• BMB Reports
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• v.35 no.4
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• pp.389-394
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• 2002

$[Ru(bpy)_2(dppz)]^2+$ (bpy=2,2'-bipyfidine, dppz=dipyrido[3,2-a:2',3'-c]phenazine) (RuBD), a long-lifetime metal-ligand complex, displays favorable photophysical properties. These include long lifetime, polarized emission, but no significant fluorescence from the complex that is not bound to DNA. To show the usefulness of this luminophore (RuBD) for probing the bending and torsional dynamics of nucleic acids, its intensity and anisotropy decays when intercalated into supercoiled and relaxed pTZ18U plasmids were examined using frequency-domain fluorometry with a blue light-emitting diode (LED) as the modulated light source. The mean lifetimes for the supercoiled plasmids (< $\tau$ >=148 ns) were somewhat shorter than those for the relaxed plasmids (< $\tau$ >=160 ns). This suggests that the relaxed plasmids were shielded more efficiently from water. The anisotropy decay data also showed somewhat shorter slow rotational correlation times for supercoiled plasmids (288 ns) than for the relaxed plasmids (355 ns). The presence of two rotational correlation times suggests that RuBD reveals both the bending and torsional motions of the plasmids. These results indicate that RuBD can be useful for studying both the bending and torsional dynamics of mucleic acids.

• BMB Reports
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• v.38 no.1
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• pp.104-110
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• 2005

We extended the measurable time scale of DNA dynamics to microsecond using $[Ru(phen)_2(dppz)]^{2+}$ (phen = 1,10-phenanthroline, dppz = dipyrido[3,2-a:2',3'-c]phenazine) (RuPD), which displays a mean lifetime near 500 ns. To evaluate the usefulness of this luminophore (RuPD) for probing nucleic acid dynamics, its intensity and anisotropy decays when intercalated into supercoiled and linear pBluescript (pBS) II SK(+) phagemids were examined using frequency-domain fluorometry with a blue light-emitting diode (LED) as the modulated light source. The mean lifetime for the supercoiled phagemids (< $\tau$ > = 489.7 ns) was somewhat shorter than that for the linear phagemids (< $\tau$ > = 506.4 ns), suggesting a more efficient shielding from water by the linear phagemids. The anisotropy decay data also showed somewhat shorter slow rotational correlation times for supercoiled phagemids (997.2 ns) than for the linear phagemids (1175.6 ns). The slow and fast rotational correlation times appear to be consistent with the bending and torsional motions of the phagemids, respectively. These results indicate that RuPD can have applications in studies of both bending and torsional dynamics of nucleic acids.

• Tribology and Lubricants
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• v.32 no.4
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• pp.107-112
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• 2016

This paper presents a rotordynamic analysis of the reduction gear system applied to the 250 kW super critical CO₂ cycle. The reduction gear system consists of an input shaft, intermediate shaft, and output shaft. Because of the high rotating speed of the input shaft, we install tilting pad bearings, rolloer bearings support the intermediate and output shafts. To predict the tilting pad bearing performance, we calculate the applied loads to the tilting pad bearings by considering the reaction forces from the gear. In the rotordynamic analysis, gear mesh stiffness results in a coupling effect between the lateral and torsional vibrations. The predicted Campbell diagram shows that there is not a critical speed lower than the rated speed of 30,000 rpm of the input shaft. The predicted modes on the critical speeds are the combined bending modes of the intermediate and output shaft, and the lateral vibrations dominate when compared to the torsional vibrations. The damped natural frequency does not strongly depend on the rotating speeds, owing to the relatively low rotating speed of the intermediate and output shaft and constant stiffness of the roller bearing. In addition, the logarithmic decrements of all the modes are positive; therefore all modes are stable.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.25 no.2
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• pp.119-127
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• 2012

A wire rope is comprised of several metal wires which are wound together like a helix and it can resist relatively large axial loads, as compared with bending and torsional loads. A shipbuilding crane for erection such as a floating crane, a gantry crane, and a crawler crane hoists up and down heavy blocks by using these wire ropes. Thus, it is necessary to find dynamic properties of a wire rope in order to safely lift the blocks using the crane. In this study, a formula for calculating the tension and torsional moment acting on wire ropes of the crane was derived based on the existing study, and then dynamic simulation of the crane was performed based on the formula. The result shows that the dynamic simulation can be applied to find the safe method for block erection of shipyards.

• Bulletin of the Korean Chemical Society
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• v.20 no.4
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• pp.445-450
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• 1999

Molecular dynamics (MD) simulation of non-rigid H-Y zeolite framework are performed at 298.15 and 5.0 K. Usual bond stretching, bond angle bending, torsional rotational, and non-bonded Lennard-Jones and electrostatic interactions are considered as intraframework interaction potentials. Calculated atomic parameters are in good agreement with the experiment, which indicates the successful reproduction of the framework structure and its motion. Both calculated bond lengths and bond angles are also in good agreement with the experiment except generally for a little longer bond lengths and a little smaller T-O-H bond angles. The calculated overall site occupation of HI keeps the order O(2) > O(3) > O(4) > O(t) at 298.15 K, which is very different from the experimental prediction, O(l) > O(3) > O(2) at 5 K. Calculated IR spectra of the H-Y zeolite framework show that most of the main peaks of the O-H bonds are in the broad region 3700-5000 cm-1 and that the O-T stretching bands appeared in 0-2000 cm-1 and at 2700 cm-1

