• Journal of Ocean Engineering and Technology
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• v.14 no.2
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• pp.106-111
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• 2000

Recently it was reported that the life of Al Sacrifical anode is being used in port piers has been significantly shortened compared with the original design life (e.g. average life shortened from 20 years to 13-15 year) Those factors involving these problems mentioned above were seemed to be a quality of anode material and diverse environmental factors such as pH flow rate temperature Dissolved oxygen Chemical oxygen demand and resistivity etcm In this study flow rate and contamination degree(pH) of sea water affecting to sacrificial anode life hve been investigated in terms of electrochemical characteristics of Al alloy sacrificial anode It was known that the lifetime of Al alloy anode was shortened not only by increasing of self-corrosion quantity by varying flow rate of sea water but also by increasing corrosion current density due to the potential difference increment between Al anode and steel structure cathode by varying contamination degree of sea water. Especially when anode current density is from 1mA/cm2 to 3mA/cm2 and flow rate of sea water is under 2m/s anode current efficiency is 90% above However flow rate is over 2m/s anode current efficiency fell down sharply due to erosion corrosion as well as galvanic corrosion.

• Proceedings of the KAIS Fall Conference
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• 2004.11a
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• pp.99-102
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• 2004

Display process has adopted RCA clean, being applied to large area and coped with environmental issue for last ten years. However, the approaching concept of ozonized, hydrogenised, or electrolyzed water cleaning technologies is within RCA clean paradigm. In this work, only electrolyzed anode water was applied to clean particles and organics as well as metals based on Pourbaix concept, and as a test vehicle, MgO particles were introduced to prove the new concept. The electrolyzed anode water is very oxidative with high oxidation reduction potential(ORP) and low in pH of more than 900mV and 3.1, respectively. MgO particles were immerged in the anode water and its weight losses due to dissolution were measured with time. Weight losses were in the ranges of 100 to 500 micrograms in 250m1 anode waters depending on their ORP and pH. Therefore it was concluded that the cleaning radicals in the anode water was at least in the range of 1 to 5E20 ea per 250 ml anode water equivalent to IE18 ea/cm3. Hence it can be assumed that the anode water be applied to display cleaning since 1E10 to IE15 ea/cm3 ranges of contaminants are being treated. In addition, it was observed that anode water does not develop micro-roughness on hydrophobic surface while it does on the native silicon oxide.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.2
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• pp.155-162
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• 2016

A proton exchange membrane fuel cell (PEMFC) produces only water at cathode by an electrochemical reaction between hydrogen and oxygen. The generated water is transported across the membrane from the cathode to the anode. The transported water collected in water-trap and drained to the cathode within the humidifier outlet. If the condensate water is not being drained at the appropriate time, condensate water in the anode can cause the performance degradation or fuel efficiency degradation of fuel cell by the anode flooding or unnecessary hydrogen discharge. In this study, we proposed an optimization method of condensate water drain logic for the water drain performance and the water drain algorithm as considered the condensate water generating speed prep emergency case. In conclusion, we developed the water management strategy of fuel processing system (FPS) as securing fuel efficiency and operating stability.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.6 no.1
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• pp.78-82
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• 2005

Display manufacturing process has adopted RCA cleaning, applying to larger area and coping with environmental issue for last ten years. However, the approaching concept of ozonized, hydrogenised, or electrolyzed water cleaning technologies is within RCA clean paradigm. In this work, only electrolyzed anode water was applied to clean particles and organics as well as metals based on Pourbaix concept, and as a test vehicle, MgO particles were introduced to prove the new concept. The electrolyzed anode water is very oxidative with high oxidation reduction potential (ORP) and low in pH of more than 900 mV and 3.1, respectively. MgO particles were immersed in the anode water and its weight losses due to dissolution were measured with time. Weight losses were in the ranges of 100 to 500 micrograms in 250 ml anode water depending on their ORP and pH. Therefore it was concluded that the cleaning radicals in the anode water was at least in the range of 1 to $5{\times}10^{20}$ ea per 250 ml anode water equivalent to $1{\times}10^{18} ea/cm^2$. Hence it can be assumed that the anode water applied to display cleaning from now on $1{\times}10^{10}$ to $1{\times}10^{15} ea/cm^2$ ranges of contaminants are being treated. In addition, it was observed that anode water did not develop micro-roughness on hydrophobic surface while it did on the native silicon oxide.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.34 no.1
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• pp.37-42
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• 1998

Al alloy anode is mostly used for protecting marine structures such as pier steel piles and ship's body. Recently it has been reported that the life of Al alloy anode has been shortened significantly than the original design life. It is suggested that the suspected reasons for this problem mentioned above seems to be the improper protection design of alloy of anode on sea water regardless of environmental facotrs such as flow rate, temperature, contamination degree etc. However there is few paper about to the sea water contamination degree affecting to the life of Al alloy anode. In this study, the property of Al alloy anode was investigated as a parameter of sea water contamination degree such as variation of pH 2, 4, 6, 8, 10 and each sea port's contaminated waters.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.04b
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• pp.1-5
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• 2000

