• Journal of environmental and Sanitary engineering
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• v.12 no.3
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• pp.73-79
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• 1997

This research was intended as an investigation of applying Reduced Pressure Evaporation as efficient treatment method for landfill leachate. According to the variance of time, temperature, pressure and pH in experiments, the properties of leachate treatment are follows. The removal efficiencies of COD, NH$_{3}$-N, TOC, Conductivity and SS on the basis of reaction time was 96.4%-97.5%, -1.4%-53.7%, 81.7%-89.0%, 92.0%-95.3% and 99.86%-99.97%, respectively. When the pH of Influent was 7.5, the pH of effluent was increased to 10-11 with time elapse. It is concluded that the orgin of pH increase may be ammonia. When the properties of concentrate were investigated at the concentration ratio 90%(V/V), concentration difficiency represented in the ratio of experimental value/calculated value had following orders ; COD>TOC>NH$_{3}$-N>Conductivity>SS. Concentrate had good precipitation because of additive thermal treatment in the process. When evaporation experiments with pH adjustment of 4.0, 6.0, 7.5, 9.0 and 10.0 were performed ; Acidic evaporation experiments(pH 4.0, 6.0) showed low removal efficiency(81.6, 87.6%) of COD and high removal efficiency (97.5%. 84.6%) of NH$_{3}$-N at initial evaporation. Basic evaporation(pH 9.0, 10.0) showed high removal efficiency (97.2%, 98.9%) of COD and very low removal efficiency (-7.4%, -27.2%) of NH$_{3}$-N at initial evaporation.

• Journal of Wetlands Research
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• v.11 no.3
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• pp.37-47
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• 2009

This research was conducted at the constructed wetland in Goheung reclaimed land, and water quality components were measured at the 12 points in 15 March 2008 and 10 January 2009, respectively. Temperature, pH, DO, EC and salinity components were measured at the field, and TOC, Cl-, COD, TSS, T-P and TN components were analyzed laboratory. Concentrations of field measured components at inflow points were higher than in constructed wetland. TOC concentration ratio of inflow water to constructed wetland water was higher in January, and Cl concentration ratio of it was higher in March. And, COD concentration ratio of it were 1.37 for March and 1.49 for January, respectively. T-P and T-N concentration ratios of it at inflow points were higher 3 times than in constructed wetland. Constructed wetland attenuated concentration of contaminated components inflow to it. Removal efficiencies of Cl-, T-P and T-N components in inflow water were high at the constructed wetland. removal efficiencies of Cl component were 83% for 1st monitoring and 76% for 2nd monitoring, this removal efficiency be caused by dilution effect of constructed wetland. removal efficiencies of T-P component were 67% for 1st monitoring and 69% for 2nd monitoring, and they of T-N component were 100% for 1st monitoring and 95% for 2nd monitoring. Abnormal removal efficiency of T-N component is caused that nitrogen in inflow water was a little. Removal efficiency of T-P component was higher in January, and T-N component was higher in March. This is caused by environmental difference between growing season and winter.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.10
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• pp.703-709
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• 2013

Ozonation was performed under various experimental conditions that $Al_2O_3$ catalysts dosage and temperature for removal of DMP in laboratory scale batch reactor. Flow rate of ozone $1.0Lmin^{-1}$ and ozone concentration of $300{\pm}10mgL^{-1}$ were maintained constantly, and the pH, $COD_{Cr}$ and TOC was measured in 10 min intervals during the 60 min at oxidation processes. As a result, the presence of the $Al_2O_3$ than only ozonation increased the removal efficiency of both $COD_{Cr}$ and TOC in solution. The pseudo first-order rate constants for the elimination of $COD_{Cr}$ and TOC were $3.65{\times}10^{-4}sec^{-1}$, $2.52{\times}10^{-4}sec^{-1}$, and activation energy was $0.75kcal{\cdot}mol^{-1}$ and $0.70kcal{\cdot}mol^{-1}$ at $20^{\circ}C$, respectively.

