• Title/Summary/Keyword: C-V character

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GROUP THEORY FOR TETRAAMMINEPLATINUM(II) WITH $C_{2v}\;AN;C_{4v}$ POINT GROUP IN THE NON-RIGID SYSTEM

  • Ashrafi, Ali-Reza;Hamadanian, Masood
    • Journal of applied mathematics & informatics
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    • v.14 no.1_2
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    • pp.289-303
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    • 2004
  • The non-rigid molecule group theory (NRG) in which the dynamical symmetry operations are defined as physical operations is a new field of chemistry. Smeyers in a series of papers applied this notion to determine the character table of restricted NRG of some molecules. In this work, a simple method is described, by means of which it is possible to calculate character tables for the symmetry group of molecules consisting of a number of NH3 groups attached to a rigid framework. We study the full non-rigid group (f-NRG) of tetraammineplatinum(II) with two separate symmetry groups C2v and C4v. We prove that they are groups of order 216 and 5184 with 27 and 45 conjugacy classes, respectively. Also, we will compute the character tables of these groups.

FREE LIE SUPERALGEBRAS AND THE REPRESENTATIONS OF gl(m, n) AND q(n)

  • KWON JAE-HOON
    • Journal of the Korean Mathematical Society
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    • v.42 no.2
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    • pp.365-386
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    • 2005
  • Let L be the free Lie superalgebra generated by a $Z_2$-graded vector space V over C. Suppose that g is a Lie superalgebra gl(m, n) or q(n). We study the g-module structure on the kth homogeneous component Lk of L when V is the natural representation of g. We give the multiplicities of irreducible representations of g in Lk by using the character of Lk. The multiplicities are given in terms of the character values of irreducible (projective) representations of the symmetric groups.

Study on the Sublimatographic Characters of Sulfur (황의 Sublimatographic Characters에 관한 연구)

  • Sohn, Jin-Un;Kim, Joo-Bong
    • Elastomers and Composites
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    • v.7 no.1
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    • pp.53-58
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    • 1972
  • Sublimatographic study on the method of test for sulfur in the petroleum and rubber products was as following results: (1) The relation between the heating temperature$(t_h)$ and the vacuum condensing point(V.C.P.) of sulfur at different degree of vacuum appeared as Fig.4. The results were in good agreement with those expected from the $t_h-V.C.P$ curves of sublimatographic separation of sulfur. (2) The relation between the degree of vacuum and the V.C.P. at different heating temperature of sulfur appeared as follows; $$tv.c.p.=\alpha+{\beta}logP_{va}$$ (3) The V.C.P of sulfur could be physical property comparing with melting point and boiling point. (4) The relation between the V.C.P. and the quantity of sublimation of sulfur becomes quantitative as Fig.7.

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A Kinetic Study on the Solvolysis of Benzyl Chloride under High Pressure (고압하에서 염화벤질의 가용매분해반응에 대한 속도론적 연구)

  • Kwon, Oh-Cheun;Kyong, Jin-Burm
    • Journal of the Korean Chemical Society
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    • v.31 no.3
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    • pp.207-214
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    • 1987
  • Rates of solvblysis of benzyl chloride in ethanol-water mixtures have been measured at 30 and $40^{\circ}C$ under various pressures up 1.6 kbar. The plots of 1n k as a function of pressure are fitted to a second order function in p, and values of ${\Delta}V^{\neq}$and ${\Delta}{\beta}^{\neq}$ are obtained from the results. Also the values of various pseudo thermodynamic quantities were evaluated from the rate constants. The relationships of the 1n k to $Q_w$ or 1n $C_w$ indicate that the reaction proceeds through $S_N1$ mechanism. A comparison between the present and the previous results gives that the increasing order of ${\mid}{{\Delta}V_0}^{\neq}{\mid}$ and n-values are $p-Cl>p-H>p-CH_3$ and $p-CH_3>p-H.p-Cl$, respectively. From these results, it is believed substituent such as the $p-CH_3$group favors the $S_N1(1)$ character, while the p-Cl group leads to the $S_N1(2)$ character.

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Fabrication and Character istics of self-aligned AlGaAs/GaAs HBT using $WN_{x}$ as emitter metal ($WN_{x}$ 에미터 전극을 갖는 자기정렬 AlGaAs/GaAs HBT의 제작과 특성)

  • 이종민;이태우;박문평;최인훈;박성호;박철순
    • Proceedings of the IEEK Conference
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    • 1998.06a
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    • pp.461-464
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    • 1998
  • Self-aligned AlGaAs/GaAs HBTs with the emitter area of 1.5*10.mu.$m^{2}$ were fabricated usng $WN_{x}$ as emitter metal. Their DC and RF characteristics were investigated. The common emitter current gain was 45 at $J_{c}$ = 6*$10^{4}$A/$cm^{2}$. From the Gummel plot, the ideality factors of $I_{c}$ and $I_{B}$ were 1.18 and 1.70, respectively. Emitter and base resistance were extracted from voltage drop region in gummel plot, and their values were 5.3.ohm. and 38.2.ohm.. The extrapolated $f_{T}$ = 72GHz and $f_{max}$ = 81GHz were obtained at $V_{CE}$ = 2V.

