• Applied Chemistry for Engineering
• /
• v.35 no.1
• /
• pp.48-53
• /
• 2024

We predicted the calendar aging and long-term lifetime of lithium-ion batteries using an electrochemical-based SEI growth model. Numerical simulation was carried out employing the four different long-term SEI growth models (i.e., solvent diffusion limited model, electron migration limited model, Li-interstitial diffusion limited model, reaction limited model), and we calculated the capacity fade and loss of lithium inventory during calendar aging. The result showed that the electron migration limited model and Li-interstitial diffusion limited model showed lower capacity fade, while the solvent diffusion limited model and reaction limited model reached 80% of capacity fade within 10 years. During calendar aging, the lower storage temperature showed less capacity fade due to the hindrance of SEI growth rate. During cycling, the higher C-rate showed a shorter life cycle; however, the differences were not significant.

• ETRI Journal
• /
• v.45 no.5
• /
• pp.768-780
• /
• 2023

The application of unmanned aerial vehicles (UAVs) has recently attracted considerable interest in various areas. A three-dimensional multiple-input multiple-output concentric two-hemisphere model is proposed to characterize the scattering environment around a vehicle in an urban UAV-to-vehicle communication scenario. Multipath components of the model consisted of lineof-sight and single-bounced components. This study focused on the key parameters that determine the scatterer distribution. A time-variant process was used to analyze the nonstationarity of the proposed model. Vital statistical properties, such as the space-time-frequency correlation function, Doppler power spectral density, level-crossing rate, average fade duration, and channel capacity, were derived and analyzed. The results indicated that with an increase in the maximum scatter radius, the time correlation and level-crossing rate decreased, the frequency correlation function had a faster downward trend, and average fade duration increased. In addition, with the increase of concentration parameter, the time correlation, space correlation, and level-crossing rate increased, average fade duration decreased, and Doppler power spectral density became flatter. The proposed model was compared with current geometry-based stochastic models (GBSMs) and showed good consistency. In addition, we verified the nonstationarity in the temporal and spatial domains of the proposed model. These conclusions can be used as references in the design of more reasonable communication systems.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.57 no.5
• /
• pp.839-844
• /
• 2008

A novel state of health estimation method for hybrid electric vehicle lithium battery using sliding mode observer has been presented. A simple R-C circuit method has been used for the lithium battery modeling for the reduced calculation time and system resources due to the simple matrix operations. The modeling errors of simple model are compensated by the sliding mode observer. The design methodology for state of health estimation using dual sliding mode observer has been presented in step by step. The structure of the proposed system is simple and easy to implement, but it shows robust control property against modeling errors and temperature variations. The convergence of proposed observer system has been proved by the Lyapunov inequality equation and the performance of system has been verified by the sequence of urban dynamometer driving schedule test. The test results show the proposed observer system has superior tracking performance with reduced calculation time under the real driving environments.

• Journal of Communications and Networks
• /
• v.5 no.2
• /
• pp.104-115
• /
• 2003

It is well known that Multiple Input Multiple Output (MIMO) systems offer the promise of achieving very high spectrum efficiencies (many tens of bit/s/Hz) in a mobile environment. The gains in MIMO capacity are sensitive to the presence of spatial and temporal correlation introduced by the radio environment. In this paper, we examine how MIMO capacity is influenced by a number of factors e.g., a) temporal correlation b) various combinations of low/high spatial correlations at either end, c) combined spatial and temporal correlations. In all cases, we compare the channel capacity that would be achievable under independent fading. We investigate the behaviour of "capacity fades," examine how often the capacity experiences the fades, develop a method to determine level crossing rates and average fade durations and relate these to antenna numbers. We also evaluate the influence of channel correlation on the capacity autocorrelation and assess the fit of a Gaussian random process to the temporal capacity sequence. Finally we note that the particular spatial correlation structure of the MIMO channel is influenced by a large number of factors. For simplicity, it is desirable to use a single overall correlation measure which parameterizes the effect of correlation on capacity. We verify this single parameter concept by simulating a large number of different spatially correlated channels.

• Journal of electromagnetic engineering and science
• /
• v.5 no.1
• /
• pp.1-7
• /
• 2005

The implementation of a simple analog in-phase combiner is presented for a high capacity radio relay system with space diversity. It provides good performance in terms of simple hardware and easy control, and measured results are in good agreement with simulated ones. To suggest practical applications, signatures with/without diversity are measured for STM-1 signal of 64-QAM radio relay system combined with a 13-tap equalizer, and they provided more than 25 dB fade depth at 10$^{-3}$ BER under the frequency selective fading condition.

