• 한국전기전자재료학회논문지
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• 제12권1호
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• pp.11-17
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• 1999

Aging characteristics of the crosslinked polyethylene have been measured after applying electrical, thermal and combined stresses. ICP and FT-IR measurements confirmed diffusion of low molecular weight components such as antioxidant and presence of carbonyl group. Carbonyl group of aged crosslinked polyethylene under combined stress was detected by FT-IR. As deterioration of the crosslinked polyethylene progresses, crystallinity degree and density decrease. Also, dielectric properties have been measured by tan $\delta$ and $\varepsilon$$_{r}$ measurements. The three-parameter Weibull distribution was found to be the best suited among other probabilistic distribution representing the dielectric breakdown strength of aged crosslinked polyethylene. The scale parameter and location parameter decreases as the applied stress increases. The shape parameter increases as the stress increases.s.

• 한국식품과학회지
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• 제32권6호
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• pp.1298-1305
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• 2000

0.1, 0.5, 1.0, 2.0% epichlorohydrin으로 가교결합시킨 감자 전분을 각각 5% 첨가한 polyethylene cast 필름을 제조하여 이들의 기계적 성질 및 열분해 특성, 생분해 특성을 분석하였다. Instron으로 측정한 필름의 기계적 성질에서는 가교결합 감자 전분으로 제조한 필름이 무처리 감자 전분으로 제조한 필름보다 인장강도, 신장율, 인장에너지 모두가 더 높게 나타나 필름의 기계적 강도가 향상되었음을 알 수 있었다. FT-IR과 Instron으로 측정한 필름의 열분해 특성에서는 가교결합 감자 전분으로 제조한 필름이 무처리 감자 전분으로 제조한 필름보다 빠르게 열분해됨이 확인되었다. 또한 필름의 생분해 특성에서도 가교결합 감자 전분으로 제조한 필름이 무처리 감자 전분으로 제조한 필름보다 생분해 정도가 더 뛰어난 것으로 나타났다.

• 전기학회논문지
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• 제61권6호
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• pp.827-832
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• 2012

The crosslinked polyethylene (XLPE) is the most widely used insulating material for power cable. Due to its thermosetting characteristics, the XLPE can not be recycled, while the needs for the environmental friendly and recyclable insulator is rapidly increasing. In this paper, some important and basic electrical properties of non-crosslinked polyethylene such as conduction current characteristics, water the tree characteristics, AC breakdown test were experimentally investigated. It was shown that some of the tested samples had better performances from the application point of view for replacing current XLPE.

• Macromolecular Research
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• 제17권12호
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• pp.950-955
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• 2009

The physical and rheological properties of thermoplasticized irradiation-crosslinked polyethylene foam using supercritical methanol treatment were investigated by GPC, FTIR, DSC, WAXS, DMTA and UDS. The polyethylene foam was selectively decrosslinked into thermoplasticized polyethylene in an appropriate supercritical methanol condition without any undesirable side reactions such as oxidation and disproportionation. The thermoplasticization was promoted with increasing reaction temperature to reach completion above $380^{\circ}C$. The supercritical reaction condition affected the crystallization behavior, and mechanical and rheological properties of the decrosslinked polyethylene foam, but not its crystallographic structure or crystallinity.

• 폴리머
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• 제33권6호
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• pp.520-524
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• 2009

가교 폴리에틸렌 파이프의 산화 열화가 진행되는 동안 인장 특성의 변화 및 화학적 구조의 변화를 조사하여 산화 열화가 파이프의 성능에 미치는 영향을 분석하였다. 가교 폴리에틸렌 파이프의 산화 열화를 유도하기 위하여 고온 열처리 및 UV 조사 방법을 이용하였으며 파이프 생산 시 다이 온도가 파이프의 산화 열화에 미치는 영향도 조사하였다. 산화 열화 과정 중 파이프의 인장 특성 변화는 만능재료시험기로, 화학적 구조의 변화는 적외선분광기로 각각 조사하였다. 열에 의한 산화 열화가 진행됨에 따라 파이프의 인장 강도는 서서히 감소하였으나 파단 신율은 급격히 감소하였고, 파이프 내부로 도입된 산소 분자로 인해 화학적 구조도 변화하였다. 이러한 결과는 가교 폴리에틸렌 파이프의 생산 및 저장 중 산화 열화에 따른 성능 저하를 평가하는데 유용하게 사용될 것이다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.55-58
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• 1999

