• Journal of Environmental Science International
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• v.15 no.2
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• pp.121-131
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• 2006

Atmospheric bulk (wet and dry) samples were monthly collected in Masan and Heangam areas of Korea, to assess the deposition flux and seasonal variation of polycyclic aromatic hydrocarbons (PAHs). Deposition fluxes of PAHs in bulk samples were determined using gas chromatography coupled to mass spectrometer detector (GC/MSD). Particle deposition fluxes from Masan and Haengam areas varied from 13 to $87\;g/m^2/year$ and from 5 to $52\;g/m^2/year$, respectively. PAHs deposition fluxes in atmospheric bulk samples in Masan and Haengam areas ranged from 135 to $464\;{\mu}g/m^2/year$ and from 62.2 to $194\;{\mu}g/m^2/year$, respectively. Atmospheric deposition fluxes of particles and PAHs in this study were comparable to or slightly lower values than those from different locations in Korea and other countries. PAHs profiles of atmospheric deposition bulk samples showed slightly different from two sampling areas, however the predominant species of PAHs were similar. Indeno (1,2,3-c,d)pyrene, benzo(g,h,i)perylene, phenanthrene compounds were the most detected PAHs in deposition bulk samples. Carcinogenic PAHs occupied the contribution of approximately $30-40\%$ of the total PAHs deposition fluxes. The non-metric multi-dimensional scaling (MDS) was used, to assess the differentiation of PAHs source between two sampling areas. The result suggests that PAHs contamination sources were different according to the location and season surveyed. There was no an apparent relationship between the PAHs deposition flux against temperature and rainfall amount, even though summer season with the highest temperature and the largest amount of precipitation showed the lowest PAHs deposition flux. Benzo(e)pyrene/benzo(a)pyrene ratio indicated that the photo-degradation process was one of important factors to the seasonal variation of PAHs with the lower deposition fluxes.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.5
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• pp.465-478
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• 1998

In this study, seasonal variations of the dry deposition velocity and deposition flux for the sulfur dioxide were analysed. The field observation was performed during one year (from November 1, 1995 to October 31, 1996) in Chunchon basin. The turbulence data were measured by 3-dimensional sonic anemometer/thermometer, and were estimated by mean meteorological data obtained at two heights (2.5 m and 10 m) of meteorological tower. Also, the estimation methods were evaluated by comparing the turbulence data. The results showed that the estimated dry deposition velocity and turbulence parameter such as uc and sensible heat flux using mean meteorological data were relatively similar to the sonic measurements, but all showed somewhat large differences. The dry deposition velocity was large in summer and small in winter mainly due to canopy resistance (rc). The major factor which affects diurnal variation of the velocity was aerodynamic resistance (rw). The SO2 dry deposition flux was large in winter and small in summer in Chunchon.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.6
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• pp.657-666
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• 2005

The objectives of this study were to investigate atmospheric dry deposition of inorganic nitrogen-containing compounds to waterbody. Target waterbody is Juam reservoir functioning as one of the major water supply sources in Chollanamdo. Nitrate and ammonium dry deposition fluxes were directly measured using dry deposition plate (DDP) covered with greased strips and a water surface sampler (WSS). The daytime average $NO_{3}^{-}\;and\;NH_{4}^{+}$ fluxes measured with DDP and WSS were $1.7\∼2.6$ times higher than those at nighttime. The seasonal average flux of $NH_{4}^{+}$ showed the highest value in summer. The daytime and nighttime average dry deposition fluxes of particulate phase Nitogen-containing Compounds ($1.13,\;0.80\;mg/m^{2}$ day) were much higher than those of gas phase compounds ($0.50,\;0.24\;mg/m^{2}$ day).

