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Radon Concentration in Groundwater of Korea (전국 규모로 본 국내 지하수의 라돈 함량)

  • Cho, Byong-Wook
    • The Journal of Engineering Geology
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    • v.28 no.4
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    • pp.661-672
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    • 2018
  • Radon concentration was measured in a total of 5,453 groundwater samples from wells across Korea. The radon concentrations showed the values ranging from 0.1 Bq/L to 7,218.7 Bq/L, with a median of 48.8 Bq/L which is lower than those of other countries having similar geological conditions. The distribution of radon concentrations was lognormal. The median value is high in the granite areas (63.5-105.1 Bq/L) while it is low in the sedimentary rocks and Cheju volcanic area (16.0-20.3 Bq/L). When grouping the groundwater with well depth, the median radon value is high in weathering and/or upper bedrock zone (61.4 Bq/L) while it is low in alluvium and/or weathering zone (28.5 Bq/L). About 17.7% of the total samples exceeded 148 Bq/L of USEPA guideline value. The exceeding radon ratio more than 148 Bq/L in groundwater is highest in Jurassic granite area, however, the exceeding radon rates more than 300 Bq/L and 500 Bq/L are highest in CGRA area.

A Survey of Indoor and Outdoor Radon Concentrations in Five Major Cities (주요 5개 도시의 실내외 라돈농도 조사연구)

  • ;;;Takao lida
    • Journal of environmental and Sanitary engineering
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    • v.17 no.3
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    • pp.75-82
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    • 2002
  • This outline survey of indoor and outdoor radon concentrations in five major cities in Korea was carried out with Electrostatic Integrating Radon Monitor(EIRM) from February to December, 1996 and January to december, 1998. The mean indoor and outdoor radon concentrations in five major cities in 1996 were $21.9{\;}Bq/\textrm{m}^3$ and $9.6{\;}Bq/\textrm{m}^3$, respectively. The mean indoor and outdoor radon concentrations in 1998 were $20.8{\;}Bq/\textrm{m}^3$ and $9.0{\;}Bq/\textrm{m}^3$, respectively. These were below the U.S.EPA radon action level. The range of indoor to outdoor radon concentrations were $0.8{\;}Bq/\textrm{m}^3{\;}~{\;}45.6{\;}Bq/\textrm{m}^3$ in 1996, $0.5{\;}Bq/\textrm{m}^3{\;}~{\;}15.2{\;}Bq/\textrm{m}^3$ in 1998, respectively. The result of our analysis showed that radon concentrations in indoor air were clearly higher than those in outdoor air. Inspection of seasonal distribute pattern indicates the enhancement during winter relative to summer.

Performance Evaluation of Biofuel cell using Benzoquinone Entrapped Polyethyleneimine-Carbon nanotube supporter Based Enzymatic Catalyst (벤조퀴논 포집 폴리에틸렌이민-탄소나노튜브 지지체 기반 효소촉매의 바이오연료전지로서의 성능평가)

  • Ahn, Yeonjoo;Chung, Yongjin;Kwon, Yongchai
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.258-263
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    • 2017
  • In this study, we synthesized biocatalyst consisting of glucose oxidase (GOx), polyethyleneimine (PEI) and carbon nanotube (CNT) with addition of p-benzoquinone (BQ) that was considered anodic catalysts of enzymatic biofuel cell (EBC). For doing this, PEI/CNT supporter was bonded with BQ by physical entrapping method stemmed from electrostatic attractive force ([BQ/PEI]/CNT). In turn, GOx moiety was further immobilized on the [BQ/PEI]/CNT to form GOx/[BQ/PEI]/CNT catalyst. This catalyst has a special advantage in that the BQ that has been usually dissolved into electrolyte was immobilized on supporter. According to the electrochemical analysis, maximum current density of the GOx/[BQ/PEI]/CNT catalyst was 1.9 fold better than that of the catalyst that did not entrap BQ with the value of $34.16{\mu}A/cm^2$, verifying that catalytic activity of the catalyst was enhanced by adoption of BQ. Also, when it was used as anodic catalyst of the EBC, its maximum power density was 1.2 fold better than that of EBC using the catalyst that did not entrap BQ with the value of $0.91mW/cm^2$. Based on such results, it turned out that the GOx/[BQ/PEI]/CNT catalyst was promising and viable as anodic catalyst of EBC.

