• Title/Summary/Keyword: Diffusion zone

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Prediction of chloride diffusion coefficient of concrete under flexural cyclic load

  • Tran, Van Mien;Stitmannaithum, Boonchai;Nawa, Toyoharu
    • Computers and Concrete
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    • v.8 no.3
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    • pp.343-355
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    • 2011
  • This paper presented the model to predict the chloride diffusion coefficient in tension zone of plain concrete under flexural cyclic load. The fictitious crack based analytical model was used together with the stress degradation law in cracked zone to predict crack growth of plain concrete beams under flexural cyclic load. Then, under cyclic load, the chloride diffusion, in the steady state and one dimensional regime, through the tension zone of the plain concrete beam, in which microcracks were formed by a large number of cycles, was simulated with assumptions of continuously straight crack and uniform-size crack. The numerical analysis in terms of the chloride diffusion coefficient, $D_{tot}$, normalized $D_{tot}$, crack width and crack length was issued as a function of the load cycle, N, and load level, SR. The nonlinear model as regarding with the chloride diffusion coefficient in tension zone and the load level was proposed. According to this model, the chloride diffusion increases with increasing load level. The predictions using model fit well with experimental data when we adopted suitable crack density and tortuosity parameter.

Analytical Model of Salt Budget in the Upper Indian River Lagoon, Florida USA

  • Kim, Young-Taeg
    • Ocean and Polar Research
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    • v.26 no.1
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    • pp.33-42
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    • 2004
  • Effect of freshwater discharge on the long-term salt balance in the Northern and Central Indian River Lagoon (IRL) is successfully simulated by a new analytical solution to a water balance-based one-dimensional salt conservation equation. Sensitivity tests show that the salinity levels drop abruptly even during the dry season (November to May) due to the high surface runoff discharge caused by tropical storms, depressions, and passage of cold fronts. Increasing surface runoff and direct precipitation has risen by ten times, lowering the salinity level down to 12psu in the Northern Central zone, and to 17 psu in the Northern zone. However, the salinity level in the Southern Central zone has decreased to 25 psu. High sensitivity of the Northern Central zone to freshwater discharge can be partially explained by a rapid urbanization in this zone. During the dry season, less sensitivity of the Southern Central zone to the increased surface runoff is attributed to the proximity of the zone to the Sebastian Inlet and a strong diffusion condition possibly resulting from the seawater intrusion to the surficial aquifer at the Vero Beach. During the wet season, however, the whole study area is highly sensitive to freshwater discharge due to the weak diffusion conditions. High sensitivity of the IRL to the given diffusion conditions guarantees that the fresh-water release occurs during strong wind conditions, achieving both flood control in the drainage basin and a proper salinity regime in the IRL.

A Study on the Co-flow Diffusion Flame Temperature Measurement at Various Fuel Flows Rate Using the Rapid Insertion Technique (급속삽입법을 이용한 연료 유량에 따른 동축류 확산화염에서의 온도 측정에 관한 연구)

  • Han Yongtaek;Lee Kihyung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.1
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    • pp.51-59
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    • 2005
  • Co-flow laminar diffusion flames' temperature has been studied experimentally for ethylene$(C_2H_4)$ using a co-flow burner in order to investigate the characteristics of diffusion flame's temperature distribution. The temperature distributions in the flame were measured by rapid insertion of a R-type thermocouple. The measurement area was divided into three zones. 1st area was expect to created PAH zone, Il nd area was expect to form soot zone, which is known to generate most soot volume fraction, and III rd area was expect to from soot oxidization zone. Also The temperature along the flame y-axis as a fuel quantity was measured. As a results, we have measured temperature neglecting the effect of soot particles attached to the thermocouple junction, which is close to the nozzle and upstream zone has a unstable flow in co-flow diffusion flame and acquires that the flame y-axis temperature has a uniform temperature in the generated soot volume fraction zone(II nd).