• Korean Chemical Engineering Research
• /
• v.46 no.1
• /
• pp.131-136
• /
• 2008

Silica- or titania-filled poly (vinylidene fluoride-co-hexafluoropropylene)-based polymer electrolytes were prepared by phase inversion technique using N-methyl-2-pyrrolidone and dimethyl acetamide as solvent and water as non-solvent. The polymer electrolytes were adopted to the lithium metal polymer battery using high-capacity cathode $Li[Ni_{0.15}Co_{0.10}Li_{0.20}Mn_{0.55}]O_2$ and lithium metal anode. After the repeated charge-discharge test for the cell, it was proved that the cell adopting the polymer electrolyte based on the phase-inversion membrane containing 40~50 wt% silica showed the highest discharge capacity (180 mAh/g) until 80th cycle and then abrupt capacity fade was just followed. The capacity fade might be due to the deposition of lithium dendrite on the polymer electrolyte, in which the capacity retention was no longer sustainable.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.9
• /
• pp.2519-2526
• /
• 2010

Silane-based self-assembly was employed for the surface modification of carbon-coated Si electrodes and their surface chemistry and electrochemical performance in battery electrolyte depending on the molecular structure of silanes was studied. IR spectroscopic analyses revealed that siloxane formed from silane-based self-assembly possessed Si-O-Si network on the electrode surface and high surface coverage siloxane induced the formation of a stable solid-electrolyte interphase (SEI) layer that was mainly composed of organic compounds with alkyl and carboxylate metal salt functionalities, and PF-containing inorganic species. Scanning electron microscopy imaging showed that particle cracking were effectively reduced on the carbon-coated Si when having high coverage siloxane and thickened SEI layer, delivering > 1480 mAh/g over 200 cycles with enhanced capacity retention 74% of the maximum discharge capacity, in contrast to a rapid capacity fade with low coverage siloxane.

• Journal of Electrical Engineering and Technology
• /
• v.9 no.1
• /
• pp.98-105
• /
• 2014

As environmentally friendly energy takes center stage, interests for Electric Vehicles/Plug in Hybrid Electric Vehicles (EVs/PHEVs) are getting increase. With this trend, there is no doubt EVs will take large portion to penetrations of total cars. Therefore, accurate EV modeling is required. Battery is one of the main components with the power system view of aspect. Hence, in this paper, reviews and discussions of some types of batteries for EV are contained by considering energy density and weight of the batteries. In addition, simulations of Li-Ion battery are accomplished with various variables such as temperature, capacity fading and charge/discharge current. It is confirmed that temperature is the main factor of capacity fading. Validation of the modeled battery is also conducted by comparing it with commercialized battery.

• Korean Journal of Materials Research
• /
• v.19 no.10
• /
• pp.517-521
• /
• 2009

Si-C composite with hollow spherical structure was synthesized using ultrasonic treatment of organosilica powder formed by hydrolysis of phenyltrimethoxysilane. The prepared powder was pyrolyzed at various temperatures ranging from 900 to 1300 $^{\circ}C$ under nitrogen atmosphere to obtain optimum conditions for Li-ion battery anode materials with high capacity and cyclability. The XRD and elemental analysis results show that the pyrolyzed Si/C composite at 1100 $^{\circ}C$ has low oxygen and nitrogen levels, which is desirable for increasing the electrochemical capacity and reducing the irreversible capacity of the first discharge. The solid Si-C composite electrode shows a first charge capacity of $\sim$500 mAhg$^{-1}$ and a capacity fade within 30 cycles of 0.93% per cycle. On the other hand, the electrochemical performance of the hollow Si-C composite electrode exhibits a reversible charge capacity of $\sim$540 mAhg$^{-1}$ with an excellent capacity retention of capacity loss 0.43% per cycle up to 30 cycles. The improved electrochemical properties are attributed to facile diffusion of Li ions into the hollow shell with nanoscale thickness. In addition, the empty core space provides a buffer zone to relieve the mechanical stresses incurred during Li insertion.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.29 no.9C
• /
• pp.1279-1288
• /
• 2004

In this paper, the DMR(Digital Microwave Radio) system-based OFDM(Orthogonal Frequency Division Multiplexing) scheme in microwave channel environments has been proposed and system performances have been evaluated. The existing single carrier DMR system has a complex system structure due to using high-level QAM(Quadrature Amplitude Modulation) modulation scheme and so charmel capacity is limited by sensitive effects from fading. Therefore, in the proposed DMR system, it uses that the OFDM scheme for enhancement of fading distortion and also uses that the band-limited pulse shaping filter instead of windowing for no additional data such as GI/GB and for using efficient of IFFT/FFT block. The performance of OFDM/QPSK-DMR system and single carrier DMR system are analysed by computer simulation using two-ray model under the microwave channel environments The computer simulation results confirm that the fade margin of the proposed OFDM/QPSK-DMR system is highly increased as the number of sub-carriers is larger.