A Study of the Prediction of Earthquake Occurrence by Detecting Radon Radioactivity (라돈방사능농도의 측정을 통한 지진발생 예측에 관한 연구)

  • ;;;Takao Lida;Katsuhiro Yoshioka
    • Journal of Environmental Science International
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    • v.12 no.6
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    • pp.677-688
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    • 2003
  • The purpose of this study was to predict occurrence of earthquakes in Korea by measuring the concentration of radon radioactivity in the air and in the underground water. Two monitoring systems of radon concentration detection in the air were installed in Seoul, East Coast area, whereas of radon concentration in the underground water in Kyungju area during December, 1999 to June, 2001. The distribution of radon concentration in the air in Seoul is as follows Winter(10.10 $\pm$ 2.81 Bq/㎥), autumn(8.41 $\pm$ 1.35 Bq/㎥), summer(5.83 $\pm$ 0.05 Bq/㎥) and spring (5.34 $\pm$ 0.44 Bq/㎥), whereas the distribution of radon in the air in the East Coast area showed some difference as follows : autumn (14.08 $\pm$ 5.75 Bq/㎥), Summer (12.04 $\pm$ 0.53 Bq/㎥), Winter (12.02 $\pm$ 1.40 Bq/㎥) and spring (8.93 $\pm$ 0.91 Bq/㎥). In the meanwhile, the distribution of radon in the water is as follows : spring (123.59 $\pm$ 16.36count/10min), Winter (93.95 $\pm$ 79.69counter/10min), autumn (68.96 $\pm$ 37.53counter/10min) and spring (34.45 $\pm$ 9.69counter/10min). The daily range of the density of radon concentration in Seoul and East Coast area was between 5.51 Bq/㎥ - 9.44 Bq/㎥, 7.15 Bq/㎥ - 15.27 Bq/㎥, respectively. Correlation of the distributions of radon concentrations in the air and in underground water with earthquake showed considerable variations of radon concentration before the occurrence of the earthquake. The results suggested that radon radioactivity seemed to be helpful for the prediction of the occurrence of earthquake.

Simultaneous Separation and Determination of $^{l4}C\;and\;^3H$ in Spent Resins from PWR Nuclear Power Plants (가압경수로형 원전에서 발생된 폐수지의 $^{14}C$$^3H$ 동시 분리 및 측정)

