• Title/Summary/Keyword: Arachidic acid

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Deposition Transfer and Electrical Properties of Arachidic acid and Stearic acid (Arachidic acid와 Stearic acid의 누적전이와 전기특성)

  • 최영일;송진원;이경섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.764-767
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    • 2001
  • Because using LB method, result that produce Arachidic acid and Stearic acid LB film and measure the accumulation characteristic and electrical characteristic is as following. Organic monolayers of surface of the water compression each 9 layer's LB film to slide glass and manufactured MIM device compressing molecular film only. Could confirm that accumulation was good seeing as absorption coefficient and SEM picture, AFM picture that prevent manufactured LB films. Formation of domain of coexistence form that prevent LB film is indefinite and distinction of border side was not clear, and could know that roughness appears greatly. Obtained current by applied voltage could know that is proportional almost, though Arachidic acid appeared as bulk of current that happen in equaler certification voltage than Stearic acid is less, this alkyl chain longer Arachidic acid that serving relations special quality is superior know can .

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$\pi$-A Characteristics of Arachidic Acid Monolayer (Arachidic Acid 단분자막의 $\pi$-A 특성)

  • 이대일;최용성;장상묵;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1991.10a
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    • pp.10-11
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    • 1991
  • In this paper, Arachidic Acid of long-chain fatty acid was soluted by chloroform and observed $\pi$-A curve in trough. In our experimental result, optimum pressure for fabricating the LB film was 30mN/m. In $\pi$-A curve measurment, temperature dependence was investigated between 20-50($^{\circ}C$). However, in this temperature range, the variation of solid phase pressure was not observed.

Electrical properties and deposited films of Arachidic Acid (Arachidic Acid의 누독막(累讀膜)과 전기적특성(電氣的特性))

  • Cho, S.Y.;Chun, D.K.;Lee, K.S.;Lee, W.S.;Chung, H.S.
    • Proceedings of the KIEE Conference
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    • 1996.11a
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    • pp.215-217
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    • 1996
  • We have examined the electrical properties of arachidic acid Langmuir(L)films by using a displacement-current-measuring technique with pressure stimulation, displacement current peak appeared at a area per molecule around $90{\AA}^2$, possibly due to the orientational change in hydrophobic part of arachidic acid molecules. The displacement current is the transient current, it is generated when charged particles existing in single monolayers are displaced with the external stimulation. In this report, we mainly describe the displacement current generation from arichidic acid monolayers with pressure stimulation.

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Self-Assembled and Langmuir-Blodgett Arachidic Acid Monolayers on Silver: A Comparative Reflection-Absorption Fourier Transform Infrared Spectroscopic Study

  • Ahn, Sang-Jung;Mirzakhojaev, Diyas A.;Son, Dong-Hee;Kim, Kwan
    • Bulletin of the Korean Chemical Society
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    • v.15 no.5
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    • pp.369-374
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    • 1994
  • Self-assembled (SA) and Langmuir-Blodgett (LB) monolayers of arachidic acid on silver surfaces have been investigated by a reflection-absorption Fourier transform infrared spectroscopy. Arachidic acid was adsorbed on silver as carboxylate with its two oxygen atoms bound symmetrically to the surface. Although both the SA and LB monolayers consisted of fully extended trans zigzag carbon chains, a closer examination indicated that the SA monotayers should possess a more ordered crystalline structure than the LB monolayers. The infrared spectral data dictated that the extent of methyl group exposure at the air-film interface was greater in the SA monolayers than the LB monolayers, in agreement with the contact angle measurement. From a theoretical analysis, the alkyl chains in each monolayers seemed to be tilted away from the surface normal by less than $3.5^{\circ}$, but in opposite directions. Arachidic acid monolayers were concluded to have same structure as stearic acid monolayers.

Study on Morphology and Current-Voltage (I-V) property of Arachidic acid LB film (Arachidic acid LB 막의 표면 이미지와 I-V 특성 연구)

  • Ryu, Kil-Yong;Lee, Nam-Suk;Park, Sang-Hun;Park, Jae-Chul;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.05a
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    • pp.61-62
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    • 2006
  • 본 연구에서는 대표적인 양친매성분자인 Arachidic acid를 이용하여 박막을 제작하였으며, 층수 변화에 따른 표면이미지와 전압-전류 특성을 측정하였다. Arachidic acid 는 포화지방산으로 ($CH_3(CH_2)_{18}$ COOH)의 구조를 가지며, 크기가 $27.5{\AA}$으로 $CH_3(CH_2)_{18}$의 소수기와 COOH의 친수기로 구성되어 있어, Langmuir-Blodgett (LB) Trough을 사용하여 박막제작과 분자제어가 쉽다. Chloroform을 용매로 하여 2 mmol/l의 농도를 조성하여 ${\pi}$-A 등온선을 통해 기체 상태, 액체 상태, 고체 상태를 관찰하였다. LB 막의 제작 및 평가에서 막의 안정성은 ${\pi}$-A 곡선, AFM(Atomic force microscopy) 등을 통하여 확인하였다. 또한 LB 막을 Metal/유기물 LB막/Metal 구조의 소자로 제작하여 전압-전류 특성을 측정하였다.

