• Title/Summary/Keyword: Chemical Type

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THE EFFECT OF ACID ETCHING ON GLASS IONOMER CEMENT SURFACES (Glass ionomer cement 표면의 산부식 효과에 관한 연구)

  • Han, Seung-Weon;Park, Sang-Jin;Min, Byung-Soon;Choi, Ho-Young;Choi, Gi-Woon
    • Restorative Dentistry and Endodontics
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    • v.18 no.1
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    • pp.1-26
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    • 1993
  • The purpose of this study was to investigate the effect of acid etching on the surface appearance and fracture toughness of five glass ionomer cements. Five kinds of commercially available glass ionomer cements including chemical curing filling type, chemical curing lining type, chemical curing metal reinforced type, light curing tilling type and light curing lining type were used for this study. The specimens for SEM study were fabricated by treating each glass ionomer cement with either visible light curing or self curing after being inserted into a rubber mold (diameter 4mm, depth 1mm). Some of the specimens were etched with 37% phosphoric acid for 0, 15, 30, 60, go seconds, at 5 minutes, 1 hour and 1 day after mixing of powder and liquid. Unetched ones comprised the control group and the others were the experimental groups. The surface texture was examined by using scanning electron microscope at 20 kV. (S-2300, Hitachi Co., Japan). The specimens for fracture toughness were fabricated by curing of each glass ionomer cement previously inserted into a metal mold for the single edge notch specimen according to the ASTME399. They were subjected to a three-point bend test after etching for 0, 30, 60, and 90 seconds at 5 minutes-, 1 hour-and 1 day-lapse after the fabrication of the specimens. The plane strain fracture toughness ($K_{IC}$) was determined by three-point bend test which was conducted with cross-head speed of 0.5 mm/min using Instron universal testing machine (Model No. 1122) following seven days storage of the etched specimens under $37^{\circ}C$, 100% humidity condition. Following conclusions were drawn. 1. In unetched control group, crack was present, but the surface was generally smooth. 2. Deterioration of the surface appearance such as serious dissolving of gel matrix and loss of glass particles occured as the etching time was increased beyond 15 s following Immediate etching of chemical curing type of glass ionomer cements. 3. Etching after 1 h, and 1 d reduced surface damage, 15 s, and 30s etch gave rough surface appearance without loss of glass particle of chemical curing type of glass ionomer cements. 4. Light curing type glass ionomer cement was etched by acid, but there was no difference in surface appearances according to various waiting periods. 5. It was found that the value of plane stram fracture toughness of glass ionomer cements was highest in the light curing filling type as $1.79\;MNm^{-1.5}$ followed by the light curing lining type, chemical curing metal reinforced type, chemical curing filling type and chemical curing lining type. 6. The value of plane stram fracture toughness of the chemical curing lining type glass ionomer cement etched after 5 minutes was lower than those of the cement etched after 1 hour or day or unetched (P < 0.05). 7. Light curing glass ionomer cement showed Irregular fractured surface and chemical curing cement showed smooth fractured surface.

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RESEARCH PAPERS : A STUDY ON REMOVAL OF PB2+ ION USING PELLET - TYPE RED MUD ADSORBENTS

  • Kim, Jung-Sik;Han, Sang-Won;Hwang, In-Gook;Bae, Jae-Heum;Shuzo Tokunaga
    • Environmental Engineering Research
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    • v.7 no.1
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    • pp.33-37
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    • 2002
  • The two kinds of pellet-type red-mud adsorbents (bead-type, crushed-type) were from red mud, which is generated as a by-product during the production of aluminum hydroxide from bauxite ore. The adsorption experiments of Pb^{2+} ion in the aqueous solution by these red-mud adsorbents were studied with a continuous adsorption ccolumn. As a result, the crushed-type adsorbent shows better performance in adsorption of Pb^{2+} than the bead-type adsorbent between the two types of the pellet-type adsorbents. The continusous adsorption experiment shows that the pellet-type adsorbents made from red mud have good performance for removal of Pd^{2+}. The breakthrough curves of the red-mud adsorbents were compared with that of activated carbon.

Miniaturization of Polymerase Chain Reaction

  • Lee, Ji-Youn;Kim, Jae-Jeong;Park, Tai-Hyun
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.4
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    • pp.213-220
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    • 2003
  • Polymerase chain reaction (PCR) is one of the most widely used analytical tool and is an important module that would benefit from being miniaturized and integrated onto diagnostic or analytical chips. There are potentially two different approaches for the miniaturization of the PCR module: chamber-type and flow-type micro-PCR. These miniaturized PCRs have distinct characteristics and advantages. In this article, we review the necessity of micro-PCR, the materials for the chip fabrication, the surface modification, and characteristics of the two types of micro-PCR. The motivation underlying the development of micro-PCR, the advantages and disadvantages of the various materials used in fabrication and the surface modification methods will be discussed. And finally, the precise features of the two different types of micro-PCR will be compared.