  • Park, Soon-Dal;Kim, Jung-Suck;Kim, Jong-Goo;Han, Sun-Ho;Jee, Kwang-Yong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.3
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    • pp.179-188
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    • 2007
  • In this work $^{14}C\;and\;^3H$ distribution characteristics of spent resins from nuclear power plants(NPPs), pressurized water reactors(PWRs), was investigated. It was found that the recovery percent of $^{14}C$ by the wet oxidation-acid stripping was $81%{\sim}100%$ for the added activity range of $^{14}C,\;0.72\;Bq{\sim}460\;Bq$, and it was not affected by the kinds of stripping acids, 3N-HCl, $3\;N-HNO_3\;and\;3\;N-H_2SO_4$. And the recovery percent of $^3H$ by distillation using the same apparatus was $81%{\sim}101%$ for the added activity range of $^3H,\;0.60\;Bq{\sim}435\;Bq$. Among the tested stripping acids, 3\;N-HCl, $3\;N-HNO_3\;and\;3\;N-H_2SO_4$, only the trapped $^3H$ solution by distillation in $3\;N-H_2SO_4$ was compatible with the 3H scintillator, Ultimagold XR. Neither of the $^{14}C\;and\;^3H$ trapping solutions from the spent ion exchange resin samples by the wet oxidation-3 $N-H_2SO_4$ stripping contained gamma nuclides. However, some gamma nuclides, $^{60}Co,\;^{134}Cs,\;^{137}Cs\;and\;^{54}Mn$, were found in the trapped $^3H$ solutions of the spent resins by the wet oxidation-3 N-HCl stripping. It was the same for the $^3H$ trapping solutions of the spent resins by Sample Oxidizer(PACKARD MODEL 307). Meanwhile only two nuclides, $^{134}Cs,\;and\;^{134}Cs$, were found in the $^{14}C$ trapping solutions of the spent resins by Sample Oxidizer(PACKARD MODEL 307). It was found that most of the $^{14}C$ in the spent resins existed as inorganic carbon form, more than about 70% of the total $^{14}C$ content. Among the analyzed 30 spent ion exchange resin samples, the average concentration of $^{14}C$ and $^3C$ for the high radioactive samples, 8 samples, was $19000\;Bq/g{\pm}41000\;Bq/g,\;670\;Bq/g{\pm}460\;Bq/g$ and that for the low radioactive samples, 22 samples, was $4.2\;Bq/g{\pm}4.3\;Bq/g,\;6.0\;Bq/g{\pm}5.3\;Bq/g$, respectively. And the average $^{14}C/^3H$ ratio for the high radioactive samples, was higher, 28, than that of low radioactive samples, 0.70. Some linear relationship trend was found between the activity concentrations of $^{14}C\;and\;^3H$.

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[ 137Cs] and 40K Activities of Foodstuffs Consumed in Jeju (제주지역에서 소비되는 식품 중 137Cs과 40K 방사능 농도)

  • Kang, Tae-Woo;Hong, Kyung-Ae;Park, Won-Pyo;U., Zang-Kual
    • Korean Journal of Environmental Agriculture
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    • v.23 no.1
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    • pp.52-58
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    • 2004
  • This work was conducted to provide the reference data of radioactivity in the foodstuffs at a radiological emergency situation in Jeju Island The sampled foodstuffs were agricultural (31), livestock (6), marine (12) and forest products (4), and processed foods (3) consumed by Jeju Islanders. $^{137}Cs$ and $^{40}K$ activities were determined by HPGe r-ray spectromety. The activity ranges of $^{137}Cs$ was ${\sim}650\;mBq/kg$ fresh in the agricultural products, ${\sim}131\;mBq/kg$. fresh in the livestock, ${\sim}834\;mBq/kg$ fresh in the forest, ${\sim}253\;mBq/kg$ fresh in the marine and $32.0{\sim}483\;mBq/kg$. fresh in the processed foods (tea). In case of $^{40}K$ the activity was $16.6{\sim}542\;Bq/kg$. fresh in the agricultural products, $39.1{\sim}294\;Bq/kg$ fresh in the livestock, $85.5{\sim}116\;Bq/kg$ fresh in the forest, $50.1{\sim}657\;Bq/kg$ fresh in the marine, and $33.6{\sim}1,065\;Bq/kg$ fresh in the processed foods (tea). The highest activity of $^{137}Cs$, 834mBq/kg fresh was observed in oak mushroom and $^{40}K$ 1,065 Bq/kg fresh in coffee. Annual effective doses of $^{137}Cs$ and $^{40}K$ by intake of foodstuffs per capita were the following order; agricultural products (66,543 nSv) > livestock products (19,311 nSv) > processed foods (6,648 nSv) > marine products (6,579 nSv) > forest products (860 nSv). Therefore, total annual effective dose was summed 99,941 nSv which is quite low level comparing to the annual effective dose by external exposure, 2,400,000 nSv. The data obtained in this study can be useful for monitoring whether the foodstuffs are contaminated or not at an emergency radiation accident, and showed that the foodstuffs consumed in Jeju are safe in terms of annual effective dose of $^{137}Cs$ and $^{40}K$