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Investigation the frequency change in number of layers and fabrication morphology of Arachidic Acid LB Films (Arachidic Acid LB박막의 누적층수에 따른 주파수 변화와 모폴로지 특성)

  • Yang, Chang-Heon;Choi, Won-Suk;Lee, Nam-Suk;Chang, Jeong-Soo;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1371-1372
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    • 2007
  • In this study, in order to confirm the application possibility to the molecular electronic device, morphlogical property of the Arachidic acid was investigated. We have investigated morphology by BAM image and AFM. ${\pi}$-A curves investigated surface pressure of this LB film from liquid to solid state ranged between 40 to 45 mN/m. BAM images investigated the different states of Arachidic Acid LB film. When the surface pressure reaches at 40 mN/m, the monolayer was deposited onto the hydrophilic glass substrates by Y-type deposition. We also investigated the frequency characteristics of LB modified glass by QCM. We investigated morphology of arachidic acid by AFM. As a result, we obtained the frequency characteristic and morphology of LB films from controlling the deposited layers.

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Study on Morphology and Current-Voltage (I-V) property of Arachidic acid Thin film by LB method (LB법을 이용한 Arachidic acid 박막의 표면이미지와 I-V특성 연구)

  • Ryu, Kil-Yong;Lee, Nam-Suk;Park, Sang-Hun;Park, Jae-Chul;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.394-395
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    • 2006
  • 본 연구에서는 Arachidic acid Langmuir-Blodgett (LB) 막의 표면이미지와 전압-전류 특성을 측정하였다. Arachidic acid는 포화지방산으로 ($CH3(CH_2)_{18}$ COOH)의 구조를 가지며, 크기가 $27.5\;{\AA}$으로 $CH_3(CH_2)_{18}$의 소수기와 COOH의 친수기로 구성되어 있어, LB Trough를 사용하여 박막제작과 분자제어가 쉽다. Chloroform을 용매로 하여 2mmol/l의 농도를 조성하여 ${\pi}$-A 등온선을 통해 기체 상태, 액체 상태, 고체 상태를 관찰하였다. LB막의 제작 및 평가에서 막의 안정성은 ${\pi}$-A곡선, AFM (Atomic force microscopy) 등을 통하여 확인 하였다. 또한 LB 막을 Metal/LB막/Metal 구조의 소자로 제작하여 전압-전류 특성을 측정하였다.

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Study on air-water interface phenomenon and electrical property of Arachidic acid LB films (LB법을 이용한 Arachidic acid LB막의 공기-물 계면현상과 전기적특성 연구)

  • Ryu, Kil-Yong;Lee, Nam-Suk;Park, Jae-Chul;Choi, Yong-Sung;Lee, Kyung-Sub;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.263-264
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    • 2006
  • 본 연구에서는 Arachidic acid Langmuir-Blodgett (LB)막의 계면특성과 전기적 특성을 측정하였다. Arachidic aicd는 포화지방산으로 ($CH_3(CH_2)_{18}COOH$)의 구조를 가지며, 크기가 27.5[$\AA$]으로 $CH_3(CH_2)_{18}$의 소수기와 COOH의 친수기로 구성되어 있다. LB막은 박막제작시 배열과 배향의 제어가 용이하다. Chloroform을 용매로 하여 2[mmol/l]의 농도를 조성하여 ${\pi}-A$ 등온선을 통해 기체 상태, 액체 상태, 고체 상태를 관찰하였으며 편광각 현미경 (Brewster angle microscopy) 이미지를 통해 각 상태에서의 이미지를 관찰하였다. 또한 LB막의 제작시 사용되어진 ITO 기판은 친수처리 전 후의 접촉각의 측정을 통하여 막의 안정성을 확인하였다. 또한 LB막을 Metal/LB막/Metal 구조의 소자로 제작하여 전압-전류 특성을 측정하였다.

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The Current Measurement by Electrode Distance of Organic Monolayers (유기단분자막의 전극거리에 따른 전류 측정)

  • 이경섭;전동규;오재한;강용철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.169-172
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    • 1998
  • We have investigates a surface pressure, a displacement current and a charge measurement by distance of between electrode 1 and water surface of organic monolayers. And the displacement current was generated during compression of Arachidic acid mono1ayers at a air-water interface. The result from our work show that the displacement current of a Langmuir(L) film for Arachidic acid monolayers has the different maximum points according to the electrode distance. We are known that the displacement current and a charge was generated in inverse proportion to electrode distance d.

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