As the semiconductor devices are miniaturized, the number of the unit cleaning processes increases. In order to processes by conventional RCA cleaning process, the consumption of volume of liquid chemical and DI water became huge. Therefore, the problem of environmental issues are evolved by the increased consumption of chemicals. To resolve this matter, an advanced cleaning process by Electrolyzed Water was studied in this work. The electrolyzed water was made by an electrolysis equipment which was composed of three chambers of anode, cathode, and middle chambers. In the case of electrolyzed water with electrolytes in the middle chamber, oxidatively acidic water of anode and reductively alkaline water of cathode were obtained. The oxidation/reduction potentials and pH of anode water and cathode water were measured to be +l000mV and 4.8, and -530mV and 6.3, respectively. The Si-wafers contaminated with metallic impurities were cleaning with the electrolyzed water. To analysis the amounts of metallic impurities on Si-water surfaces, ICP-MS(Inductively Coupled Plasma-Mass spectrometer) was introduced. From results of ICP-MS measurements, it was concluded that the ability of electrolyzed water was equivalent to that of the conventional RCA cleaning.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.4
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• pp.349-355
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• 2018

This study interrogated multi-layer heterojunction anodes were interrogated for potential applications to water treatment. The multi-layer anodes with outer layers of $SnO_2/Bi_2O_3$ and/or $TiO_2/Bi_2O_3$ onto $IrO_2/Ta_2O_5$ electrodes were prepared by thermal decomposition and characterized in terms of reactive chlorine species (RCS) generation in 50 mM NaCl solutions. The $IrO_2/Ta_2O_5$ layer on Ti substrate (Anode 1) primarily served as an electron shuttle. The current efficiency (CE) and energy efficiency (EE) for RCS generation were significantly enhanced by the further coating of $SnO_2/Bi_2O_3$ (Anode 2) and $TiO_2/Bi_2O_3$ (Anode 3) layers onto the Anode 1, despite moderate losses in electrical conductivity and active surface area. The CE of the Anode 3 was found to show the highest RCS generation rate, whereas the multi-junction architecture (Anode 4, sequential coating of $IrO_2/Ta_2O_5$, $SnO_2/Bi_2O_3$, and $TiO_2/Bi_2O_3$) showed marginal improvement. The microscopic observations indicated that the outer $TiO_2/Bi_2O_3$ could form a crack-free layer by an incorporation of anatase $TiO_2$ particles, potentially increasing the service life of the anode. The results of this study are expected to broaden the usage of dimensionally stable anodes in water treatment with an enhanced RCS generation and lifetime.

• Corrosion Science and Technology
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• v.11 no.4
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• pp.112-119
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• 2012

This paper presents the results of a study of the effectiveness of cathodic protection with insoluble ICCP anode in reinforced concrete structures. Experimental tests were carried out on reinforced concrete specimens with 3 different commercial anodes for ICCP system in order to compare the effectiveness of cathodic protection. Results have shown that the kinds of anode for ICCP is irrelevant to the effectiveness of cathodic protection, In case of ICCP, the performance of cathodic protection has no relationship to the kinds of anode especially in concrete specimens with sea water condition. It has been found slightly more effective at Ti-Rod anode in fresh water condition and Ti-Mesh anode in atmospheric condition.

• Corrosion Science and Technology
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• v.6 no.3
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• pp.90-95
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• 2007

Cathodic protection technology has been widely used on ship's outer hull and inner side of ballast water tanks as a supplementary corrosion protection measure in combination with protective organic coatings. Impressed current cathodic protection system is typically opted for the ship's hull and, sacrificial anode system, for ballast water tanks. The anticipation and interest in cathodic protection system for ships has been surprisingly low-eyed to date in comparison with protective coatings. Computational analysis for the verification of cathodic protection design has been tried sometimes for offshore marine structures, however, in commercial shipbuilding section, decades old design practice is still applied, and no systematic or analytical verification work has been done for that. In this respect, over-rotection from un-erified initial design protocol has been also concerned by several experts. Especially, it was frequently reported in sacrificial anode system that even after full design life time, anode was remaining nearly intact. Another issue for impressed current system, for example, is that the anode shield area design for ship's outer hull should be compromised with actual application situation, because the state-of-the-art design equation is quite impractical from the applicator's stand. Besides that, in this study, some other critical design issues for sacrificial anode and impressed current cathodic protection system were discussed.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2000.05a
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• pp.115-121
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• 2000

As the development of industry water quality of river is going to bad because of waste water of an industrial complex and general home agricultural chemicals exhaust of $SO_3$ and CO gas acid rain and so on. Corrosion damage of boiler factory equipment and so forth occur quickly due to using of the polluted water resulting in increasing leak accident. Especially working life of hot water boiler using the polluted water becomes more short and energy loss increases. The cathodic protection method is the most economical and reliable one to prevent corrosion damage of steel structures. Mg-base alloys galvanic anode protection of cathodic protection method is suitable for than application of hot water boiler using water with high specific resistance such as tap water. This paper is studied on the cathodic protection characteristics of how water boiler. In tap water and 0.001mol/$\ell$ NaCl solution the characteristics of anodic polarization of Mg-base alloys galvanic anode and tube material is investigated the measurement of cathodic protection potential according to the time elaspsed is carried out.