Crosslinked polyethylene/silane crosslinked polyethylene (XLPE/SXLPE) blends were prepared by a twin screw extruder and their water tree growing and electrical breakdown characteristics of XLPE were improved by the addition of SXLPE, when samples were crosslinked only by the thermorolysis of DCP (dicumyl perosxide). However, steam curing process was not good for water tree characteristics. It was also found that the rate of water tree growing of XLPE/SXLPE blend increased when the content of SXLPE was 50 %. AC breadown strength slightly increased by the addition of SXLPE to XLPE when samples were crosslinked only by the thermorolysis of DCP.

• 방사선산업학회지
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• 제6권3호
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• pp.211-215
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• 2012

In this study, crosslinked polyethylene (PE) foam sheets were prepared through gamma-ray irradiation. PE foam sheets were prepared through a foaming process using sodium bicarbonate as a blowing and foaming agent. The prepared PE foam sheets were then crosslinked through gamma-ray irradiation. The crosslinking degree was increased to 86.0% with an increase in the absorption dose. The tensile strength of the crosslinked PE foam sheets was increased with an increase in the absorption dose. However, the elongation-at-break of the crosslinked PE foam sheets was decreased. The thermal decomposition temperature of the crosslinked PE foam sheets was increased to $421.2^{\circ}C$ with an increase in the absorption dose. The SEM analysis revealed that the morphology was not changed significantly after the crosslinking through gamma-ray irradiation.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.897-900
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• 2001

Space charge distributions in silane crosslinked polyethylene (SXLPE)/ crosslinked polyethylene (XLPE) laminates was investigated using a pulsed electroacoustic (PEA) method. XLPE shows heterocharge while SXLPE shows homocharge. Positive charge is accumulated at the interface of SXLPE/XLPE laminate when applied electric field is more than 20 kV/mm. The charge profile at various temperatures was also acquired using temperature-controllable PEA system. Although applied electric field is only 8.6 kV/mm, positive interfacial charge starts to appear near 50$^{\circ}C$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.173-176
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• 1999

Crosslinked Decree is an important 7actor to determine dielectric property of crosslinked polyethylene(XLPE) used for the insulation material in Power cables. Recently, though it is necessary to investigate electrical properties according to crosslinked degree as a Part of the whose characterization of cable. it is not examined closely. In this study. crosslinked degree of samples were measured according to temperature and holding time of crosslinking. electrical tree characteristics of these characteristics of these samples were analyzed by crosslinked degree and applied temperature that was chanced from normal temperature to operating temperature of power cables. As a result. when the crosslinked degree was low, dielectric properties were decreased and influence of temperature was increased. but the crosslinked degrees were high, initiation voltages of treeing were increased and dielectric properties were improved. It is proved that the optimum crosslinked degree was one of most important factor for aging time and residual lifetime of Power cable.

• 한국공작기계학회논문집
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• 제17권3호
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• pp.108-114
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• 2008

Uniaxial tension and compression test were conducted on conventional and crosslinked ultra-high molecular polyethylene (UHMWPE) all prepared from the same lot of medical grade GUR 1050. The conventional materials were unirradiated and gamma irradiated with $25kGy{\sim}200kGy$. Gamma irradiated processing was found to significantly impact the crystallinity, and hence the mechanical behavior, of the highly crosslinked UHMWPE. The crystallinity and radiation dose were key predictors of the uniaxial yielding, hardness, plastic flow, and failure properties of conventional and highly crosslinked UHMWPE. The correlation model from experiments would be the basic information to design the liner of artificial joint.