• Title/Summary/Keyword: C6

Search Result 50,241, Processing Time 0.069 seconds

Molecular Genetic Studies of Korean Population. 16. Genetic Polymorphim of the Sixth Complement Component (C6) (한국인 집단의 유전학적 연구 16. Compiement Component 6의 유전적 다형)

  • 박경숙;김영진;목지원;이미혜
    • The Korean Journal of Zoology
    • /
    • v.34 no.2
    • /
    • pp.228-231
    • /
    • 1991
  • The phenotyping of the sixth complement component (C6) was performed on plasma or serum samples from 383 unrelated Korean, by IEF and immunoblotting using anti-human C6 serum. Three common allotypes, C6 A, C6 B and C6 B2 and two rare allotypes, C6 Ml and C6 Mu were observed. The allele frequencies of C6*A, C6*B and C6*B2 were estimated to be 0.4399, 0.5144, 0.0392, respectively. These frequencies are similar to those of the Eastasian populations.

  • PDF

Synthesis and structure of ($C_6CH_2NH_3)_2CUCl_4and \;(NH_3C_6C_4C_2H_4C_6NH_3)CUCl_4$ (($C_6CH_2NH_3)_2CUCl_4와 \;(NH_3C_6C_4C_2H_4C_6NH_3)CUCl_4$의 합성과 구조)

  • 김지현;권석순;현준원;허영덕
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.14 no.4
    • /
    • pp.135-139
    • /
    • 2004
  • The layered organic-inorganic hybrid compounds($C_6H_5CH_2NH_3)_2CuCl_4$ and ($NH_3C_6/H_4C_2H_4_6/H_4NH_3)CuCl_4$ have been directly synthesized. From the X-ray diffraction data and the organic guest size, the orientation of the intercalated organic amine was determined. The inorganic sheets consist of $CuCl_4^{2-}$layers of comer-sharing octahedra copper chloride. The protonated organic amine was intercalated into the $CuCl_4^{2-}$layers with bilayer structure for ($C_6H_5CH_2NH_3)_2CuCl_4$ and monolayer structure for ($NH_3C_6/H_4C_2H_4_6/H_4NH_3)CuCl_4$.

The Complexes of Iodobenzene with Halogens and Interhalogens in Carbon Tetrachloride (요오드벤젠과 할로겐 또는 할로겐間化合物 사이의 錯物에 관한 연구)

  • Choi, Sang-Up;Kim, Eung-Ryul
    • Journal of the Korean Chemical Society
    • /
    • v.11 no.3
    • /
    • pp.94-99
    • /
    • 1967
  • The interactions of iodobenzene with iodine, iodine monobromide, iodine monochloride and chlorine in carbon tetrachloride solution have been investigated by means of ultraviolet spectrophotometric measurements. The results reveal the formation of one to one molecular complexes, $C_6H_5I{\cdot}I_2$, $C_6H_5I{\cdot}IBr$, $C_6H_5I{\cdot}ICl$, and $C_6H_5I{\cdot}Cl_2$, in solution. The equilibrium constants obtained at room temperature (about $21^{\circ}C$) for the formation of these four complexes are 0.23, 0.73, 1.2 and 0.070 l $mole^{-1}$, respectively. Comparison of these results with those reported in the literature on other complexes of similar type indicates that the relative stabilities of these complexes decrease in the following orders: ICl>IBr>$I_2$>$Br_2$>$Cl_2$ $C_6H_5I$>$C_6H_6$>$C_6H_5Br$>$C_6H_5Cl$>$C_6H_5F$.

  • PDF

The Effect of Solvents on the Formation of Complexes of Benzene with Iodine and with Iodine Monochloride (벤젠과 요오드 또는 일염화요오드 사이의 錯物에 대한 용매의 영향)

  • Choi, Sang-Up;Lee, Bu-Yong
    • Journal of the Korean Chemical Society
    • /
    • v.9 no.4
    • /
    • pp.161-168
    • /
    • 1965
  • The effect of solvents on the stabilities of the $C_6H_6{\cdot}I_2$ complex and the $C_6H_6{\cdot}ICl$ complex has been investigated through ultraviolet spectrophotometric measurements. The equilibrium constants obtained at room temperature for the formation of $C_6H_6{\cdot}I_2$ complex are 0.090, 0.216 and 0.328$ lmole^{-1}$ in chloroform, cyclohexane and n-hexane, respectively. The corresponding equilibrium constants at room temperature for $C_6H_6{\cdot}ICl$ complex are 0.125, 0.676 and 0.689 $lmole^{-1}.$ These results indicate that the stabilities of the two complexes increase with decreasing dielectric constants of the solvents used, the increase in stability being more rapid in the $C_6H_6{\cdot}ICl$ complex than in the $C_6H_6{\cdot}I_2$ complex. This may support the conclusion that the dative ionic structures, $C_6H_6^+{\cdots}I_2^-$ and/or ($C_6H_6I)^+{\cdots}Cl^-,$ play important roles on the reasonance stabilization of both the $C_6H_6{\cdot}I_2$ complex and the $C_6H_6{\cdot}ICl$ complex, the roles being more important in the latter complex than in the former complex.

