• Title/Summary/Keyword: Chemistry

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Herbicidal Activity of Chrysophanic Acid in Semi-field Condition (천연물질 Chrysophanic Acid의 포장조건 제초 활성)

  • Choi, Jung-Sup;Jang, Hyun-Woo;Seo, Bo-Ram;Hwang, Hyun-Jin;Kim, Jae-Deog;Kim, Jin-Seog;Chun, Jae-Chul;Kim, Song-Mun
    • Korean Journal of Weed Science
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    • v.30 no.4
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    • pp.429-436
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    • 2010
  • Herbicidal activity and characteristics of chrysophanic acid were investigated in semi-field condition. At early and middle post-emergence, Trifolium repens appeared to be very susceptible to chrysophanic acid of $2,000{\mu}g\;mL^{-1}$. However, herbicidal activity of chrysophanic acid of $2,000{\mu}g\;mL^{-1}$ estimated by visual injury to Artemisia princeps was not caused considerable phytotoxicity. Also by foliar application, the concentration of crysophanic acid for effectively control to Polygonum aviculare was much higher than $2,000{\mu}g\;mL^{-1}$. Herbicidal activity of chrysophanic acid to Echinochloa crus-galli, Cypres difformis, Setaria viridis, Digitaria sangguinalis, Bidens tripartita by foliar application was more effective at concentration ranges from 4,000 to $6,000{\mu}g\;mL^{-1}$. These results suggest that chrysophanic acid demanded for higher than $2,000{\mu}g\;mL^{-1}$ to successful weed control in the field condition.

Effects of Several Herbicides on Control of Creeping Bentgrass in the Kentucky Bluegrass and Its Recovery (켄터키블루그래스 포장에 침입한 크리핑벤트그래스의 제초제를 이용한 방제와 회복)

  • Kim, Young-Sun;Jo, Kap-Jun;Lee, Hyo-Sun;Kang, Young-Nam;Lim, Hye-Jung;Lee, Kyu-Seong
    • Weed & Turfgrass Science
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    • v.2 no.4
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    • pp.395-401
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    • 2013
  • This study was conducted to evaluate the selective control of creeping bentgrass invaded in Kentucky bluegrass by applying several herbicides and recovery of Kentucky bluegrass by sand injection seeding method. Selective herbicides such as mecoprop, triclopyr-TEA, imazaquin, bentazone and penosulam pyrazosulfuro-ethyl and non-selective herbicides such as glyphosate, paraquat dichloride and glyphsate ammonium oxyflorfen were used. Selective suppression of creeping bentgrass in Kentucky bluegrass was evaluated by turf color, chlorophyll and visual control indexes. Control of creeping bentgrass was most effective with the double dose application of triclopyr-TEA (2 Tri-T) in the selective herbicides and the 1 / 5 dose application of glyphosate ammonium oxyflorfen (1 / 5 GAO) in the non-selective herbicides. Visual control indexes by 2 Tri-T in selective herbicides and 1 / 5 GAOin non-selective herbicides were investigated 6.0 and 7.4, respectively. Treated sites were covered completely in 50 days after seeding Kentucky bluegrass by sand injection method.

Suppression of Dollar Spot Caused by Sclerotinia homoeocarpa on Creeping Bentgrass (Agrostis palustris Huds.) after Applying Tebuconazole, Chlorothalonil and Their Mixture (크리핑 벤트그래스에서 동전마름병 방제를 위한 Tebuconazole, Chlorothalonil 및 합제 처리)