• Journal of Korean Society for Atmospheric Environment
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• v.17 no.1
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• pp.19-29
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• 2001

Atmospheric concentrations of acidic pollutant were measured by the 4 stage filter pak method at Chunchon and by the 3 stage filter pack method at Seoul and Anmyon-do from January to December 1998. The sample was collected for 24 hours on every Wednesday. Concentrations of particulate matters were highest at Anmyon-do. The particulate concentration was much higher during the warm season than other seasons. While the particulate concentration was higher during the warm season, the concentration of gaseous matter was higher in winter. Dry deposition flux was calculated by using reported deposition velocities and concentration of pollutants measured in this study. The dry deposition velocities used in this study for SO$_2$, SO$_{4}^{2}$, HNO$_3$,NO$_{3}^{-}$ and NH$_3$ were 0.29, 0.15, 2.08( 2.13 only for Anmyon-do), 0.20 and 1.00cm/sec, respectively. At Chunchon, annual sulfur flux originated from dry deposition was 384 kg/$textrm{km}^2$, and the flux from wet deposition was 782kg/$textrm{km}^2$. Dry deposition of sulfur was 33% of total sulfur deposition. The annual nitrogen flux originated from dry deposition was 1,892kg/$textrm{km}^2$. And the flux from wet deposition was 1,066kg/$textrm{km}^2$. Dry deposition of nitrogen was 64% of total nitrogen deposition. Dry deposition as well as wet deposition have to be considerd in the study on acidification of environment such as soil or watershed.

• Journal of Environmental Science International
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• v.13 no.5
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• pp.469-478
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• 2004

Atmospheric bulk (wet and dry) samples were monthly collected in an urban environment (Daeyeon-dong) of Busan over a year, to assess the deposition flux and seasonality of dioxin-like polychlorinated biphenyls (DLPCBs) using stainless steel pots. Deposition fluxes of DLPCBs in bulk samples were determined using high resolution gas chromatography coupled to high resolution mass spectrometry (HRGC/HRMS). Particle deposition fluxes in the urban environment varied from 23 to 98 $mg^2$/year (mean 41 $gm^2$/year). DLPCB deposition fluxes in atmospheric bulk samples ranged from 0.09 to 0.77 ng-$TEQ/m^2$/year (mean 0.35 ng-$TEQ/m^2$/year). Seasonal atmospheric deposition fluxes of DLPCBs were high in winter and low in summer. Atmospheric deposition fluxes of particles and DLPCBs in this study were comparable to or slightly lower values than those of different locations in the world. Monthly DLPCB profiles in deposition bulk samples were similar over a year. Non-ortho PCBs were higher contributions to the total DLPCBs fluxes than mono-ortho PCBs. In particular, PCB 126 had the highest concentrartion (>75%) in all deposition samples, followed by PCB 169 and PCB 156. A highly positive correlation was found among the deposition fluxes of DLPCB species, suggesting the possibility of that the DLPCB contamination originated from one source. The deposition fluxes of DLPCBs were not significantly correlated with temperature and the amount of precipitation even though the summer season with the highest temperature and the largest amount of precipitation showed the lowest DLPCB deposition flux.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.5
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• pp.445-451
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• 2000

To estimate dry deposition flux of 12 elements in aerosols, aerosol particles were sampled by a low-pressure impactor(LPI) and a dust jar. The concentrations of 12 elements in aerosol particle and dry deposition were analyzed by a PIXE analysis using as a 2.0 MeV-proton beam. The mean dry deposition velocities of 12 elements were estimated by ranges of 0.74∼2.62 cm/sec. The results showed that the highest value was 3.26 cm/sec for Ca and the lowest value 0.74 cm/sec for Fe. The dry deposition flux for elements was calculated as a function of particle size by 1-step method and 12-step method. In this work, dry deposition velocities were computed with the two existing models; the coarse-particle fraction(4∼30 mm diameter) using the dry deposition velocity model of the Noll and Fang(1998) and the fine-particle fraction (0.05∼4mm diameter) using the Shemel and Hodgson(1980) model. The ratios of the mean calculated/measured fluxes were 3.59 for 1-step method and 0.60 for 12-step method respectively.

• Journal of Environmental Impact Assessment
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• v.7 no.2
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• pp.127-133
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• 1998

The atmospheric deposition flux was measured with dustfall from July of 1997 to July of 1998 at nine sampling sites located in Tae-an peninsula to examine the seasonal variations. The results showed that the average dry deposition was higher in spring than the other seasons. Thus, it is considered that yellow sand is one major source of the additional deposition flux in spring. There also appeared the higher measurement of deposition at the sites nearby road (like Hagampo, Bangali and Sinduri) in summer, and it is assumed that the heavy traffic caused by summer visitors was the main factor of that. For more accurate study, the qualitiative analysis should be taken on the deposited materials.

