• Title/Summary/Keyword: Dip-coating process

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Preparation and Electrochemical Characterization of SnO2/Ti Electrode by Coating Method (코팅 방법에 따른 SnO2/Ti 전극의 제조 및 전기화학적 특성)

  • Kim Han-Joo;Son Won-Keun;Hong Ji-Sook;Kim Tae-Il;Park Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.9 no.2
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    • pp.59-63
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    • 2006
  • The study is coated tin(IV) oxide coated on the titanium substrate electrodes by electrodepositon and dip-coating method and studied about that physical and electrochemical characterization by coating methods. After titanium substrate is etched in HCl, electrodespotion is coated $SnCl_2{\cdot}2H_2O$ in nitrate solution by pulse technique, dip-coating method is also used $SnCl_2{\cdot}2H_2O$ in 1;1V% HCl and coated by dipping and annealing process. tin(IV) oxide coated on titanium substrate electrodes by two coating methods are studied x-ray diffraction (XRD), scanning electron microscopy (SEM) to compare physical characterization of electrode and potential window by cyclic voltammetry (CV) to observe electrochemical characterization.

Manufacture of Recycled PET E-Textile by Plasma Surface Modification and CNT Dip-Coating (플라즈마 표면 개질과 CNT 함침공정을 통한 고전도성의 재생PET사 전자섬유)

  • Jun-hyeok Jang;Sang-un Kim;Joo-Yong Kim
    • Science of Emotion and Sensibility
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    • v.26 no.1
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    • pp.79-86
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    • 2023
  • This study aims to create a highly conductive E-textile made by recycling PET with a Dip-coating process. PET fiber with hydrophobic properties is characterized by the difficulty in imparting great conductivity when both Virgin and Recycled are made of electronic fibers through a Dip-coating process. To advance the effectiveness of the Dip-coating process, a sample made of recycled PET was surface modified for 50 w 5 minutes and 10 minutes employing a Covance-2mprfq model from FEMTO SCIENCE. After that, the sample was immersed in an SWCNT dispersion (.1 wt%, Carbon Co., Ltd.) for 5 minutes, and then dip coating was conducted to allow the solution to permeate well into the sample through a padder (DAELIM lab). After the procedure was completed, the resistance measurement was measured with a multimeter at both ends and then accurately remeasured with a wider electrode. As a result of this contemplation, it was affirmed that great conductivity might be given through an impregnation process through the plasma surface modification. When the surface modification was performed for 10 minutes, the resistance was reduced by up to 2.880 times. Dependent on the results of this research, E-fibers employed in the smart wearable sector can also be made of recycled materials, improving smart wearable products that can save oil resources and reduce carbon emissions.

Fabrication Of Thin Electrolyte Layer For Solid Oxide Fuel Cell by Vacuum Slurry Dip-coating Process (진공 슬러리 담금 코팅 공정에 의한 고체 산화물 연료전지용 박막 전해질막 제조에 관한 연구)

  • Son, Hui-Jeong;Lim, Tak-Hyoung;Lee, Seung-Bok;Shin, Dong-Tyul;Song, Rak-Hyun;Kim, Sung-Hyun
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.2
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    • pp.204-211
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    • 2006
  • The electrolyte in the solid oxide fuel cell must be dense enough to avoid gas leakage and thin enough to reduce the ohmic resistance. In order to manufacture the thin and dense electrolyte layer, 8 mol% $Y_2O_3$ stabilized-$ZrO_2$ (8YSZ) electrolyte layers were coated on the porous tubular substrate by the novel vacuum slurry dip-coating process. The effects of the slurry concentration, presintering temperature, and vacuum pressure on the thickness and the gas permeability of the coated electrolyte layers have been examined in the vacuum slurry coating process. The vacuum-coated electrolyte layers showed very low gas permeabilities and had thin thicknesses. The single cell with the vacuum-coated electrolyte layer indicated a good performance of $495\;mW/cm^2$, 0.7 V at $700^{\circ}C$. The experimental results show that the vacuum dip-coating process is an effective method to fabricate dense thin film on the porous tubular substrate.

A Study on the Improvement of the Interface Contact and the Prevention of the Charge Recombination by the Surface Treatment of Transparent Conductive Oxide in Dye-sensitized Solar Cell (염료감응형 태양전지 투명전도성 막의 표면처리를 통한 계면 접촉 향상 및 재결합 방지 연구)

  • Seo, Hyun-Woong;Hong, Ji-Tae;Son, Min-Kyu;Kim, Jin-Kyoung;Shin, In-Young;Kim, Hee-Je
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.11
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    • pp.2214-2218
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    • 2009
  • Dye-sensitized solar cell (DSC) has been considered as a possible alternative to current silicon based p-n junction photovoltaic devices due to its advantages of high efficiency, simple fabrication process and low production cost. Numerous researches for high efficient DSC in the various fields are under way even now. Among them, the compact layer, which prevents the back electron transfer between transparent conductive oxides and the redox electrolyte, is fabricated by various methods such as a ZnO dip-coating, $TiCl_4$ dip-coating, and Ti sputtering. In this study, we tried to fabricate the $TiO_2$ compact layer by the spin-coating method using aqueous $TiCl_4$ solution. The effect of the spin-coating method was checked as compared with conventional dip-coating method. As a result, DSC with a spin-coated compact layer had 33.4% and 6% better efficiency than standard DSC and DSC with a dip-coated compact layer.