  • Kim, Young-Sun;Lim, Hye-Jung;Ham, Suon-Kyu;Lee, Kyu-Seung;Lee, Geung-Joo
    • Weed & Turfgrass Science
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    • v.7 no.2
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    • pp.158-165
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    • 2018
  • This study was conducted to evaluate the control efficacy of dollar spot on creeping bentgrass after applying various amounts of tebuconazole, chlorothalonil and mixture of tebuconazole and chlorothalonil (tebuconazole+chlorothalonil). In effect of three fungicides on suppression against Sclerotinia homoeocarpa, tebuconazole and tebuconazole+chlorothalonil were found to inhibit more than 98% fungus growth on medium and 70% in chlorothalonil treatment. The control efficacy of tebuconazole at different rates of 31.25, 62.5, and $125a.i.\;mg\;m^{-2}$ on creeping bentgrass showed more than 80%. Application of tebuconazole ($125.0a.i.\;mg\;m^{-2}$), tebuconazole+chlorothalonil ($125.0a.i.\;mg\;m^{-2}+135.9a.i.\;mg\;m^{-2}$) and chlorothalonil ($135.9a.i.\;mg\;m^{-2}$) were suppressed 96%, 80%, 70% for the dollar spot severity, respectively. Correlation between application amount of fungicides and control efficacy of dollar spot was significantly positive, and suggested amount of tebuconazole, tebuconazole+chlorothalonil and chlorothalonil that might suppress more than 80% of dollar spot were calculated to 29.6, 132.2+142.8, and $157.0a.i.\;mg\;m^{-2}$, respectively.

Determination of Aroma Components in Pinus densiflora (Pine Needles) Studied by Using Different Extraction Methods (추출방법에 따른 솔잎의 휘발성 성분 조성 비교)

  • Lee Jae-Gon;Lee Chang-Gook;Baek Shin;Kwon Young-Ju;Jang Hee-Jin;Kwag Jae-Jin;Rhee Moon-Soo;Lee Gae-Ho
    • The Korean Journal of Food And Nutrition
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    • v.19 no.2
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    • pp.161-168
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    • 2006
  • The efficiency of six different extraction methods for the analysis of aroma components from pine needle(P. densiflora) was compared by gas chromatography-mass selective detector(GC-MSD). The six methods were dynamic headspace(DHS), reduced pressure headspace(RPHS), solid-phase microextraction(SPME), simultaneous distillation-extraction(SDE), supercritical fluid extraction(SFE) and pyrolysis distillation extraction(PDE). A total of 65 compounds were identified by using the six different extraction methods. These compounds are classified into six categories in terms of chemical functionality: 25 hydrocarbons, 16 alcohols, 9 carbonyls, 6 esters, 7 acids, and 2 ethers. The aroma compounds having low boiling point were more abundant in DHS, RPHS, and SPME extracts. On the other hand, the aroma compounds having high boiling point were more abundants in SDE, SFE and PDE extracts. The acid compounds were extracted by heat-based extraction methods such as SDE, SFE, PDE, but not by DHS, RPHS and SPME, which used neither solvent nor heat. The oxygenated terpens, hexanal, hexanol, and hexadienal were more abundant in DHS and RPHS extracts, compared with the other methods.

The Quality of Mozzarella Cheese Made by Concentrated Milk from Ultrafiltration (한외여과 농축유로 제조한 모짜렐라 치즈의 품질에 관한 연구)

  • Song, Kwang-Young;Seo, Kun-Ho;Lee, Si-Kyung;Han, Song-Ee;Kim, Myeong-Hee;Kim, Song-Hee;Mok, Bo-Ram;Yoon, Yoh-Chang
    • Food Science of Animal Resources
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    • v.31 no.6
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    • pp.907-913
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    • 2011
  • Low-fat and full-fat Mozzarella cheeses were manufactured using ultraflterated-concentrated cow milk with a bacterial cell count of 100, 000 CFU/mL to study the properties of browning, oiling-off, stretchability, and meltability of the cheeses during 3 mon of refrigerated storage. The properties of browning, oiling-off, and stretchability of UF-Mozzarella cheese were affected by fat content, addition of starter and rennet (add 50, 65, and 80% compared with the control, respectively), and baking temperature (280, 300, and $320^{\circ}C$) (p<0.05). The browning and oiling-off scores increased with an increase in baking temperature and lengthen of storage time, but some undesirable results also occurred. The stretchability score improved with an increase in baking temperature, but the gradient decreased with the length of storage time (p<0.05). The meltability score was affected by fat content, concentration factor, and storage period (p<0.05). The result of this study demonstrated the applicability of UF-milk in making Mozzarella cheese with high quality and good palatability.

