• Title/Summary/Keyword: Beryllium

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Beryllium oxide utilized in nuclear reactors: Part I: Application history, thermal properties, mechanical properties, corrosion behavior and fabrication methods

  • Ming-dong Hou;Xiang-wen Zhou;Bing Liu
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4393-4411
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    • 2022
  • In recent years, beryllium oxide has been widely utilized in multiple compact nuclear reactors as the neutron moderator, the neutron reflector or the matrix material with dispersed nuclear fuels due to its prominent properties. In the past 70 years, beryllium oxide has been studied extensively, but rarely been systematically organized. This article provides a systematic review of the application history, thermal properties, mechanical properties, corrosion behavior and fabrication methods of beryllium oxide. Data from previous literature are extracted and sorted out, and all of these original data are attached as the supplementary material, so that subsequent researchers can utilize this paper as a database for beryllium oxide research in reactor design or simulation analysis, etc. In addition, this review article also attempts to point out the insufficiency of research on beryllium oxide, and the possible key research areas about beryllium oxide in the future.

A Study on the Zircaloy-4 Brazing with Beryllium Filler Metal for the Nuclear Fuel (베릴륨 용가재를 사용한 핵연료피복재 지르칼로이-4 브레이징에 대한 연구)

  • 고진현;김형수
    • Journal of Welding and Joining
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    • v.11 no.4
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    • pp.70-78
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    • 1993
  • An attempt was made to investigate the effect of brazing time on microstructure, microhardness, and corrosion of Zircaloy -4as well as the beryllium diffusion into its sheet. The sheets were coated with beryllium and brazed at $1020^{\circ}C$ for 20-40 minutes in $2{\times}10^{-5}$ torr vacuum atmosphere. 1. Microstructurally the brazed zone was largely divided into three regions: a region of continuous or partially formed of eutectic liquid films along grain boundaries; a region of precipitation in both grains and grain boundaries; a region of elongated wide structure of .alpha.-laths, which was not affected by beryllium. 2. Due to the precipitates, the beryllium-migrated region was hardened and the width of the hardened region increased with increasing brazing time. 3. Beryllium brazed Zircaloy -4 sheets showed a higher corrosion rate than those of as-received and heat-treated at a brazing temperature. 4. Diffusion coefficient of beryllium into Zircaloy -4 at $1020^{\circ}C$ for 30 minutes was $7.67{\times}10^{-7}cm^2/sec.$ It seemed that Be penetrated Zircaloy -4 by forming eutectic liquid films along grain boundaries in the proximity of Be/Zr interface and it, thereafter, diffused into Zircaloy mainly by interstitial solid solution.

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Effects of Beryllium on Human Serum Immunoglobulin and Lymphocyte Subpopulation

  • Kim, Ki-Woong;Kim, DaeSeong;Won, Yong Lim;Kang, Seong-Kyu
    • Toxicological Research
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    • v.29 no.2
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    • pp.115-120
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    • 2013
  • To investigate the effects of short-term exposure of beryllium on the human immune system, the proportion of T-lymphocytes such as CD3+, CD4+, CD8+, CD95, and NK cells, and the proportion of B cells and $TNF{\alpha}$ level in peripheral blood and immunoglobulins in the serum of 43 exposed workers and 34 healthy control subjects were studied. External exposure to beryllium was measured by atomic absorption spectrometer as recommended by the NIOSH analytical method 7300. T lymphocyte subpopulation analysis was carried out with flow cytometer. The working duration of exposed workers was less than 3 months and the mean ambient beryllium level was $3.4{\mu}g/m^3$, $112.3{\mu}g/m^3$, and $2.3{\mu}g/m^3$ in molding (furnace), deforming (grinding), and sorting processes, respectively (cited from Kim et al., 2008). However, ambient beryllium level after process change was non-detectable (< $0.1{\mu}g/m^3$). The number of T lymphocytes and the amount of immunoglobulins in the beryllium-exposed workers and control subjects were not significantly different, except for the total number of lymphocytes and CD95 (APO1/FAS). The total number of lymphocytes was higher in the beryllium-exposed individuals than in the healthy control subjects. Multiple logistic regression analysis showed lymphocytes to be affected by beryllium exposure (odd ratio = 7.293; p<0.001). These results show that short-term exposure to beryllium does not induce immune dysfunction but is probably associated with lymphocytes proliferation.

