• Title/Summary/Keyword: De-carbonate

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Ultrasonic velocity as a tool for mechanical and physical parameters prediction within carbonate rocks

  • Abdelhedi, Mohamed;Aloui, Monia;Mnif, Thameur;Abbes, Chedly
    • Geomechanics and Engineering
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    • v.13 no.3
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    • pp.371-384
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    • 2017
  • Physical and mechanical properties of rocks are of interest in many fields, including materials science, petrophysics, geophysics and geotechnical engineering. Uniaxial compressive strength UCS is one of the key mechanical properties, while density and porosity are important physical parameters for the characterization of rocks. The economic interest of carbonate rocks is very important in chemical or biological procedures and in the field of construction. Carbonate rocks exploitation depends on their quality and their physical, chemical and geotechnical characteristics. A fast, economic and reliable technique would be an evolutionary advance in the exploration of carbonate rocks. This paper discusses the ability of ultrasonic wave velocity to evaluate some mechanical and physical parameters within carbonate rocks (collected from different regions within Tunisia). The ultrasonic technique was used to establish empirical correlations allowing the estimation of UCS values, the density and the porosity of carbonate rocks. The results illustrated the behavior of ultrasonic pulse velocity as a function of the applied stress. The main output of the work is the confirmation that ultrasonic velocity can be effectively used as a simple and economical non-destructive method for a preliminary prediction of mechanical behavior and physical properties of rocks.

Taxonomic Reassessment of the Genus Padina (Dictyotales, Phaeophyta) from the Gulf of California

  • Riosmena-Rodriguez, Rafael;Paul-Chavez, Litzia;Hernandez-Carmona, Gustavo;Lopez-Vivas, Juan Manuel;Casas-Valdez, Margarita
    • ALGAE
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    • v.24 no.4
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    • pp.213-229
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    • 2009
  • A monographic reassessment of Padina Adanson species from the Gulf of California was developed based on an exhaustive review of the character and characters states that have been used to delimit species in recent and historically valuable collections. Eight names (P. caulescens Thivy in Taylor, P. concrescens Thivy in Taylor, P. crispata Thivy in Taylor, P. durvillaei Bory Saint-Vincent, P. gymnospora [Kutzing] Sonder, P. mexicana Dawson, P. tetrastromatica Hauck and P. vickersiae Hoyt in Howe) were reported from the region. An analysis of 1,200 specimens led to the conclusion that only three species (P. durvillaei, P. concrescens and P. mexicana) can be recognized for the area based on four discriminating characters: presence of calcium carbonate in the cell wall; number of medullary cell layers in the basal area; number of medullary cell layers in the middle part and presence/absence of cortical cells. Comparative analysis of the species in the Gulf of California in relation to other recently evaluated species has shown a clear distinction among them suggesting Padina species were overestimated in our area.

Effect of Counter Anions on Solid Electrolyte Interphase Formation on Graphite Electrodes in Propylene Carbonate-based Electrolyte Solutions

  • Song, Hee-Youb;Kim, Seong In;Nogales, Paul Maldonado;Jeong, Soon-Ki
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.55-60
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    • 2019
  • Herein, the effect of counter anions on the formation of a solid electrolyte interphase (SEI) in a propylene carbonate (PC)-based electrolyte solution was investigated. Although the reversible capacities were different, reversible intercalation and de-intercalation of lithium ions occurred in the graphite negative electrode in the PC-based electrolyte solutions containing 1 M $LiClO_4$, $LiPF_6$, $LiBF_4$, and $LiCF_3SO_3$ at low temperature ($-15^{\circ}C$). This indicated that the surface films acted as an effective SEI to suppress further co-intercalation and decomposition reactions at low temperature. However, the SEIs formed at the low temperature were unstable in 1 M $LiPF_6$ and $LiBF_4/PC$ at room temperature ($25^{\circ}C$). On the other hand, increasing reversible capacity was confirmed in the case of $LiCF_3SO_3/PC$ at room temperature, because the SEI formed at the low temperature was still maintained. These results suggest that counter anions are an important factor to consider for the formation of effective SEIs in PC-based electrolyte solutions.