• Journal of Korean Society on Water Environment
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• v.33 no.6
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• pp.736-743
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• 2017

In this study, 4-nonylphenol (4-NP), an endocrine disrupting chemical, was removed by ozone treatment processes under the various experimental conditions including UV irradiation, $TiO_2$ addition. The ozone flow rate and concentration were maintained at $1.0L{\cdot}min^{-1}$ and $70{\pm}5mg{\cdot}L^{-1}$. The pH, COD and TOC of the samples were obtained every 10 minutes for 60 minutes in laboratory scale batch reactor. We found that the combination of UV irradiation and $TiO_2$ addition for ozonation improves the removal efficiency of COD and TOC in 4-NP aqueous solution. In case of the $O_3/UV/TiO_2$ system, COD and TOC were greatly reduced to 85.3 ~ 94.0% and 89.2 ~ 97.2%, respectively. 4-NP degradation rate constants, $k_{COD}$ and $k_{TOC}$, were calculated based on the COD and TOC values. Significantly, $k_{COD}$ and $k_{TOC}$ were improved in the $O_3/UV/TiO_2$ treatment process compared with single $O_3$ process, because the oxidation and the mineralization of 4-NP were increased by generating of the hydroxyl radical. The $k_{COD}$ and $k_{TOC}$ were obtained to be $5.81{\times}10^{-4}{\sim}10.8{\times}10^{-4}sec^{-1}$ and $11.9{\times}10^{-4}{\sim}19.4{\times}10^{-4}sec^{-1}$ in the $O_3/UV/TiO_2$ process. Activation energy ($E_a$) of ozone oxidation reaction based on $k_{COD}$ and $k_{TOC}$ were increased in order of $O_3/UV/TiO_2$ < $O3/UV$ < $O_3/TiO_2$ < $O_3$ process. It was confirmed that the addition of $TiO_2$ and UV irradiation to the ozone oxidation reaction significantly reduced the $E_a$ value and the degradation of 4-NP.

• Journal of environmental and Sanitary engineering
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• v.13 no.2
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• pp.106-114
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• 1998

This study was carried out for the purpose of industrial reuse of effluent released from activated sludge unit by $\gamma $-ray irradiation technique. The dissolved organic carbon in the effluent of an activated sludge unit is mostly refractory or inert material which are difficult to be degraded by micro organism. The effluent generated from activated sludge unit was irradiated with Co$^{60}$ $\gamma $-ray under condition of air bubbling. The effects of irradiation on the pH, COD, TOC, color, molecular weight distribution were investigated by membrane filtration and u.v.-spectrum analysis. With increasing dose, the TOC was decreased smoothly. The COD was increased at lower dose, while the COD was decreased at higher dose. The TOC and COD, however, were decreased smoothly when TiO$_{2}$ was added to the solution. It was thought that the differential decreasing trend of COD and TOC in according to the absence or presence of TiO$_{2}$ was due to the molecular weight distribution shifted from group of higher molecular weight to group of lower one which are more easy to be decomposed. The removal efficiency of color was 71.5% and it was increased to 85.7% when TiO$_{2}$ was added to the solution. The $\gamma $-ray irradiation was effective on the production of chlorine.

• Korean Journal of Environmental Agriculture
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• v.25 no.2
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• pp.129-137
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• 2006

A study was conducted to investigate the behavior of pollutant forms at each area in the sewage treatment plant by natural purification method. The sewage treatment plant by natural purification method that consisted of aerobic and anaerobic area was constructed. The efficiency of sewage treatment depending on the operation time, the loading amount of pollutant season variation were investigated. The removal amount of BOD, COD, TOC and SS in the aerobic area was significantly increased as the treatment proceeded. Decreased BOD, COD, TOC, SS, T-N and T-P depending on the loading amount of pollutants in the aerobic and ananerobic area were mostly insoluble BOD (IBOD), insoluble COD (ICOD), soluble TOC (STOC), volatile SS (VSS), dissolved T-N (DTN) and dissolved T-N (DTP) types, respectively. The removal efficiency of BOD, COD, TOC, SS, T-N and T-P in hot season (summer and autumn) were more than that in cold season (spring and winter). The removal efficiencies of BOD, COD, TOC, SS, T-N and T-P of the effluent were about 92, 89, 73, 95, 46 and 84% in all seasons, respectively.

