• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.181-186
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• 2004

Catalytic combustion is one of the suitable methods which is applicable to micro heat source due to high energy density and no flame quenching. And hydrogen can be oxidized at room temperature with platinum catalyst. So hydrogen-fueled micro catalytic combustor with platinum catalyst can be good and easy-handling heat source for another micro devices. In this work we focused on general catalytic combustion characteristics of hydrogen-air premixed gas in 10mm scale catalytic combustor for the further application to micro scale. Platinum was coated on dense ceramic monolith which can be installed in simple-structured catalytic combustor. We investigated the effect of flow rate, heat loss and platinum percentage in catalyst-coated monolith on catalytic combustion performance by temperature distribution in the combustor. By those results we confirmed catalytic reactivity and estimated reaction area. And we simulated micro scale catalytic reaction by sliced monolith. The results of this work will be important design factors for micro scale catalytic combustor.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.677-682
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• 2001

Catalytic combustion is the environmental-friendly technology, which has been applied to a variety of areas for industrial and domestic use in recent years. Accordingly, this study performed the development of the catalytic manufacturing technology for the high temperature and of the catalytic combustor in priority, which were aimed to be applied to a commercialized boiler. Paliadium(Pd) of a noble metal was used as a catalyst for the high temperature and supported on alumina($Al_[2}O_{3}$) and zirconia($ZrO_{2}$) in constant weight ratio. Activity of Pd catalysts is compared and analyzed in the catalytic combustion of natural gas. The ratio of $Pd/Al_{2}O_{3}=4$ was found to be better than any other weight ratios in activity and durability. The performance examination of catalysts and of combustion through the plate-type combustor made it possible to be developed the cylindrical-type combustor which has increased combustion area. Catalytic combustion boiler of 25,000 kcal/hr class was also developed, which had the optimum combustion condition at the nozzle of 5.95mm and the orifice of 21mm. This condition was determined through the performance experiments of catalytic combustion boiler to which the cylindrical-type catalytic combustor was applied.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.12
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• pp.1681-1690
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• 1998

The aim of this paper is to investigate combustion characteristics of lean premixed mixture stabilized by catalytic surface reaction. The catalytic combustor consisted of a catalyst bed and a thermal combustor. The catalyst bed was made of two stage, Pd catalyst in the first stage and Pt catalyst in the second stage. Auto ignition of lean mixture took place in the thermal combustor. Ignition temperature was about $810{\sim}820^{\circ}C$ at the fuel-air ratio of 1.5~3.0 % and the mixture velocity of 11~18m/sec. The position of flame front in the thermal combustor moved toward back as preheat temperature increased and fuel-air ratio decreased. The f1ame supported by surface reaction was stabilized without any flame stabilizers. NOx emissions from the catalytic combustor were below 2.0 ppm ($O_2$ 15 %) when gas temperature was limited below $1350^{\circ}C$. This result demonstrates that NOx emission from the catalytic combustor is much low comparing with conventional combustors.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.05a
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• pp.247-250
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• 2009

The catalytic combustor has the advantage of stable combustion under very lean conditions with low emissions of $NO_x$, CO and unburned hydrocarbon(UHC). Notwithstanding these advantages, the commercial application of the catalytic combustion has been delayed due to the complicated reaction process. For the stable operation of catalytic combustor, study on the combustion characteristics of the catalytic combustor is needed. So, in this study, numerical study on the propane combustion characteristics of the catalytic combustor with Pd-based catalyst is performed.

• Journal of the Korean Society of Combustion
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• v.19 no.4
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• pp.49-55
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• 2014

Design criterion for the size of micro Pt-catalytic combustor is investigated in terms of heat release rate. One-dimensional plug flow model is applied to determine the surface reaction constants using the experimental data at stoichiometric butane-air mixture. With these reaction constants, the mass fraction of butane and heat release rate predicted by the plug flow model are in good agreement with the experimental data at the combustor exit. The relationship between the size of micro catalytic combustor and mixture flowrate is introduced in the form of product of two terms-the effect of fuel conversion efficiency, and the effect of chemical reaction rate and mass transfer rate.