Stabilization Characteristics of Diffusion Flame with Auxiliary Fuel Supply through a Bluff Body (보조연료의 공급이 확산화염의 보염특성에 미치는 영향)

  • An, J.G.;Song, K.K.
    • Journal of the Korean Society of Combustion
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    • v.1 no.1
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    • pp.11-18
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    • 1996
  • The stabilization characteristics of diffusion flame formed behind a bluff body with fuel injection slits was experimentally investigated by varying main fuel injection angles and auxiliary fuel injection conditions. The flame stability limits, temperature and length of recirculation zone, direct and schlieren photographs of flames were measured in order to study the stabilization mechanism of the diffusion flame. The results of this investigation are as follows. The stability limits can be improved by the condition of the kind and quanity of the injected auxiliary fuel. The length and temperature decrease with injection of auxiliary fuel, and these phenomena are remarkable when LPG is injected into the recirculation zone. When the LPG is injected into the recirculation zone, flame remains sooty. Fluctuation of fuel and main stream is generated actively by air injection.

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Derivation of the First-Order Mass-Transfer Equation for a Diffusion-Dominated Zone of a 2-D Pore (2차원으로 구현한 다공성 매질의 확산주도영역에 관한 1차 물질이동 방정식의 유도)

  • Kim, Young-Woo;Seo, Byong-Min;Hwang, Seung-Min;Park, Cha-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.2
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    • pp.99-103
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    • 2010
  • A new analytic solution was derived for the diffusion into or from an immobile zone of a rectangular 2-D pore. For a long time, the new solution converges to a traditional mobile-immobile zone (MIM) model, but only if the latter is used with an apparent initial concentration that is smaller by almost 20% than the true one. This is the tradeoff for using a simple MIM model instead of an exact model based on the diffusion equation. The mass-transfer coefficient was found to be constant for a sufficiently long time; it was proportional to the molecular diffusion and inversely proportional to the square of the pore depth. The mass-transfer coefficient was time-dependent for a sufficiently short time and may be significantly larger than its asymptotic value.

Analysis of Suspended Load using A Two-Dimensional Advection-Diffusion Equation in Coastal Zone (2차원 이송-확산 방정식을 이용한 해안에서의 부유사 해석)

  • Kang, Gyu-Young;Kim, Su-Jin;Cho, Yong-Sik
    • 한국방재학회:학술대회논문집
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    • 2007.02a
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    • pp.177-180
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    • 2007
  • Numerical simulations on the suspended load in the Do jang fish port are carried out. Suspended load is analysed by using the two-dimensional advection-diffusion equation. To describe behaviors of a pollutant in costal zone, a split-operator method is applied to the numerical model. The advection part is first solved by SOWMAC and then the diffusion part is solved by a three-level locally implicit scheme.

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Burke-Schumann analysis of silica formation by hydrolysis in an external chemical vapor deposition process (외부 화학증착 공정에서의 가수분해반응으로 인한 실리카 생성에 대한 버크-슈만 해석)

  • Song, Chang-Geol;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.5
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    • pp.1671-1678
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    • 1996
  • In external chemical vapor deposition processes including VAD and OVD the distribution of flame-synthesized silica particles is determined by heat and mass transfer limitations to particle formation. Combustion gas flow velocities are such that the particle diffusion time scale is longer than that of gas flow convection in the zone of particle formation. The consequence of these effects is that the particles formed tend to remain along straight smooth flow stream lines. Silica particles are formed due to oxidation and hydrolysis. In the hydrolysis, the particles are formed in diffuse bands and particle formation thus requires the diffusion of SiCl$\_$4/ toward CH$\_$4//O$\_$2/ combustion zone to react with H$\_$2/O diffusing away from these same zones on the torch face. The conversion kinetics of hydrolysis is fast compared to diffusion and the rate of conversion is thus diffusion-limited. In the language of combustion, the hydrolysis occurs as a Burke-Schumann process. In selected conditions, reaction zone shape and temperature distributions predicted by the Burke-Schumann analysis are introduced and compared with experimental data available. The calculated centerline temperatures inside the reaction zone agree well with the data, but the calculated values outside the reaction zone are a little higher than the data since the analysis does not consider diffusion in the axial direction and mixing of the combustion products with ambient air. The temperatures along the radial direction agree with the data near the centerline, but gradually diverge from the data as the distance is away from the centerline. This is caused by the convection in the radial direction, which is not considered in the analysis. Spatial distribution of silica particles are affected by convection and diffusion, resulting in a Gaussian form in the radial direction.