  • PDF

Host-Guest Interactions of Cyclic and Acyclic Polyethers with Alkylammonium Ions (고리 및 비고리 폴리에테르와 알킬암모늄 이온과의 호스트-게스트 상호작용)

  • Jeong, Jong Hwa;Kim, Dae Yeon;Lee, Sim Seong
    • Journal of the Korean Chemical Society
    • /
    • v.38 no.7
    • /
    • pp.509-515
    • /
    • 1994
  • The interactions of 11 kinds of primary and secondary alkylammonium ions with cyclic (12C4, 15C5, 18C6, DT18C6 and DA18C6) and acyclic$(Q_2O_5)$ polyethers were investigated by NMR titration and conductometry. All of the alkylammonium ions under investigation form the relatively stable 1 : 1 complexes with crown ethers and acyclic polyether by H-bond. The interactions of alkylammonium ions with analogeous hosts having different size were in the order of 18C6 > 15C5 > 12C4, and the strengthes of donor atoms toward the alkylammonium ions were in the order of N > O > S. 18C6 forms more favorable interactions with primary alkylammonium ions than secondary alkylammonium ions, otherwise DA18C6 shows the opposite behaviors. The stability constants for complexations of 18C6 with the alkylammonium ions were determined conductometrically in methanol at 25$^{\circ}C$. The major factors affecting the stability of complexes were the type of alkylammonium ions, the length of alkyl-chain and the steric hindrance due to the structure of alkyl groups on complexation.

  • PDF

Molecular Species of Triglycerides in Watermelon Seed Oil (수박씨 기름의 triglyceride 분자종에 관한 연구)

  • Chun, Seok-Jo;Park, Yeung-Ho
    • Korean Journal of Food Science and Technology
    • /
    • v.19 no.4
    • /
    • pp.377-381
    • /
    • 1987
  • From the profiles of triglyceride composition and the fatty acid at ${\beta}-position$ of glycerol, triglyceride molecular species were found to be 26 kinds in watermelon seed oil. The major triglyceride molecular species in watermelon seed oil were $C_{18:1}{\cdot}C_{18:2}{\cdot}C_{18:1}$ OLO; 6.4%, $C_{18:0}{\cdot}C_{18:2}{\cdot}C_{18:2}$ SLL; 7.1%, $C_{18:1}{\cdot}C_{18:2}{\cdot}C_{18:2}$ OLL; 16.6%, $C_{16:0}{\cdot}C_{18:2}{\cdot}C_{18:2}$ PLL; 19.6% and $C_{18:2}{\cdot}C_{18:2}{\cdot}C_{18:2}$ LLL; 27.6%, Triglyceride molecular species of watermelon seed oil characterized that LLL species existed more than 27% of the total triglyceride molecular species.

  • PDF

Evaluating the Efficiency of the Device in Shielding Scattered Radiation during Treatment of Carcinoma of the Penis (음경암의 방사선치료 시 자체 제작한 Device의 산란선 차폐 효과에 대한 유용성 평가)

  • Gim, Yang-Soo;Lee, Sun-Young;Lim, Suk-Gun;Gwak, Geun-Tak;Pak, Ju-Gyeong;Lee, Seung-Hoon;Hwang, Ho-In;Cha, Seok-Yong
    • The Journal of Korean Society for Radiation Therapy
    • /
    • v.21 no.1
    • /
    • pp.9-15
    • /
    • 2009
  • Purpose: We evaluated the device that was created for maintaining the patient's setup and protecting the testicles from scattered radiation during treatment of carcinoma of the penis. Materials and Methods: The phantom testicles were made of vaseline cotton gauze and the device consisted of 5 mm of acryl box and 4 mm of lead shielding. $3{\times}3\;cm^2$, $4{\times}4\;cm^2$, $5{\times}5\;cm^2$, $6{\times}6\;cm^2$, $7{\times}7\;cm^2$ field sizes were used for this study and measurement was made at 4, 5, 6, 7, 8, 10 cm from the lower edge of the field for 10 times with lead shielding and without the shielding respectively. 200 cGy was delivered using 6 MV photons. Results: The scatted radiation without lead shielding at 4, 5, 6, 7, 8, 10 cm from the lower edge of the field were 14.8-4.7 cGy with $3{\times}3\;cm^2$, 15.7-5.2 cGy with $4{\times}4\;cm^2$, 17.6-5.5 cGy with $5{\times}5\;cm^2$, 19.9-6.6 cGy with $6{\times}6\;cm^2$, 22.2-7.6 cGy with $7{\times}7\;cm^2$ and the measured dose without lead shielding were 7.1-2.6 cGy with $3{\times}3\;cm^2$, 8.9-3.6 cGy with $4{\times}4\;cm^2$, 12.3-4.8 cGy with $5{\times}5\;cm^2$, 14.6-5.0 cGy with $6{\times}6\;cm^2$ and 21.1~6.4 cGy with $7{\times}7\;cm^2$. As shown above, the scatted radiation decreased after using lead shielding. Depending of the range of field sizes, the resulting difference between without shielding values and with shielding values were: 7.8-1.1 cGy at 4 cm, 5.1-1.2 cGy at 5 cm, 3.8-1.1 cGy at 6 cm, 3.4-1.7 cGy at 7 cm, 2.8-1.7 cGy at 8 cm, 2.4-2.5 cGy at 9 cm and 2.1-1.8 cGy at 10 cm. In the situation as described above, the range in values depending on the distance was 7.8-1.1 cGy with $3{\times}3\;cm^2$, 6.9-1.6 cGy with $4{\times}4\;cm^2$, 5.3-0.8 cGy with $5{\times}5\;cm^2$, 5.3-1.5 cGy with $6{\times}6\;cm^2$ and 1.1-1.8 cGy with $7{\times}7\;cm^2$. Conclusion: Using the device we created to shield the testicles from scattered radiation during treatment of carcinoma of the penis, we have found that scattered radiation to the testicles is decreased by the phantom testicles, and by increasing the distance between the testicles and penis.