Electrochemical Lithium Insertion/Extraction for Carbonaceous Thin Film Electrodes in Propylene Carbonate Solution

  • Fukutsuka, Tomokazu;Abe, Takeshi;Inaba, Minoru;Ogumi, Zempachi;Matsuo, Yoshiaki;Sugie, Yosohiro
    • Carbon letters
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    • v.1 no.3_4
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    • pp.129-132
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    • 2001
  • Carbonaceous thin films were prepared from acetylene and argon gases by plasma assisted chemical vapor deposition (Plasma CVD) at 873 K. The carbonaceous thin films were characterized by mainly Raman spectroscopy, and their electrochemical properties were studied by cyclic voltammetry and charge-discharge measurements in propylene carbonate (PC) solution. Raman spectra showed that crystallinity of carbonaceous thin films is correlated by the applied RF power. The difference of the applied RF power also affected on the results of cyclic voltammetry and charge-discharge measurements. In PC solution, intercalation and de-intercalation of lithium ion can occur as well as in the mixed solution of EC and DEC.

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Production of uranium tetrafluoride from the effluent generated in the reconversion via ammonium uranyl carbonate

  • Neto, Joao Batista Silva;de Carvalho, Elita Fontenele Urano;Garcia, Rafael Henrique Lazzari;Saliba-Silva, Adonis Marcelo;Riella, Humberto Gracher;Durazzo, Michelangelo
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1711-1716
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    • 2017
  • Uranium tetrafluoride ($UF_4$) is the most used nuclear material for producing metallic uranium by reduction with Ca or Mg. Metallic uranium is a raw material for the manufacture of uranium silicide, $U_3Si_2$, which is the most suitable uranium compound for use as nuclear fuel for research reactors. By contrast, ammonium uranyl carbonate is a traditional uranium compound used for manufacturing uranium dioxide $UO_2$ fuel for nuclear power reactors or $U_3O_8-Al$ dispersion fuel for nuclear research reactors. This work describes a procedure for recovering uranium and ammonium fluoride ($NH_4F$) from a liquid residue generated during the production routine of ammonium uranyl carbonate, ending with $UF_4$ as a final product. The residue, consisting of a solution containing high concentrations of ammonium ($NH_4^+$), fluoride ($F^-$), and carbonate ($CO_3^{2-}$), has significant concentrations of uranium as $UO_2^{2+}$. From this residue, the proposed procedure consists of precipitating ammonium peroxide fluorouranate (APOFU) and $NH_4F$, while recovering the major part of uranium. Further, the remaining solution is concentrated by heating, and ammonium bifluoride ($NH_4HF_2$) is precipitated. As a final step, $NH_4HF_2$ is added to $UO_2$, inducing fluoridation and decomposition, resulting in $UF_4$ with adequate properties for metallic uranium manufacture.

New Record of Two Oligohymenophorean Ciliates (Protozoa: Ciliophora) from Korea

  • Jung, Jae-Ho
    • Animal Systematics, Evolution and Diversity
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    • v.37 no.4
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    • pp.280-286
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    • 2021
  • During a field survey on Korean coastal marine waters, two ciliates belonging to the genera Pseudovorticella Foissner & Schiffmann, 1975 and Frontonia Ehrenberg, 1838 in the class Oligohymenophorea de Puytorac et al., 1974, were collected. Even though the two genera are very common in the aquatic ecosystems, they had been superficially studied in Korean habitats. Using the observation of living cells and specimens impregnated by protargol, silver carbonate, and silver nitrate, two newly recorded ciliate are identified as P. paramarina Sun, Ji, Warren & Song, 2009 and F. ocularis Bullington, 1939. A brief diagnosis, remark, and comprehensive micrographs are provided for each species.