• Journal of Environmental Science International
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• v.10 no.1
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• pp.1-8
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• 2001

This study was carried out estimating the dry deposition flux of $SO_2$at eight urban areas in Korea during one year of 1996. To calculate the deposition flux, deposition velocities were calculated by turbulence parameters estimated from routine meteorological data. Also, hourly averaged $SO_2$concentrations which calculated from air pollution monitoring data of each city were used. The dry deposition velocities were mostly higher in the coastal areas than the other areas, which would be caused by relatively strong wind. And, they were high in the daytime because of turbulence activities. The deposition flux of $SO_2$is mainly related to the atmospheric concentration. The annual average $SO_2$concentration and the deposition flux were 22.62ppb and 1510.52g/$\textrm{km}^2$/hr at Pusan respectively. Also, the flux was higher in winter than other season, which was a significant contribution of exhausted fuel for heating. While the deposition velocity was high to 0.688cm/sec at Yosu in case of strong wind and small cloud cover, the deposition flux was high to 1597.4g/$\textrm{km}^2$/hr at Pusan in case of weak wind and small cloud cover.

• Journal of Environmental Health Sciences
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• v.29 no.4
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• pp.10-16
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• 2003

Atmospheric samples were conducted from September 2001 to July 2002 with GPS-l PUF sampler in rural site to concentration distributions of gas/particle PCBs and to calculate dry deposition flux of PCBs. $\Sigma$PCBs concentrations of gas/particle PCBs were 59.29$\pm$48.83, 6.56$\pm$6.59 pg/㎥, respectively. Gas contribution (%) of total PCBs (gas + particle) was 90% which existed gas phase in the atmosphere. The particle contribution (%) of PCB congeners increased relatively more of the less volatile congeners with the highest chlorine number. The correlation coefficients (r) between total PCBs and temperature ($^{\circ}C$) showed negative correlation in - 0.62 (p<0.0l) for particle phase, positive correlation in 0.63 (p<0.01) for gas phase. In other word, particle phase PCBs is enriched in colder weather which could be due to greater in corporation of condensed gas phase at low temperature. The calculated dry deposition of total PCBs (gas + particle) was 0.008, 0.008 $\mu\textrm{g}$ $m^{-2}$ da $y^{-l}$ which showed maximum dry deposition flux in December, minimum data in July Bs in the atmosphere. The calculated dry deposition fluxes of total PCBs were influenced by particle phase PCBs even though PCBs in the atmosphere were present primarily in the gas phase.e.

• Journal of Environmental Impact Assessment
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• v.8 no.2
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• pp.31-44
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• 1999

Atmospheric dry deposition flux and ambient particle mass size distribution were measured to evaluate the impact of atmospheric deposition around the Nanjido landfill sites. Wind direction affects greatly on the variation of mass flux and mass size distribution and made two times higher when the wind was blown from the road side. The effect of Nanjido landfill on the mass size distribution was significant comparing to simultaneously measured mass size distribution at the other sampling site. The results showed that the particle diameter bigger than $10{\mu}m$ explained the majority of atmospheric dry deposition flux. A survey was also carried out to investigate the contamination of soils in a completed Nanjido landfill. The chemical properties of the soil analyzed in the present study include pH, oxidation-reduction potential (ORP), anion and cation concentration, total organic carbon(TOC), and some-metal elements concentrations were analyzed. Microbial activity in the soils was also evaluated by measuring dehydrogenase activities. TOC in the soil contaminated with leachate was $467.0{\mu}g/g-dry$ soil, and the TOC in the soil, where Nanjido landfill gases were emitted from, was $675{\mu}g/g-dry$ soil. The highest microbial activity of $968.0{\sim}2147{\mu}g-TPF/g-dry$ soil day was found in the soil spouting Nanjido landfill gases. Compared with those in the uncontaminated soil, the concentrations of Cr, Cu and Ph in the contaminated soil were higher.