The Study of Radon and Uranium Distribution in the Groundwater at Regional Difference of Daejeon (대전지역별 지하수중의 우라늄, 라돈 농도준위 분포조사 연구)

  • Yoon, Yoon-Yeol;Cho, Soo-Young;Lee, Kil-Yong;Kim, Yong-Je
    • Journal of Radiation Protection and Research
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    • v.31 no.1
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    • pp.25-30
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    • 2006
  • To know radon and uranium concentration variations in groundwater with regional difference, groundwaters were sampled at five different Daejeon area. Seventy-five samples were analyzed and forty samples were collected twice at drying and after raining season to know surface water effect. The average radon and uranium concentration of five areas are $270.9{\pm}152.3\;Bq/L,\;43.8{\pm}23.5\;{\mu}g/L$ at Yusung-gu, $112.9{\pm}65.8\;Bq/L,\;0.45{\pm}0.23\;{\mu}g/L$ at Seo-gu, $41.3{\pm}24.0\;Bq/L,\;4.9{\pm}11.3\;{\mu}g/L$ at Dong-gu, $131.8{\pm}99.5\;Bq/L,\;54.3{\pm}127.5\;{\mu}g/L$ at Daeduk-gu and $44.0{\pm}43.0\;Bq/L,\;8.1{\pm}11.6\;{\mu}g/L$ at Jung-gu. The mean concentrations of analyzed samples to know surface water effect were ranged from 0.5 to 640 ${\mu}g/L$ for uranium and from 0.4 to 729 Bq/L for radon. The average concentration of radon and uranium after raining season were lower than those of drying season. The mean contents of radon End Uranium at drying season were $253{\pm}14\;Bq/L,\;63{\pm}12.2\;{\mu}g/L$, and $195{\pm}11\;Bq/L,\;45.4{\pm}11.7\;{\mu}g/L$ after raining season.

Analysis of Air Discharge and Disused Air Filters in Radioisotope Production Facility

  • Kim, Sung Ho;Lee, Bu Hyung;Kwon, Soo Il;Kim, Jae Seok;Kim, Gi-sub;Park, Min Seok;Jung, Haijo
    • Progress in Medical Physics
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    • v.27 no.3
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    • pp.156-161
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    • 2016
  • When air discharged from a radioisotope production facility is contaminated with radiation, the public may be exposed to radiation. The objective of this study is to manage such radiation exposure. We measured the airborne radioactivity concentration at a 30 MeV cyclotron radioisotope production facility to assess whether the exhaust gas was contaminated. Additionally, we investigted the radioactive contamination of the air filter for efficient air purification and radiation safety control. To measure the airborne radiation concentration, specimens were collected weekly for 4 h after the beginning of the radioisotope production. Regarding the air purifier, five specimens were collected at different positions of each filter-pre-filter, high-efficiency particulate air filter, and charcoal filter-installed in the cyclotron production room. The concentrations of F-18, I-123, I-131, and Tl-201 generated in the radioiodine production room were $13.5Bq/m^3$, $27.0Bq/m^3$, $0.10Bq/m^3$, and $11.5Bq/m^3$, respectively; the concentrations of F-18, I-123, and I-131 produced in the radioisotope production room were $0.05Bq/m^3$, $16.1Bq/m^3$, and $0.45Bq/m^3$, correspondingly; and those of F-18, I-123, I-131, and Tl-201 generated in the accelerator room were $2.07Bq/m^3$, $53.0Bq/m^3$, $0.37Bq/m^3$, and $0.15Bq/m^3$, respectively. The maximum radiation concentration of I-123 generated in the radioiodine production room was 1,820 Bq/g, which can be disposed after 2 days. The maximum radiation concentration of Tl-202 generated in the radioisotope production room was 205 Bq/g, and this isotope must be stored for 53 days. The I-123 generated in the radioiodine production room had a maximum concentration of 1,530 Bq/g and must be stored for 2 days. The maximum radiation concentration of Na-22 generated in the radioisotope production room was 0.18 Bq/g and this isotope must be disposed after 827 days. To manage the exhaust, the efficiency of air purification must be enhanced by selecting an air purifier with a long life and determining the appropriate replacement time by examining the differential pressure through systematic measurements of the airborne radiation contamination level.