Comparison of dental porcelain baking methods by base-alloy and bonding strength by thermocycling (Base-Alloy에 따른 치과 도재의 소성방법과 열순환에 따른 결합강도 비교)

  • Kim, Im-Sun;Min, Kyung-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.772-779
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    • 2010
  • This study measured the bonding strength of various porcelain prosthesis materials before and after thermocycling to select prosthesis materials that can maximize beauty and tolerance. To measure bonding strength, various porcelain materials were baked on with-Beryllium metals, non-Beryllium metals 8group and Zirconia 1 group among commercially available base alloys, and measured the bonding strength was measured before and after thermocycling. The findings of this study are as follows: 1) PTM(press-to-metal) porcelain non-Beryllium metal showed the, highteat bonding strength each 73.2MPa, 59.2MPa before and after thermocycling. 2) The porcelain materials baked on non-Beryllium metal showed higher bonding strength before and after thermocycling than those baked on with-Beryllium metal. 3) Zirconia products showed the lowest 38.7MPa bonding strength before and after thermocycling.

Modeling and characterization of beryllium reflector elements under irradiation conditions

  • Ahmed H. Elhefnawy;Mohamed A. Gaheen;Hanaa H. Abou Gabal;Mohamed E. Nagy
    • Nuclear Engineering and Technology
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    • v.55 no.12
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    • pp.4583-4590
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    • 2023
  • This study aims at modeling the beryllium reflector poisoning under neutron irradiation conditions and calculating the impact of beryllium poisoning on the core parameters of ETRR-2 research reactor. The CITVAP code was used to calculate the neutron flux and parameters of ETRR-2 core with beryllium reflector elements. The neutron flux in each reflector element was calculated to solve the modeling equations for the atomic densities of lithium-6 (6Li), tritium-3 (3H), and helium-3 (3He) using the BERYL program. The results are discussed based on CITVAP calculations of the core excess reactivity and cycle length Full Power Days (FPD). Possible solutions to minimize the degradation due to beryllium poisoning are also discussed and compared based on calculations.

Investigation of Deep Drawability and Product Qualities of Ultra Thin Beryllium Copper Sheet Metal (베릴륨동 극박판의 드로잉 성형성과 품질특성 연구)

  • Park, S.S.;Hwang, K.B.;Kim, J.B.;Kim, J.H.
    • Transactions of Materials Processing
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    • v.19 no.3
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    • pp.179-184
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    • 2010
  • The present study is focused on the deep drawability and product qualities of ultra thin beryllium copper sheet metal. The goal of this research is to investigate the limit drawing ratio in deep drawing of ultra thin beryllium copper metal. For the experiment, beryllium copper(C1720, $50{\mu}m$ in thickness) is used. Tensile test are also carried out to find out the material properties. Deep drawing experiments are carried out in Universal Testing Machine(UTM) to obtain limit drawing ratio. Deep drawing tests are carried out for various specimen sizes. Teflon film is used as a lubricant and constant blank holding force is imposed. Sheet thickness and surface hardness are measured along radial direction after deep drawing. Thickness is measured using optical microscope. For beryllium copper(C1720), the maximum LDR of 2.4 is obtained when the die shoulder radius is 20 or 30 times of sheet thickness.