Recent Discovery of Secondary Mineral Deposits in an Idaho Lava Tube

  • Kesner, David W.
    • Journal of the speleological society of Korea
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    • no.4
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    • pp.33-39
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    • 1996
  • Secondary mineral deposits of gypsum, mirabilite, thenardite, crisobolite have long been known and, in fact, are quite common in lava tubes of southwest Idaho. Until recently, calcium carbonate were found in a few tubes in very small amounts and were thought to be qu are. The recent ‘rediscovery’ of Helen's Hidden Hide - Away lava tube h significantly changed this thinking. The deposits in this lava tube are only quite extensive but extremely varied in structure. As this is a v recent discovery, only basic preliminary work will be presented in t paper. It is hoped this will stimulate intrest for further and more inte study of the lava tubes of southwestern Idaho.

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Electrochemical Lithium Intercalation within Graphite from Ionic Liquids containing BDMI+ Cation (BDMI+ 양이온을 함유한 이온성 액체로부터 흑연으로의 전기화학적 리튬 삽입)

  • Lee, You-Shin;Jeong, Soon-Ki;Lee, Heon-Young;Kim, Chi-Su
    • Journal of the Korean Electrochemical Society
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    • v.13 no.3
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    • pp.186-192
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    • 2010
  • In situ electrochemical atomic force microscopy (ECAFM) observations of the surface of highly oriented pyrolytic graphite (HOPG) was performed before and after cyclic voltammetry in lithium bis(fluorosulfonyl)imide (LiTFSI) dissolved in 1-buthyl-2,3-dimethylimidazolium (BDMI)-TFSI to understand the interfacial reactions between graphite and BDMI-based ionic liquids. The formation of blisters and the exfoliation of graphene layers by the intercalation of $BDMI^+$ cations within HOPG were observed instead of reversible lithium intercalation and de-intercalation. On the other hand, lithium ions are reversibly intercalated into the HOPG and de-intercalatied from the HOPG without intercalation of the $BDMI^+$ cations in the presence of 15 wt% of 4.90 mol/$kg^{-1}$ LiTFSI dissolved in propylene carbonate (PC). ECAFM results revealed that the concentrated PC-based solution is a very effective additive for preventing $BDMI^+$ intercalation through the formation of solid electrolyte interface (SEI).

A Study On The Junctional Epithelial Downgrowth After DeEpithelization Using Pulsed Nd : YAG Laser In Rat Peiodontal Bone Defect Filled With Calcium Carbonate (백서 치주 골결손부에 calcium carbonate 이식 및 pulsed Nd:YAG 레이저에 의한 치은상피의 제거 후 접합상피의 치유양상)

  • Jeong, Cheol-Woong;Chung, Hyun-Ju
    • Journal of Periodontal and Implant Science
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    • v.26 no.1
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    • pp.276-292
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    • 1996
  • The purpose of this study was to evaluate whether removal of gingival epithelium with pulsed Nd :YAG laser could inhibit the downgrowth of junctional epithelium after alloplastic material grafting in periodontal bone defect. The periodontal bone defects were created surgically on the palatal aspect of the upper right and left molar teeth in 30 rats and filled with resorbable calcium carbonate($Biocoral\;450^{(R)}$: Inoteb, France). The control sites(right molar area) was sutured. The test side (left molar area) received controlled deepithelization of the oral and sulcular epithelium with pulsed Nd:YAG laser($Sunrise\;Maste^{(R)}$: Sunrise Technologies, U.S.A.) under the mode of 1.75W, 15Hz, 116mJ/pulse and was sutured. The control and test sites were evaluated clinically and histologically, at 1, 3, 7, 14, and 28 days postoperation. Clinically, the gingiva showed normal color and shape at the 5th day in the control site and at the 10th day in the test sites. Histologically, the junctional epithelium was formed at the 7th day in the control sites and at the 14th day in the test sites, and the long JE attachment were observed at the 28th day in both sites. The attachment of connective tissue to root surface was observed initially at the 7th day in the control sites and at the 14th day in the test sites, and completed at the 28th day in both sites. In summary, these results showed that the removal of oral epithelium using pulsed Nd:YAG Laser could not prevent epithelial downgrowth after alloplastic material implantation in rat periodontal bone defect.

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