v.41 no.9
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• pp.647-652
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• 2004

In aqueous tape casting of alumina slurry systems, the relationships between the suspension compositions and the defects of the dried tapes were discussed. The suspensions compositions were controlled with the ratios of the solids, water and organics binder contents. The effects of the thickness of dried tape and kinds of binder system were also examined. In the defect free region, the apparent viscosity showed nearly same value due to the count balancing effect of solid and organic binder content on the apparent viscosity. When water content was constant, increasing solid led to decrease of organic binder content. The defect free region was narrowed with increasing of casting thickness. When linear type acrylic emulsion binders system (D1000 and D 1035) were used, defect free zone formed the belt type in the triangle of solid, water and organic binder content according to the line of constant water contents. However the defect free region was not found in the cross-link type emulsion binder system (D 1050).