Chloride Penetration into Concrete in Tidal Zone by Diffusion-Convection Analysis (확산과 이송을 고려한 콘크리트의 염소이온 침투해석)

  • Kim, Ki-Hyun;Cha, Soo-Won;Jung, Hyung-Mok
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.22 no.6
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    • pp.607-615
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    • 2009
  • Analysis of chloride penetration into concrete is performed considering the repeated wetting and drying conditions of tidal zone, by means of the developed finite element program which enables the diffusion-convection analysis to be conducted. Heat conduction and moisture diffusion are also included in the finite element analysis program in order that their effects to chloride penetration may be considered. For the efficiency of calculation, the analyses of temperature, relative humidity and free chloride concentration are conducted successively in that order, by treating the convection of chloride due to moisture diffusion as an source or sink term. By comparing the analysis result from finite element analysis, where main variable is a wetting and drying period, with the chloride profiles from ACI Life-365 method, it is shown that the Life-365 method gives an accurate result for the submerged zone but does not consider the differences of wetting and drying period. To obtain an accurate chloride profile in the tidal zone, it is confirmed that the diffusion-convection finite element analysis should be applied.

Structure and Characteristics of Diffusion Flame behind a Bluff-Body in a Divergent Flow(I) (확대유로내의 Bluff-Body 후류확산화염의 구조 및 특성 (1))

  • 최병륜;이중성
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.5
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    • pp.1269-1279
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    • 1995
  • An experimental study is carried out on turbulent diffusion flames stabilized by a circular cylinder in a divergent duct flow. A commercial grade gaseous propane is injected from two slits on the rod as fuel. Flame stability limits, as well as size and temperrature of recirculation zone, are measured by direct and schlieren photographs to clarify the characteristics and structure of diffusion flames and to assess the effect of various divergent angle of duct. The results of the present study are as follows. Temperature in the recirculation zone decreases with increasing divergent angle. The blow-off velocity in parallel duct is higher than that in divergent duct. Critical blow-off velocity is expected to be about 8-12 degree through blow-off velocity pattern. Regardless of divergent angles, the length of recirculation zone is nearly constant, and this length becomes longer with rod diameter. Pressure gradient has an effect on the eddy structure in shear layer behind the rod. With the increase of divergent angle, large scale eddies by dissipated energy in shear layer are split into small scale eddies, and the flame becomes a typical distributedreacting flame.

Evaluation of Apparent Chloride Diffusion Coefficient of Fly Ash Concrete by Marine Environment Exposure Tests (해양 환경 폭로 시험을 통한 FA 콘크리트의 겉보기 염화물 확산계수 평가)

  • Yoon, Yong-Sik;Lim, Hee-Seob;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.3
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    • pp.119-126
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    • 2019
  • In case of RC(Reinforced Concrete) structures which are constructed in coastal areas, chloride ions in sea water corrode the steel rebar in concrete. Especially in coastal areas, RC structures are affected by not only immersion of sea water, but also tidal of sea water and airborne chloride ions. In this study, marine environment exposure tests are conducted, considering 3 types of exposure environments(immersion zone, tidal zone, splash zone) and the exposure periods of 180 days, 365 days, and 730 days. Also, the concrete mixtures for this study are established, considering 3 levels of W/B(Water to Binder) ratio(0.37, 0.42, 0.47) and 2 levels of substitution rate of Fly ash(0 %, 30 %). In all exposure environments, Fly ash concrete has lower apparent chloride diffusion coefficients than OPC concrete. It is thought that fly ash's pozzolan reaction improves chloride resistance of concrete. Fly ash concrete has up to 63.5 % of decreasing rate in 180 days of exposure and up to 55.8 % of decreasing rate in 730 days of exposure, based on diffusion coefficients of OPC concrete. As a result of evaluation about effects of exposure environments, apparent chloride diffusion coefficients of fly ash concrete are evaluated in order of tidal zone, immersion zone, and splash zone. In tidal zone, It is thought that repeated cycles of wetting and drying of sea water cause the diffusion of chloride ions rapidly.