Effect of Sub- and Super-critical Water Treatment on Physicochemical Properties of Porcine Skin

  • Jo, Yeon-Ji;Kim, Jae-Hyeong;Jung, Kyung-Hun;Min, Sang-Gi;Chun, Ji-Yeon
    • Food Science of Animal Resources
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    • v.35 no.1
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    • pp.35-40
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    • 2015
  • Super- and sub-critical water treatments have been of interest as novel methods for protein hydrolysis. In the present study, we studied the effect of sub-critical water (Sub-$H_2O$, $300^{\circ}C$, 80 bar) treatment as well as super-critical water (Super-$H_2O$, $400^{\circ}C$, 280 bar) treatment on the physicochemical properties of porcine skin (PS), which has abundant collagen. Porcine skin was subjected to pre-thermal treatment by immersion in water at $70^{\circ}C$, and then treated with sub- or super-critical water. Physicochemical properties of the hydrolysates, such as molecular weight distribution, free amino acid content, amino acid profile, pH, color, and water content were determined. For the molecular weight distribution analysis, 1 kDa hydrolyzed porcine skin (H-PS) was produced by Super-$H_2O$ or Sub-$H_2O$ treatment. The free amino acid content was 57.18 mM and 30.13 mM after Sub-$H_2O$ and Super-$H_2O$ treatment, respectively. Determination of amino acid profile revealed that the content of Glu (22.5%) and Pro (30%) was higher after Super-$H_2O$ treatment than after Sub-$H_2O$ treatment, whereas the content of Gly (28%) and Ala (13.1%) was higher after Sub-$H_2O$ treatment. Super-$H_2O$ or Sub-$H_2O$ treatment affected the pH of PS, which changed from 7.29 (Raw) to 9.22 (after Sub-$H_2O$ treatment) and 9.49 (after Super-$H_2O$ treatment). Taken together, these results showed that Sub-$H_2O$ treatment was slightly more effective for hydrolysis than Super-$H_2O$ was. However, both Sub-$H_2O$ and Super-$H_2O$ treatments were effective processing methods for hydrolysis of PS collagen in a short time and can be regarded as a green chemistry technology.

Effect of Soybean Protein Isolate on the Baking Qualities of Bread (분리 대두단백질의 첨가가 제빵적성에 미치는 영향)

  • Bae, Song-Hwan;Rhee, Chul
    • Korean Journal of Food Science and Technology
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    • v.30 no.6
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    • pp.1295-1300
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    • 1998
  • This study was conducted to investigate the effect of soybean protein isolate (SPI) on the baking qualities of bread which was made of composite flour blended with SPI extracted at acidic (pH 2.0, 3.0), neutral (pH 7.0) and alkaline (pH 10.0, 12.0) conditions. The mixogram showed that water absorption of composite flour dough blended with SPI extracted at pH 2.0 and 12.0 was higher than that of 100% wheat flour dough, and mixing time was shorter than that of 100% wheat flour dough. No differences were found between the composite flour blended with SPI at level of 5% and 100% wheat flour on the loaf volume of bread. The loaf volume of bread made of composite flour blended with $SPI_2\;AND\;SPI_3$ at level of 10% was lower than that of 100% wheat flour, but that of $SPI_7,\;SPI_{10},\;and\;SPI_{12}$, which had higher emulsion capacity than $SPI_2,\;SPI_3$ was similar to that of 100% wheat flour. No differences were found between the composite flour blended with SPI at level of 5% and that of 100% wheat flour on springiness, chewiness, cohesiveness, gumminess, adhesiveness and hardness of bread. The composite flour blended with SPI at level of 10% was similar to 100% wheat flour on springiness, chewiness, cohesiveness, gumminess, adhesiveness and hardness of bread except for chewiness, gumminess and hardness of $SPI_2,\;and\;SPI_{12}$ which were significantly higher than that of 100% wheat flour (P<0.05).

