• Title/Summary/Keyword: CO conversion

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Conversion Characteristics of CH4 and CO2 in an Atmospheric Pressure Plasma Reactor (대기압 플라즈마 반응기에서의 CH4와 CO2의 전환처리 특성)

  • Kim, Tae Kyung;Lee, Won Gyu
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.653-657
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    • 2011
  • Conversion characteristics of $CH_4$ and $CO_2$ was studied using an atmospheric pressure plasma for the preparation of synthesis gas composed of $H_2$ and CO. The effects of delivered power, total gas flow rate, and gas residence time in the reactor on the conversion of $CH_4$ and $CO_2$ were evaluated in a plasma reactor with the type of dielectric barrier discharge. The increase of reactor temperature did not affect on the increase of conversion if the temperature does not reach to the appropriate level. The conversion of $CH_4$ and $CO_2$ largely increased with increasing the delivered power. As the $CH_4/CO_2$ ratio increased, the $CH_4$ conversion decreased, whereas the $CO_2$ conversion increased. Generally, the $CH_4$ convesion was higher than the $CO_2$ conversion through the variation of the process parameters.

CO2 conversion technology for CO gas synthesis using coal (석탄을 사용한 CO가스 제조를 위한 CO2 전환기술)

  • Lee, Ho-Yong;Park, Ji-Yong;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.4
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    • pp.712-717
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    • 2015
  • In this study, the experiment of CO production was performed using carbon dioxide and coal. The synthesis characteristics of CO gas was investigated using the chemical activation method of KOH. The preparation process has been optimized through the analysis of experimental variables such as activating chemical agents to coal ratio, the flow rate of gas and reaction temperature during $CO_2$ conversion reaction. Without the catalyst of KOH, the 66.7% of $CO_2$ conversion was obtained at the conditions of $T=950^{\circ}C$ and $CO_2$ flow rate of 300 cc/min. On the other hand, the 98.1% of $CO_2$ conversion was obtained using catalyst of KOH at same conditions. It was found that the feed ratio(Coal : KOH = 4 : 1) had better $CO_2$ conversion and CO selectivity than other feed ratios.

Effects of Operating Variables on CO Conversion of WGS Catalyst in a Fluidized Bed Reactor Equipped with Bed Insert (내부 삽입물을 적용한 유동층 반응기에서 WGS 촉매의 CO 전화율에 미치는 조업변수들의 영향)

  • Park, Jihye;Lee, Dongho;Park, Youngeheol;Moon, Jongho;Rhee, Youngwoo;Ryu, Hojung
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.2
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    • pp.209-217
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    • 2014
  • To enhance the performance of SEWGS system by holding the WGS catalyst in a SEWGS reactor, a spring type bed insert was developed. In this study, effects of operating variables such as steam/CO ratio, gas velocity, syngas concentration on CO conversion were investigated in a fluidized bed reactor using the spring type bed insert to hold the WGS catalyst as tablet shape. CO conversion increased initially as the steam/CO ratio increased. But further increment of the steam/CO ratio caused decreasing of CO conversion because of increment of gas velocity and decrement of syngas concentration. Moreover, CO conversion decreased as the gas velocity increased and the syngas concentration decreased at the same steam/CO ratio. Continuous operation up to 48 hours (2 days) was carried out to check reactivity decay of WGS catalyst supported by spring type bed insert. The average CO conversion was 99.04% and we could conclude that the WGS reactivity at those conditions was maintained up to 48 hours.