• Journal of the Korean Society of Combustion
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• v.10 no.3
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• pp.17-24
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• 2005

A sub-millimeter scale catalytic combustor with a simple plate-shaped combustion chamber was fabricated. A porous ceramics support coated with platinum catalyst was placed in the chamber. The combustor has a gallium arsenide window on the top that is transparent to infrared ray. The temperature distribution in the combustion chamber was measured using infrared thermal imager while hydrogen-air premixture is steadily supplied to the combustor. The area where the catalytic reaction took place broaden for higher flow rate and lower equivalence ratio made activated area in the combustion chamber broaden. The amount of coated platinum catalyst did not affect the reaction. Stop of reaction, which is similar to flame quenching of conventional combustion, was investigated. Large content of heat generation and broad activated area are essential criteria to prevent stop of reaction that has a bad effect on the combustor performance.

• Journal of the Korean Institute of Gas
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• v.5 no.1
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• pp.45-51
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• 2001

Catalytic combustion is the environmental-friendly technology, which has been applied to a variety of areas for industrial and domestic use in recent years. Accordingly, this study performed the development of the catalytic manufacturing technology for the high temperature and of the catalytic combustor in priority, which were aimed to be aimed to a commercialized condensing boiler. Palladium(Pd) of a noble meta] was used as a catalyst for the high temperature and supported on $alumina(Al_{2}O_{3})\;and\;zirconia(ZrO_2)$ in constant weight ratio. Activity of Pd catalysts is compared and analysed in the catalytic combustion of natural gas. The ratio of $Pd/Al_{2}O_{3}\;=\;4$ was found to be better than any other weight ratios in activity and durability. The performance examination of catalysts and of combustion through the plate-type combustor made it possible to be developed the cylindrical-type combustor which has increased combustion area. Catalytic combustion condensing boiler of 25,000 kcal/hr class was also developed, which had the optimum combustion condition at the no221e of 5.95mm and the orifice of 21mm. This condition was determined through the performance experiments of catalytic combustion condensing boiler to which the cylindrical-type catalytic combustor was applied.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.328-334
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• 2000

The hybrid catalytic(catalytic+thermal) combustor of a lean methane-air mixture on platinum catalyst was investigated numerically using a 2-D boundary layer model with detailed homogeneous and heterogeneous chemistries. For the more accurate calculations, the actual surface site density of monolith coated with platinum was decided by the comparison with experimental data. It was found that the homogeneous reactions in the monolith had little effect on the change of temperature profile, methane conversion rate and light off location. However, the radicals such as OH and CO were produced rapidly at exit by homogeneous reactions. Thus the homogeneous reactions were important to predict the productions of CO and NOx exactly. In thermal combustor, the production of $N_2O$ was more dominant than that of NO due to the relative important of the reaction $N_2+O(+M){\to}N_2O(+M)$. Finally the production of CO and NOx by amount of methane addition were studied.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.3049-3052
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• 2008

MCFC(molten carbonate fuel cell) power generation system is prime candidate for the utilization of fossil based fuels to generate ultra clean power with a high efficiency. In the MCFC power plant system, a combustor performs a role to supply high temperature mixture gases for cathode and heat for reformer by using the stack off-gas of the anode which includes a high concentration of $H_2O$ and $CO_2$. Since a combustor needs to be operated in a very lean condition and to avoid excessive local heating, catalytic combustor is usually used. The catalytic combustion is accomplished by the catalytic chemical reaction between fuel and oxidizer at catalyst surface, different from conventional combustion. In this study, a mathematical model for the prediction of internal flow and catalytic combustion characteristics in the catalytic combustor adopted in the MCFC power plant system is suggested by using the numerical methods. The numerical simulation models are then implemented into the commercial CFD code. After verifying result by comparing with the experimental data and calibrated kinetic parameters of catalytic combustion reaction, a numerical simulation is performed to investigate the variation of flow and combustion characteristics by changing such various parameters as inlet configuration and inlet temperature. The result show that the catalytic combustion can be effectively improved for most of the case by using the perforated plate and subsequent stable catalytic combustion is expected.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.3
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• pp.149-155
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• 2009

In this work a numerical study to find the characteristics of the internal flow and mixing process has been conducted in a static mixer used in the system of catalytic combustor of the fuel cell power plant. After introducing the model description and final governing equations the present numerical approach is applied to the analysis of static mixer, which may have one or more helical elements inside the circular tube by changing such various parameters as incoming mass flow rates and the number of helical elements. The results show that although the static mixer is efficient in mixing fuel and air, more optimization processes are required to achieve the appropriate mixing characteristics in front of the honeycomb type catalytic combustor used in the MCFC power plant