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1997.10a
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• pp.43-49
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• 1997

A rotating rigid disk, attached on a flexible shaft or supported by a torsional spring, experiences precessional whirling due to gyroscopic moment loading. It is well known in rotor dynamics area that, as the rotational speed increases, the precessional mode of the rotating rigid disk starts splitting into two: forward and backward precessional modes. On the other hand, it is also well known in disk vibration area that a rotating flexible disk also shows another kind of mode splitting phenomenon due to the rotation, resulting in forward and backward traveling waves. When rotating multiple flexible disks are coupled in vibration with the supporting Flexible shaft, the associated mode splitting should be compatible with the two seemingly different vibration analysis methods. This paper investigates the possibility of fusing the precessional and traveling wave mode splittings so that the bending coupled disk vibrations in HDD spindle systems can be better understood.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.20 no.9
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• pp.849-855
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• 2010

Damping may change the response characteristics of nonlinear oscillations due to the parametric excitation of a thin cantilever beam. When the natural frequencies of the first bending and torsional modes are of the same order of magnitude, we can observe the one-to-one combination resonance in the perturbation analysis depending on the characteristic parameters. The nonlinear behavior about the combination resonance reveals a chaotic motion depending on the natural frequencies and damping ratio. We can analyze the chaotic dynamics by using the eigenvalue analysis of the perturbed components. In this paper, we derived the equations for autonomous system and solved them to obtain the characteristic equation. The stability analysis was carried out by examining the eigenvalues. Numerical integration gave the physical behavior of each mode for given parameters.

• Bulletin of the Korean Chemical Society
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• v.19 no.4
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• pp.422-428
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• 1998

In the present paper, we report a molecular dynamics (MD) simulation of non-rigid zeolite-A framework only as the base case for a consistent study of the role of intraframework interaction on several zeolite-A systems using the same technique in our previous studies of rigid zeolite-A frameworks. Usual bond stretching, bond angle bending, torsional rotational, and non-bonded Lennard-Jones and electrostatic interactions are considered as intraframework interaction potentials. The comparison of experimental and calculated structural parameters confirms the validity of our MD simulation for zeolite-A framework. The radial distribution functions of non-rigid zeolite-A framework atoms characterize the vibrational motion of the framework atoms. Mean square displacements are all periodic with a short period of 0.08 ps and a slow change in the amplitude of the vibration with a long period of 0.53 ps. The displacement auto-correlation (DAC) and neighbor-correlation (DNC) functions describe the up-and-down motion of the framework atoms from the center of α-cage and the back-and-forth motion on each ring window from the center of each window. The DAC and DNC functions of the framework atoms from the center of α-cage at the 8-ring windows have the same period of the up-and-down motion, but those functions from the center of 8-ring window at the 8-ring windows are of different periods of the back-and-forth motion.

• Bulletin of the Korean Chemical Society
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• v.17 no.8
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• pp.735-744
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• 1996

We present results of molecular dynamic (MD) simulations for the thermodynamic and structural properties of liquid n-alkanes, from n-butane to n-heptadecane, using three different models Ⅰ-Ⅲ. Two of the three classes of models are collapsed atomic models while the third class is an atomistically detailed model. Model Ⅰ is the original Ryckaert and Bellemans' collapsed atomic model [Discuss. Faraday Soc. 1978, 66, 95] and model Ⅱ is the expanded collapsed model which includes C-C bond stretching and C-C-C bond angle bending potentials in addition to Lennard-Jones and torsional potentials of model Ⅰ. In model Ⅲ all the carbon and hydrogen atoms in the monomeric units are represented explicitly for the alkane molecules. Excellent agreement of the results of our MD simulations of model Ⅰ for n-butane with those of Edberg et al.[J. Chem. Phys. 1986, 84, 6933], who used a different algorithm confirms the validity of our algorithms for MD simulations of model Ⅱ for 14 liquid n-alkanes and of models Ⅰ and Ⅲ for liquid n-butane, n-decane, and n-heptadecane. The thermodynamic and structural properties of models Ⅰ and Ⅱ are very similar to each other and the thermodynamic properties of model Ⅲ for the three n-alkanes are not much different from those of models Ⅰ and Ⅱ. However, the structural properties of model Ⅲ are very different from those of models Ⅰ and Ⅱ as observed by comparing the radial distribution functions, the average end-to-end distances and the root-mean-squared radii of gyrations.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.25 no.12
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• pp.881-887
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• 2015

The stiffness and natural frequencies for blades, flexbeam, and torque tube of bearingless rotor system are measured to determine the material input properties such as mass distributions and stiffness distribution for the rotor dynamics and load analysis. The flap stiffness, lag stiffness, and torsional stiffness are calculated by measuring section strain or twist angle, gages position, and applied loads through bending and twist tests. The modal tests are undertaken to find out the natural frequencies for flap, lag, torsion modes in non-rotating conditions. The stiffness values and mass properties are tuned and updated to match prediction frequencies to the measured frequencies. The rotorcraft comprehensive code(CAMRAD II) is used to analyze the natural frequencies of the specimens. The analysis results with the updated material properties agree well with the measured frequencies. The updated properties will be used to analyze the rotor stability, dynamic characteristics and loads for the rotor rotation test in a whirl tower.