Co-doping Effects on the Blue Up-conversion Characteristics of Fluoride Glasses (희토류 원소의 복합첨가에 의한 fluride 유리에서의 청색 상향전이현상)

  • 류선윤
    • Journal of the Korean Ceramic Society
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    • v.37 no.1
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    • pp.33-43
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    • 2000
  • Up-conversion of rare-earth element added glass is promising area for short wavelength laser source by utilizing high power semiconductor infra-red laser if the efficiency can be increased by proper method. In this study, relatively low phonon energy fluoride glasses were prepared by co-doping rare-earth elements to realize the high efficiency up-convertor. The physical, chemical, andoptical properties of co-doped fluoride glasses were measured. 10 combinations of 5 different rare-earth fluoride elements doped samples were prepared and their transition temperatures, chemical durability, density, hardness, refractive index, absorption, fluorescence, and fluorescence lifetime were measured. 480nm wavelengths blue up-conversion was found in the Yb3+/Tm3+ co-doped glass sample with 800nm laser source and the optimum composition for the most efficient blue up-conversion was found from the glass sample with 0.3 mol% TmF3 and 1 mol% YbF3.

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Conversion Characteristics of Warm-up Catalytic Converter for the Diesel Vehicle (디젤자동차용 웜업 촉매 시스템의 정화 특성)

  • Choi Byungchul;Juhng Woonam;Yoon Youngbae;Jung Myunggun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.3
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    • pp.80-86
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    • 2005
  • In this study, we investigated the characteristics of the conversion efficiency and the effect of ageing Diesel Oxidation Catalyst (DOC). The DOC was composed of Warm-up Catalytic Converter (WCC) and Underbody Catalytic Converter (UCC). As the result, the conversion efficiency of THC was 10$\~$50$\%$ on WCC and 30$\~$40$\%$ on UCC .The conversion efficiency of CO was 80$\~$90$\%$ on WCC and remained 10$\~$20$\%$ of CO was purified on UCC. The WCC shows high conversion efficiency on CO. After 20 hours aging process of engine bench, conversion efficiencies of THC and CO were improved a little, because it was activated catalyst surface by 20 hours aging. In case of 80 hours aging, the conversion efficiencies of THC and CO were decreased on WCC. However, the UCC was not affected by aging process .

Preliminary Design of the Supercritical $CO_2$ Brayton Cycle Energy Conversion System (초임계 이산화탄소 Brayton 에너지 전환계통 예비설계)

  • Cha, Jae-Eun;Eoh, Jae-Hyuk;Lee, Tae-Ho;Sung, Sung-Hwan;Kim, Tae-Woo;Kim, Seong-O;Kim, Dong-Eok;Kim, Moo-Hwan
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3181-3188
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    • 2008
  • The supercritical $CO_2$ Brayton cycle energy conversion system is presented as a promising alternative to the present Rankine cycle. The principal advantage of the S-$CO_2$ gas is a good efficiency at a modest temperature and a compact size of its components. The S-$CO_2$ Brayton cycle coupled to a SFR also excludes the possibilities of a SWR (Sodium-Water Reaction) which is a major safety-related event, so that the safety of a SFR can be improved. KAERI is conducting a feasibility study for the supercritical carbon dioxide (S-$CO_2$) Brayton cycle power conversion system coupled to KALIMER(Korea Advanced LIquid MEtal Reactor). The purpose of this research is to develop S-$CO_2$ Brayton cycle energy conversion systems and evaluate their performance when they are coupled to advanced nuclear reactor concepts of the type under investigation in the Generation IV Nuclear Energy Systems. This paper contains the research overview of the S-$CO_2$ Brayton cycle coupled to KALIMER-600 as an alternative energy conversion system.

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CO Conversion Characteristics of WGS Catalysts for SEWGS System (SEWGS 시스템을 위한 WGS 촉매들의 CO 전환 특성)