  • PDF

Separation of $C_3H_6/C_3H_8$ by PEBAX-NaY Zeolite Composite Membranes (PEBAX-NaY Zeolite 복합막에 의한 $C_3H_6/C_3H_8$ 분리에 관한 연구)

  • Kim, Seul-Gi;Lee, Hyun-Kyung
    • Membrane Journal
    • /
    • v.25 no.1
    • /
    • pp.42-47
    • /
    • 2015
  • In this study, PEBAX[poly(ether-block-amide)]-NaY zeolite composite membranes were prepared, and those prepared membranes were studied on permeability of $C_3H_6$ and $C_3H_8$, and selectivity ($C_3H_6/C_3H_8$). NaY zeolite particles in PEBAX-NaY zeolite composite membranes was dispersed as aggregated particles with the size $0.5{\sim}2.5{\mu}m$ by SEM observation. TGA measurement showed the weight loss change resulted from the amount of NaY zeolite when NaY zeolite was added into PEBAX. By gas permeation experiment, the permeabilities of $C_3H_6$ and $C_3H_8$ were decreased by the more addition NaY zeolite in PEBAX. Overall, $C_3H_6$ was having higher permeability than $C_3H_8$. The selectivity $C_3H_6/C_3H_8$ was decreased by the more NaY zeolite in PEBAX.

The Complexes of Fluorobenzene with Halogens and Interhalogens in Carbon Tetrachloride (플루오로벤젠과 할로겐 또는 할로겐間化合物 사이의 錯物에 관한 연구)

  • Choi, Sang-Up;Han, Bong-Joo
    • Journal of the Korean Chemical Society
    • /
    • v.11 no.3
    • /
    • pp.89-93
    • /
    • 1967
  • The interactions of fluorobenzene with iodine monochloride, iodine monobromide, bromine and chlorine in carbon tetrachloride solution have been examined through ultraviolet spectrophotometric measurements. The results indicate the formation of one to one molecular complexes, $C_6H_5F{\cdot}ICl$, $C_6H_5F{\cdot}IBr$, $C_6H_5F{\cdot}Br_2$, and $C_6H_5F{\cdot}Cl_2$ in solution. The equilibrium constants obtained at room temperature for the formation of these four complexes are 0.161, 0.072, 0.045 and 0.035 l $mole^{-1}$, respectively. Comparison of these results with those reported in the literature on other complexes of similar type reveals that the relative stabilities of these complexes decrease in the following orders: ICl>IBr>$I_2$>$Br_2$>$Cl_2$ $C_6H_6$>$C_6H_5Br$>$C_6H_5Cl$>$C_6H_5F$

  • PDF

Structure of $[cis-ReCl_4(py)(N-C_6H_3-2,6-i-Pr_2)\cdot(NH_2-C_6H_3-2,6-i-Pr_2)]$ (py=pyridine) ($[cis-ReCl_4(py)(N-C_6H_3-2,6-i-Pr_2)\cdot(NH_2-C_6H_3-2,6-i-Pr_2)]$ 착물의 구조(py=pyridine))

  • 최남선;이순원
    • Korean Journal of Crystallography
    • /
    • v.10 no.2
    • /
    • pp.105-109
    • /
    • 1999
  • Ar 기류 하에서 Re(N-C6H3-2,6-i-Pr2)2Cl3(py) (1)과 propionaldehyde (C2H5CHO)가 반응하여 생성된 혼합물에서, [cis-ReCl4(py)(N-C6H3-2,6-i-Pr2)·(NH2-C6H3-2,6-i-Pr2)] (2)가 분리되었다. 이 화합물의 구조가 X-ray 회절법으로 규명되었다. 착물 2의 결정학 자료: 단사정계 공간군 P21/n, a=11.555(1) Å, b=27.066(3) Å, c=11.881(1) Å, β=117.991(8)°, Z=4, R(wR2)=0.0332(0.0851.

  • PDF