A Fabrication Method of Blade Type Tip for Probe Unit Device (프르브유닛 소자용 블레이드형 팁 제조방법)

  • Lee, Keun-Woo;Lee, Jae-Hong;Kim, Chang-Kyo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.8
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    • pp.1436-1440
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    • 2007
  • Beryllium copper has been known to be an important material for the various fields of industry because it can be used for mechanical and electrical/electronic components that are subjected to elevated temperatures (up to $400^{\circ}C$ for short times). Blade type tip for probing the cells of liquid crystal display(LCD) was fabricated using beryllium copper foil. The dry film resist was employed as a mask for patterning of the blade type tip. The beryllium copper foil was etched using hydrochloric acidic iron-chloride solution. The concentration, temperature, and composition ratio of hydrochloric acidic iron-chloride solution affect the etching characteristics of beryllium copper foil. Nickel with the thickness of $3{\mu}m$ was electroplated on the patterned copper beryllium foil for enhancing its hardness, followed by electroplating gold for increasing its electrical conductivity. Finally, the dry film resist on the bridge was removed and half of the nickel was etched to complete the blade type tip.

Molecular Orbital Calculation for Polymeric Beryllium Hydride, Polyeithylene and Polymeric Boron Hydride According to the Pseudo-Lattice Method

  • Oh, Seok-Heon;Jhang, Man-Chai;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.1
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    • pp.37-41
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    • 1984
  • The pseudolattice calculations in the CNDO/2 level of approximation are carried out for polymeric beryllium hydride, polyethylene and polymeric boron hydride. Since there is no evidence on the geometry for polymeric boron hydride, the two possible geometries are assumed. One is a polyethylene-type geometry and the other is a polymeric beryllium hydride-type geometry. In order to compare their relative stability, we calculate polyethylene and polymeric beryllium hydride and then compare with polymeric boron hydride having the assumed structures. The total energy calculation indicates that a polymeric beryllium bydride-type geometry is more stable than a polyethylene-type geometry. Our results obtained for polyethylene are in good agreement with those given by CNDO/2 crystal orbital. From the convergence problem with respect to the number of unit cells (M), the calculation with value of 4 for M can be considered to give the convergence limit results.

Beryllium Analysis on the Brazing Zone of Zircaloy-4 Cladding (Zircaloy-4 피복관 부레이징 계면의 베릴륨 분석)

  • Lee, Key-Soon;Lee, Byong-Whi
    • Nuclear Engineering and Technology
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    • v.21 no.4
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    • pp.341-345
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    • 1989
  • The distribution behaviors of beryllium which may produce a deleterious damage in the zircaloy cladding have been investigated by the X-ray line scanning of EPMA. The results obtained are as follows; 1) The alloy phase formed by the brazing contains ~6.3 mass % of beryllium. 2) The beryllium diffusion in the base metal (cladding and bearing pad) is recognized only in the range ~5 $\mu$m from the brazing interface.

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The effect of preheat treatment on ceramic to metal bond strength (도재-금속의 결합 강도에 미치는 비금속 합금의 열처리 효과)

  • Kim, Chi-Young;Kim, Young-Gon; Cho, Hyun-Seol
    • Journal of Technologic Dentistry
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    • v.24 no.1
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    • pp.33-41
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    • 2002
  • In dental prosthetics, the application of metal-ceramic restorations has steadily increased since their introduction. This is due to excellent esthetics in combination with high mechanical stability. In order to optimum bond strength between metal and ceramics, controlled oxidation of metal substructure is essential factor. Beryllium containing and beryllium free Ni-Cr alloys for metal-ceramic restorations were evaluated for the metal-ceramic bond strength by changing heat treatment for oxide formation. A mechanical three-point bending test was employed to evaluate the interfacial bond strength of metal-ceramic. In each metal, plate type specimens were used for mechanical three-point bending test. With Ni-Cr alloys for metal ceramics, mechanical three-point bending test showed that double degassing was more available preheat treatment method than another. It was found that beryllium containing Ni-Cr alloys are more effective than beryllium-free for metal-ceramic bond strength.

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