  • Ryu, Hojung;Park, Jihye;Lee, Dongho;Park, Jaehyeon;Bae, Dalhee
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.2
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    • pp.96-104
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    • 2015
  • Reactivity of commercial WGS catalyst and four new catalysts(RMC-3, PC-73, PC-67SU, PC-59) manufactured with various compositions by Korea Electric Power Research Institute(KEPCO RI) were compared to select suitable WGS catalyst for SEWGS system. Steam/CO ratio, gas velocity, flow rates of syngas, and temperature were considered as operating variables. As a result, commercial catalyst showed the highest CO conversion and RMC-3 catalyst showed also high CO conversion. Therefore, commercial and RMC-3 catalysts were selected as applicable catalysts. However, PC-73 catalyst showed low CO conversion at low temperature($200^{\circ}C$) but showed good reactivity at high temperature($225{\sim}250^{\circ}C$), and therefore, PC-73 catalyst was selected as applicable catalyst for high temperature operation. Continuous operations up to 24 hours for those three catalysts(commercial, RMC-3, PC-73) were conducted to check reactivity decay of catalysts. All three catalysts maintained their original reactivity.

Study of the Increase of Conversion Efficiency of $CO_2$ by Discharge Plasmas (방전 플라즈마에 의한 이산화탄소 전환 효율 상승에 관한 연구)

  • Cho, Moon-Soo;Kwak, Dong-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.904-907
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    • 2002
  • In this study, the plasma-assisted $CO_2$ conversion characteristics were investigated in the streamer corona discharge and silent discharge reactors with dielectric of $Al_2O_3$, to improve the conversion efficiency $CO_2$. Some discharge characteristics of $CO_2$ as parameters of gap spacing and applied voltage frequency, in both corona and silent discharge reactor were also obtained. The maximum $CO_2$ conversion rate was 10.1 [%] under the 5.2 [W] of discharge power and 250 [Hz] of applied voltage frequency.

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Conversion of $CO_2$ and $CH_4$ to Syngas by Making Use of Microwave Plasma Torch (전자파 플라즈마 토치를 이용한 이산화탄소와 메탄의 Syngas 합성)

  • Dong Hun, Shin;Yong Cheol, Hong;Han Sup, Uhm
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2004.11a
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    • pp.195-200
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    • 2004
  • Carbon dioxide ($CO_2$) and methane (CH$_4$) are two major greenhouse Bases. $CO_2$is a stack gas of many industrial processes and the main product of the hydrocarbon combustion. There is recent research interest on the synthesis gas (syngas) formation from $CO_2$ and CH$_4$, via the following reaction: CH$_4$+$CO_2$longrightarrow 2H$_2$+$CO_2$, in order to reduce the greenhouse effects and to synthesize various chemicals, Preliminary experiments were conducted on the conversion of $CO_2$ and CH$_4$ to syngas by making use of a microwave plasma torch at atmospheric pressure. Conversion rates of $CO_2$and CH$_4$ to hydrogen (H$_2$), carbon monoxide (CO) and higher hydrocarbons were investigated using Gas Chromatography (GC) and Fourier Transform Infrared (FTIR). The experimental data indicate that the main products were H$_2$, CO and small amount of higher hydrocarbons, such as ethylene (C$_2$H$_4$).

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Implementation of Multi Session PDF Converter Using Automated Scripts for Windows (윈도우즈 자동화 스크립트를 이용한 멀티 세션 PDF 변환기 구현)

  • Kang, Byeong-Jun;Kim, Hun-Hee;Joo, Sang-Woong;Shim, Kyou-Chul;Kang, Hyun-Jin;Kim, Kyung-Hwan;Jeong, Hoe-Kyung
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2013.10a
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    • pp.643-645
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    • 2013
  • When you convert word processor files with large amounts of input data to PDF files in on/off line, current PDF conversion solutions do one of the source files to perform the conversion task in the Windows PDF virtual printer environment. Depending on the size of the original PDF file conversion speed to convert PDF to do a large amount of different and if you are performing a very slow speed. When you convert files to PDF in this sequence, depending on the capacity of the original file, PDF conversion rate is different, if automating a mass conversion to the PDF, the speed is very slow. In this paper, the PDF conversion which can use the Windows Terminal Server from one Windows Server when performing a PDF conversion processing of the source file, to create a multi-session Terminal, to perform the PDF conversion process at the same time was studied.

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