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ALGEBRAS OF GELFAND-CONTINUOUS FUNCTIONS INTO ARENS-MICHAEL ALGEBRAS

  • Oubbi, Lahbib
    • Communications of the Korean Mathematical Society
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    • v.34 no.2
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    • pp.585-602
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    • 2019
  • We characterize Gelfand-continuous functions from a Tychonoff space X into an Arens-Michael algebra A. Then we define several algebras of such functions, and investigate them as topological algebras. Finally, we provide a class of examples of (metrizable) commutative unital complete Arens-Michael algebras A and locally compact spaces X for which all these algebras differ from each other.

A Study on Solidification and Wear Character of Multi-alloyed White Cast Iron

  • Yu, Sung-Kon;Matsubara, Yasuhiro
    • Journal of Korea Foundry Society
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    • v.20 no.4
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    • pp.260-268
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    • 2000
  • 응고 및 마모거동을 연구하기 위하여 Cr, V, Mo 및 W의 조성이 다른 3종류의 백주철을 주조하였다. 고주파유도용해로에서 장입시켜 1873K까지 승온시켜 장입원료들을 모두 용해시킨 후 1823K에서 Y블럭주형에 주입하였다. 얻어진 3종류의 백주철조성은 다음과 같다: Fe-3%C-10%Cr-5%Mo-5%W(합금1), Fe-3%C-10%V-5%Mo-5%W(합금2) 및 Fe-3%C-17%Cr-3%V(합금 3)응고과정을 추적하기 위하여 각 시편으로부터 50g을 채취한 후 알루미나도가니에 넣고 실리콘카바이드로를 사용하여 1723K의 알콘분위기하에서 재용해를 시켰다. 용금을 10K/분의 속도로 냉각시키면서 열분석을 행하였으며 도중 몇 차례 소입 실험을 병행하였다.합금1의 경우 초정오스테나이트, (오스테나이트+$M_7C_3$)공정, (오스테나이트+$M_6C$)공정, 합금2의 경우 초정 MC, 초정오스테나이트, (오스테나이트+MC)공정 , (오스테나이트+$M_2C$)공정, 합금3의 경우 초정 $M7C_3$와 (오스테나이트+$M_7C_3$)공정으로 구성되어 있었다. 주방상태, 균질화열처러상태, 공냉상태, 템퍼링상태에서 내마모시험을 행하였다. 먼저 주방상태시 편을 진공분위기하에서 1223K에서 5시간동안 균질화열처리를 행한후 로냉을 시켰다. 다시 이 시편을 1323K에서 2시간 유지후 강제공냉을 시켰으며 강제공냉된 시편을 573K에서 3시간동안 템퍼링처리를 하였다. 내마모시험은 120 mesh마모지에 10N의 하중을 가하여 실시하였다. 각 사이클마다 무게감소를 측정하였으며 8번 반복실험을 하였다. 마모량은 균질화열처리시편, 주방상태시편, 템퍼링시편, 공냉시편의 순으로 감소하였다. 합금2가 마모량이 가장 적었으며 합금3이 가장 많았다. 합금2의 마모량이 가장 적은 이유는 조직이 초정 MC, 공정 MC 및 공정 M2C로 구성되어 있기 때문으로 사료된다.주방상태에서 기지조직은 퍼얼라이트이었으나 열처리를 통하여 마르텐사이트, 템퍼드마르텐사이트, 잔류오스테나이트로 변태하였다. 이상의 결과를 종합해 보면 MC가 내마모성에 가장 기여하는 조직으로 판단되어진다.

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A Study on the Visual Effect of the Viewing -Window based on Psychology -focused on residential environment- (전망창의 시각효과에 대한 심리학적 고찰- 주거공간을 중심으로)