Evaluation of Effective Dose and Exposure Level of Radon in Process Handling NORM (인산석고 취급공정에서의 라돈농도 및 유효선량 수준 평가)

  • Chung, Eun Kyo;Jang, Jae Kil;Kim, Jong Kyu;Kim, Joon Beom;Kwon, Jiwoon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.3
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    • pp.283-291
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    • 2018
  • Objectives: To monitor the radon concentration level in plants that handle phosphorus rock and produce gypsum board and cement, and evaluate the effective dose considering the effect of radon exposure on the human body. Methods: Airborne radon concentrations were measured using alpha-track radon detectors (${\alpha}$-track, Rn-tech Co., Korea) and continuous monitors (Radon Sentinel 1030, Sun Nuclear Co., USA). Radon concentrations in the air were converted to radon doses using the following equation to evaluate the human effects due to radon. H (mSv/yr) = Radon gas concentration x Equilibrium factor x Occupancy factor x Dose conversion factor. The International Commission on Radiological Protection (ICRP) used $8nSv/(Bq{\cdot}hr/m^3)$ as the dose conversion factor in 2010, but raised it by a factor of four to $33nSv/(Bq{\cdot}hr/m^3)$ in 2017. Results: Radon concentrations and effective doses in fertilizer manufacturing process averaged $14.3(2.7)Bq/m^3$ ($2.0-551.3Bq/m^3$), 0.11-0.54 m㏜/yr depending on the advisory authority and recommendation year, respectively. Radon concentrations in the gypsum-board manufacturing process averaged $14.9Bq/m^3$ at material storage, $11.4Bq/m^3$ at burnability, $8.1Bq/m^3$ at mixing, $10.0Bq/m^3$ at forming, $8.9Bq/m^3$ at drying, $14.7Bq/m^3$ at cutting, and $10.5Bq/m^3$ at shipment. It was low because it did not use phosphate gypsum. Radon concentrations and effective doses in the cement manufacturing process were $23.2Bq/m^3$ in the stowage area, $20.2Bq/m^3$ in the hopper, $16.8Bq/m^3$ in the feeder and $11.9Bq/m^3$ in the cement mill, marking 0.12-0.63 m㏜/yr, respectively. Conclusions: Workers handling phosphorous gypsum directly or indirectly can be assessed as exposed to an annual average radon dose of 0.16 to 2.04 mSv or 0.010 to 0.102 WLM (Working Level Month).

Tritium Concentrations in Surface Seawater around Korean Peninsula (한국 주변 해역 표층해수중 삼중수소 농도)

  • Kim, Chang-Kyu;Cho, Yong-Woo;Kim, Kye-Hun
    • Journal of Radiation Protection and Research
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    • v.21 no.2
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    • pp.107-115
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    • 1996
  • An electrolytic enrichment technique was used to measure low levels of tritium in seawater around the Korean peninsula. Tritium concentrations were determined for surface seawater samples collected from the East Sea, the South Sea, and the Yellow Sea. The tritium concentrations in surface seawater samples from the study area ranged from $0.12 BqL^{-1}\;to\;1.50BqL^{-1}$ with a mean value of $0.60{\pm}0.35 BqL^{-1}$. The means of the tritium concentration were $0.54{\pm}0.30 BqL^{-1}$ for the East Sea, $0.48{\pm}0.35 BqL^{-1}$ for the South Sea, and $0.77{\pm}0.32 BqL^{-1}$ for the Yellow Sea. The tritium concentrations in the sea areas did not show much difference no matter where the samples were taken. Due to the limited number and distribution of sampling points, no systematic change in tritium levels with latitude was observed. Measured tritium levels were similar to those observed in other data collected near Japan, but higher than mid-Pacific Ocean measurements.

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