Heat Transfer Characteristic of the Spiral Type Solar Chemical Reactor (수치해석을 통한 Spiral 형상 화학 반응기의 열전달 특성)

  • Jung, Young-Guk;Lee, Jin-Gyu;Lee, Ju-Han;Seo, Tae-Beom
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.1
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    • pp.40-48
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    • 2010
  • The purpose of the research is to develop the high performance solar chemical reactor for producing hydrogen using steam reforming reaction of methane. A specific shape chemical reactor is suggested : spiral type reactor. The reactor is installed on the dish-type solar thermal system of Inha University. The temperatures, $CH_4$ conversion rates, and Hz proportion are measured. At specific condition, $CH_4$ conversion rates of the spiral type reactor are about 91%, and Hz proportion are about 66%. The spiral type reactor gives reasonably good performance without any problems caused by highly concentrated solar radiation.

Performance Analysis of Heat Transfer Characteristic and Hydrogen Product for Dish Type Solar Chemical Reactor (접시형 고온 태양열 화학 반응기의 열전달 및 수소생산 성능 분석)

  • Yang, Seung-Bok;Go, Man-Seok;O, Sang-Jun;Seo, Tae-Beom
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.774-779
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    • 2009
  • The purpose of this research is to develop the high performance of solar chemical reactor for producing hydrogen by methane reforming reaction with steam. Two shape of chemical reactor is suggested: first type is filled with porous material and second type is spiral type. These reactors is installed on the dish-type thermal system of Inha University, Inha Dish-1. Performance analysis of these two reactors is conducted from getting methane conversion.

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Influence of Chemical Admixture on the Strength Development of Concrete at Early Age (콘크리트의 초기 강도발현에 미치는 혼화제의 영향)

  • 황인성;나운;이승훈;류현기;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.741-744
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    • 2003
  • In this study, the influence of chemical admixture on early strength development of concrete is discussed. According to the results, fluidity with variation of kinds of chemical admixture is lower in the case of acceleration type than in the case of normal type. Setting time of naphthalene acceleration type is shortened by I hour, and that of melamine is nearly same, but that of polycarbonic acid is somewhat retarded in comparison with that of naphthalene normal type. Early compressive strength gains 5MPa in about 18hours regardless of the kinds of chemical admixture. But as time elapses, compressive strength is higher in order of polycarbonic acid, naphthalene and melamine type. The relativity between compressive strength and the rebound value of P-type schmidt hammer is also favorable at early age, and compressive strength of 5MPa is estimated at the rebound value of 22.

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Single Step Response Based Method for the Simple Identification of Wiener-type Nonlinear Process (단일 계단 응답에 근거한 Wiener형 비선형 공정의 간편한 모델 확인 방법)

  • Sanghun Lim;Jea Pil Heo;Su Whan Sung;Jietae Lee;Friedrich Y. Lee
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.89-96
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    • 2023
  • The Wiener-type nonlinear model where a static nonlinear block follows a dynamic linear block is widely used to describe the dynamics of chemical processes. A long process excitation step is typically needed to identify this Wiener-type nonlinear model with two blocks. In order to cope with this disadvantage, an identification method for the Wiener-type nonlinear model that uses only a single-step response is proposed here. The proposed method estimates the response of the dynamic linear sub-block from the initial part of the step response, and then the static nonlinear sub-block is identified. Because the only single-step response is used to identify the Wiener-type nonlinear model, there is great benefit in time and cost for obtaining process response. The performance of the proposed identification method with the single-step response is verified through a representative Wiener-type nonlinear process, a pH titration process, and a liquid level system.

Analysis of Heat Transfer Performance for a Solar Chemical Reactor (고온 태양열 화학 반응기의 열전달 성능 분석)

  • Jung, Young-Guk;Lee, Ju-Han;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.55-60
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    • 2009
  • The purpose of the research is to develop the high performance solar chemical reactor for producing hydrogen using steam reforming reaction of methane. A specific shape chemical reactor is suggested: spiral type reactor. The reactor is installed on the dish-type solar thermal system of Inha University. The temperatures, $CH_4$ conversion rates are measured. At specific condition, $CH_4$ conversion rates of the spiral type reactor are about 92%. The spiral type reactor gives reasonably good performance without any problems caused by highly concentrated solar radiation.

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Characteristics of Electroantennogram Parameters for the Detection of Odorants

  • Yun, Eung-Sik;Ko, Hwi-Jin;Sun, Jong-Hwan;Park, Tai-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.10 no.6
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    • pp.885-888
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    • 2000
  • Electroantennogram(EAG) can be applied to detect odorants since insects have highly specialized olfactory receptors inside their antennae. The characteristics of EAG parameters were investigated for the quantitative measurement of a general odorant using ammonia as a model odorant. The antennae of male silkworm moth, Bombyx mori, were used for the EAG. The electical signal curves generated from a pair of antennae originating from the same silkworm moth were never identical; however, they exhibited a typical type I or type II characteristic curve pattern for every pair of antennae. The correlation between the EAG parameters and the ammonia concentration was analyzed for the type I and type II antennae. The stability of each parameter was also investigated for each type of antenna. The results show the possibility of the quantitative measurement of general odorants using the EAG technique.

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