  • 함정도
    • Korean Institute of Interior Design Journal
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    • no.8
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    • pp.58-64
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    • 1996
  • People live in an environment which affects the human b by way of ‘Affordance’ .. And the interaction between h human and the surrounding environment arises ‘the sense of place' through adoptation. Considering the human emo¬t tional and psychological needs, besides the functionalones, for the design of environment gives ‘the place’ the h humanized atmosphere. Then the viewing-window, re¬f fleeting the dweller’s sensibility and aesthetic aspect, be¬c comes an important design element for the human interi¬o or atmosphere. G Generally, the view has the character of the Panorama a and sometimes of the Picture. And the viewing - window t transfigures the visual effects by ways of ‘Framing’, at t taching the ’Screen’ and ‘Successive development' of the views through openings on the wall. Hence this study w was developed from the aesthethic view-points of archi t tecture, cinema, picture and photography etc., and the c conclusions are as follows. T The ‘Frame’ limits the boundary of the view into a p particular area, while the ‘Screen’ changes the clear view t to an obscure one. And the wall-openings located with i intervals show the fragments of the outer view in a suc¬c cessive way. And these techniques applied to the viewing window make the viewer have the associated meanings d derived from the ‘Guided Projection'. So, the associative p psychology of the viewer complements the partiality, ob¬s scurity and brokenness of the view into a complete one, a and finally the view comes to be an aesthetic one to the v vIewer.

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X-ray absorption spectroscopic study of MgFe2O4 nanoparticles

  • Singh, Jitendra Pal;Lim, Weon Cheol;Song, Jonghan;Kim, Joon Kon;Chae, Keun Hwa
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.230.2-230.2
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    • 2015
  • Nanoparticles of magnesium ferrite are used as a heterogeneous catalyst, humidity sensor, oxygen sensor and cure of local hyperthermia. These applications usually utilize the magnetic behavior of these nanoparticles. Moreover, magnetic properties of nanoferrites exhibit rather complex behavior compared to bulk ferrite. The magnetic properties of ferrites are complicated by spins at vortices, surface spins. Reports till date indicate strong dependency on the structural parameters, oxidation state of metal ions and their presence in octahedral and tetrahedral environment. Thus we have carried out investigation on magnesium ferrite nanoparticles in order to study coordination, oxidation state and structural distortion. For present work, magnesium ferrite nanoparticles were synthesized using nitrates of metal ions and citric acid. Fe L-edge spectra measured for these nanoparticles shows attributes of $Fe^{3+}$ in high spin state. Moreover O K-edge spectra for these nanoparticles exhibit spectral features that arises due to unoccupied states of O 2p character hybridized with metal ions. Mg K-edge spectra shows spectral features at 1304, 1307, 1311 and 1324 eV for nanoparticles obtained after annealing at 400, 500, 600, 800, 1000, and $1200^{\circ}C$. Apart from this, spectra for precursor and nanoparticles obtained at $300^{\circ}C$ exhibit a broad peak centered around 1305 eV. A shoulde rlike structure is present at 1301 eV in spectra for precursor. This feature does not appear after annealing. After annealing a small kink appear at ~1297 eV in Mg K-edge spectra for all nanoparticles. This indicates changes in local electronic structure during annealing of precursor. Observed behavior of change in local electronic structure will be discussed on the basis of existing theories.

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Studies on Boil-off Loss Ratio in the Cocoon Shells of Multivoltine${\times}$Bivoltine Hybrids of Silkworm, Bombyx mori L.

  • Rao, D.Raghavendra;Singh, Ravindra;Premalatha, V.;Sudha, V.N.;Kariappa, B.K.;Dandin, S.B.
    • International Journal of Industrial Entomology and Biomaterials
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    • v.8 no.1
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    • pp.101-106
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    • 2004
  • The process of removal of gummy proteinous material sericin from silk is commonly called as degumming loss or boil-off loss ratio. In the present study, the boil-off loss ratio in the cocoon shells of twelve multivoltine${\times}$bivoltine hybrids and their parents were analysed. Inheritance pattern of boil-off loss ratio was analysed in crosses involving high and low boil-off loss parents, F$_1$s, F$_2$s and back-crosses by parent off spring regression analysis. Heterosis and heterobeltiosis was also analysed for this character, Highly significant (P>0.01) variations were observed in eight out of ten multivoltine and two out of five bivoltine parents indicating the presence of genetic variation in the expression of boil-off loss ratio. Among F$_1$ hybrids, ten hybrids expressed significant (P>0.01) variations when compared with control hybrid PM${\times}$NB$_4$D$_2$. Significant negative heterosis was expressed in three multi ${\times}$ bi hybrids viz., BL67${\times}$CSR$_{101}$, 96A${\times}$CSR$_{19}$ and 96C${\times}$CSR$_{19}$, which is desirable for this character, whereas expression of heterobeltiosis was significant only with one hybrid, 96C${\times}$CSR$_{18}$ in desired direction. Studies on inheritance pattern showed that the character is heritable and contribution percentage of female and male in the ratio of 50.9: 49.1 and it appears that both the parents are influencing in the expression of boil-on loss ratio in silkworm. Based on the overall performance and evaluation by multiple trait evaluation index and also considering the expression of the boil-off loss ratio three hybrids vix., BL67 ${\times}$ CSR$_{101}$, 96A${\times}$CSR$_{19}$ and 96C${\times}$CSR$_{18}$ were found superior and recommended for commercial exploitation.n.ion.n.