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The Metallic Composition of PM2.5 and PM10 in a Northeast Region of Seoul During the Spring 2001 (2001년 봄철 서울시 북동부지점에서 관측한 중금속성분의 농도분포)

  • Choi, Gyoo-Hoon;Kang, Chang-Hee;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.23 no.6
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    • pp.514-525
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    • 2002
  • The analysis of heavy metals associated with both PM2.5 and PM10 fraction of aerosols was made from a northeast region of Seoul during the spring period of 2001. The mean concentrations of fine (PM2.5), coarse (PM10-PM2.5), and PM10 fraction were observed as 49.3${\pm}$29.2, 50.5${\pm}$35.0, and 95.5${\pm}$46.1 ${\mu}g$/m$^3$, respectively during this study period. According to the results of enrichment factor (EF) analysis between different particle fractions, major elements (including Fe, Ca, Na, and K) were found to exhibit EF values of less than 10. However, heavy metal components (like Zn and Pb) showed very high EF values. Comparison of fine/coarse (F/C) concentration ratio showed that Zn, Cr, Pb, and Ni have higher ratio values than others. The metallic composition of particles was also compared on both absolute and relative terms. The results of our analysis showed an evidence that the increase in the total metallic contents is prominent during the spring period due mostly to the Asian Dust event.

A Comparison Study on Research Outputs (FY1999 to 2003) in Earth Science and Other Sciences through Analysis of KOSEF's Database (과학재단 연구 인력 DB 분석을 통한 지구과학과 타 이학계 분야간의 최근 5년간(FY1999-2003) 연구 실적 비교 분석)

  • Kim Seong-Yong;Min Tae-Sun;Heo Chul-Ho;Ahn Eun-Young
    • Journal of the Korean earth science society
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    • v.26 no.3
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    • pp.232-239
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    • 2005
  • Research outputs of science and engineering fields including Earth Science were analyzed using KOSEF's Database. A total $312(1.5\%)$ Geoscientists participated in KOSEF's Database, and the number of articles they published in SCI (Science Citation Index) journals and Non-SCI journals during the last five years (1999 to 2003) was $1,026(0.2\%)\;and\;3,265(0.5\%)$, respectively. The average number of articles per capita published in SCI journals during the last five years was 3.3 in Geoscience, 4.0 in Mathematics, 57.6 in Physics, 60.4 in Chemistry, and 33.4 in Biology. The average number of articles per capita published in SCI journals within Geoscience was 9.6 in Environmental Geology, 4.6 in Stratigraphy and Sedimentology, 4.2 in Geochemistry, 3.6in Hydrology, 3.5 in Oceanography, and 3.2 in Mining Geology. The results of this survey will be used as a reference in comparing research outputs of Earth Science and other sciences, both in quality and quantity.

Humus Analysis for the Geomorphic Development and Climatic Environment Change of Alluvial Plain in Hampyeongcheon Basin during the Late Holocene (휴무스분석을 이용한 함평천 유역의 홀로세 후기 충적평야의 지형발달과 기후환경변화)

  • Jung, Hea-Kyung;Kim, Cheong-Bin
    • Journal of the Korean earth science society
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    • v.33 no.4
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    • pp.320-328
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    • 2012
  • To investigate geomorphic development of alluvial plains and climatic environment change during the late Holocene carbon dating, soil organic carbon analysis and humus analysis of sediments from alluvial plain of Hampyeongcheon basin were performed. The lowest peat layer was formed under warm and humid climates, which is considered to correspond to the Atlantic period in the Holocene. Yellowish brown sandy clay layer was deposited in the natural levee, which we think were deposited in the generally warm and dry climates. The carbon dating age is 1,879-1,532 BC, and this period correspond to the Sub-boreal period in the Holocene. Light brown clay layer is assumed to have been deposited in transitional environment from the natural levee to the back marsh. The climatic environment was warm and humid, which is considered as transitional period from the Sub-boreal to the Sub-Atlantic in the Holocene. Light yellowish brown and light brown clay layer of the upper part are regarded as sediments of the back marsh. Light yellowish brown clay layer was deposited in the cold and dry climates, which is considered to correspond to the Sub-Atlantic period in the Holocene. Light brown clay layer was deposited in the warm and dry climates. The carbon dating age is 211-427 AD, this period corresponds to the Post Roman Warm Period in the Holocene.