• Journal of Environmental Science International
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• v.5 no.1
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• pp.51-59
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• 1996

The purpose of this study was to evaluate the partial oxidation of the biological treatment plant effluents using Fenton's reagent as a pretreatment step prior to a tertiary biological oxidation of these effluents. Fenton's reagent was evaluated as a pretreatment process for inhibitory or refractory organics. Based on the Fenton oxidation system, the petrochemical wastewater treatment plant effluent was shown to have significant improvement in toxicity after oxidation with hydrogen peroxide. For example, at ranee of 42 ∼ 184 mg/L COD of petrochemical plant effluents, the COD removal efficiencies were from 38.2% to 60.1% after reaction with hydrogen peroxide 200 mg/L and Fe2+ 100 mg/L and reaction time was 30 minutes. The total TOC reduction were about 15.8∼22.4% with same test condition and difference between the overall removal rate and BOD/COD ratio after Fenton's oxidation estabilished in the biodegradation and otherwise meets the discharge standard or reuse for cooling tower make-up water.

• Journal of Environmental Health Sciences
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• v.31 no.5 s.86
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• pp.404-410
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• 2005

The pH efforts on the removal of 1,4-dioxane and the biodegradobility enhancement of dioxane contaminated water were investigated using $O_3/H_2O_2$ baled advanced oxidation process. Experiments were conducted using a bubble column reactor under different initial pH. The $O_3/H_2O_2$ process effectively converted 1,4-dioxane to more biodegradable intermediates which had a maximum $BOD_5$ enhancement at pH 11 within the experimental range, precisely, when the initial pH increased, $BOD_5$ enhanced. However, in case of removal efficiencies of 1,4-dioxane during $O_3/H_2O_2$ oxidation the optimum condition was shown at pH 9 compared with pH 6 and 11. TOC and COD values were not largely changed for all reaction time. From the results of 1,4-dioxane removal efficiency, TOC, COD, and $BOD_5$ enhancement with reaction time, it was surely observed that 1,4-dioxane was just converted to biodegradable materials, not completely oxidized to carbon dioxide.

• Microbiology and Biotechnology Letters
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• v.24 no.5
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• pp.597-603
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• 1996

This study was carried out to examine degradation characteristics of microalgae Chlorella vulgaris in methane fermentation. We measured COD and VS reduction, gas and methane productivity, VFA (volatile fatty acid), respectively. Then we calculated material balance and hydrolysis rates in soluble and solid material. The substrate concentration was controlled from 14 gCOD$_{cr}$/l to 64 gCOD$_{cr}$/l in batch cultures, and HRT (hydraulic retention time) controlled from 2 days to 30 days in continuous experi- ments. The results were as follows. In batch culture, accumulated gas productivity increased with the increase of the substrate concentration. The SS and VSS was removed all about 30% increase of substrate concentration and the most of the degradable material removed during the first 10 days. The curve of gas and methane production rate straightly increased until substrate concentration is 26 gCOD$_{cr}$/l. In continuous culture experiments, the removal rates at HRT 10days were 20% for total COD and TOC, respectively. At longer HRT, there was no increase in the removal efficiency. At HRT 15 days, the removal rates were 30% for SS and VSS, respectively. Soluble organic materials were rapidly degraded, and so there was no accumulated. Soluble COD concentration was not increase regardless of HRT-increasing. That meaned the hydrolysis was one of the rate-limiting stage of methane fermentation. The first-order rate constants of hydrolysis were 0.23-0.28 day$^{-1}$ for VSS, and 0.07-0.08 day$^{-1}$ for COD.

• Journal of Environmental Science International
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• v.26 no.3
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• pp.401-410
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• 2017

This study analyzed the changes in the concentrations of organic matters in constructed treatment wetlands, coming from discharge water from a sewage treatment plant and non-point pollutant sources during rainfall events. At the beginning of a rainfall event, a massive amount of particulate organic matter flowed in, and was removed from the sedimentation basin (S1, S2); dissolved organic matter was removed after passing through stepwise treatment processes in the wetland. During dry period in the wetland, the removal efficiency rate for COD and TOC was -21 and -7%, respectively; during the rainfall event, the removal efficiency rate for COD and TOC were 47 and 43%, respectively. The highly-concentrated organic matters that flowd in at the beginning of the rainfall event was stabilized by various structures in the wetland before water discharge. Cyanobacteria blooms annually at the confluence of the So-ok stream and Daecheong Lake. Therefore, it is expected that the wetland will contribute significantly to reducing cyanobacteria and improving water quality in the area.