Hydrogen Permeation of SiC-CeO2 Composite Membrane by Dip-coating Process

  • Park, Jihye;Jung, Miewon
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.485-488
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    • 2013
  • A SiC-$CeO_2$ composite membrane was successfully fabricated using an ally-hydridopolycarbosilane (AHPCS) binder and treated by dip-coating at 60 times with a $CeO_2$ sol solution. The dip-coated SiC membrane was calcined at 773 K and then sintered at 1173 K under an air atmosphere. The coated membrane was characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and a BET surface analysis. The difference in permeation performance between $H_2$ and CO gases was measured by varying the temperature. The permeation flux of $H_2$ on the SiC membrane with layered $CeO_2$ was obtained as $8.45{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The CO permeation flux was $2.64{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The reaction enthalpy (${\Delta}H^{\circ}$) for the hydrogen permeation process was calculated as -7.82 J/mol by Arrhenius plots.

Investigation of Streaky Mark Defect on Hot Dip Galvannealed IF Steel

  • Xinyan, Jin;Li, Wang;Xin, Liu
    • Corrosion Science and Technology
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    • v.9 no.3
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    • pp.109-115
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    • 2010
  • Interstitial-free (IF) steels are widely used for car body material. However, a few types of streaky mark defect are commonly found on hot dip galvannealed (GA) IF steel sheets. In the present study, both the phase structure of a streaky mark defect and the microstructure of the substrate just below it were characterized by optical microscopy (OM) and scanning electron microscopy (SEM). It was found that the bright streaky mark area was composed of ${\delta}$ phase while the dark normal area was full of craters. More than half of the grains at the uppermost surface of the substrate just below the streaky mark defect are unrecrystallized grains which could result from lower finish rolling temperature during hot rolling and be kept stable during the annealing process, while almost all the grains in the normal area are equiaxed grains. In order to confirm the effect of the unrecrystallized grains on the coating morphology, hot dip galvannealing simulation experiments were carried out in IWATANI HDPS. It is proved that the unrecrystallized grains accelerate the Fe-Zn reaction rate during galvannealing and result in a flatter coating surface and an even coating thickness. Finally, a formation mechanism of the streaky mark defect on the hot dip galvannealed IF steel sheet was discussed.

A Numerical Analysis on the Coating Thickness in Continuous Hot-Dip Galvanizing (연속 아연 도금 코-팅 두께에 관한 수치 해석적 연구)

  • Lee, Dong-Won;Shin, Seung-Young;Kim, Byung-Ji;Kwon, Young-Doo;Kwon, Soon-Bum
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2955-2960
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    • 2007
  • To control the coating thickness of zinc in the process of continuous hot-dip galvanizing, it is known from early day that the gas wiping through an air knife system is the most effective because of the obtainable of uniformity of coating thickness, possibility of thin coating, working ability in high speed and simplicity of control. But, the gas wiping using in the galvanizing process brings about a problem of splashing from the strip edge for a certain high speed of coating. And, it is known that the problem of splashing is caused mainly by the existence of separation bubble at the neighbor of the strip surface. In theses connections, in the present study, we proposed two kinds of air knife systems having the same expansion rate of nozzle, and the jet structures and coating thicknesses from a conventional and new proposed nozzles are compared. In numerical analysis, the governing equations consisted of two-dimensional time dependent Navier-Stokes equations, standard ${\kappa}-{\varepsilon}$ turbulence model to solve turbulence stress and so on are employed. As a result, it is found that it had better to use the constant rate nozzle from the point view of the energy saving to obtain the same coating thickness. Also, to reduce the size of separation bubble and to enhance the cutting ability at the strip, it is recommendable to use an air knife having the constant expansion rate nozzle.

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A NUMERICAL STUDY ON THE COATING THICKNESS IN CONTINUOUS HOT-DIP GALVANIZING (연속 아연 도금 두께에 관한 수치 해석적 연구)

  • Lee, Dong-Won;Shin, Seung-Young;Cho, Tae-Seok;Kwon, Young-Doo;Kwon, Soon-Bum
    • Journal of computational fluids engineering
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    • v.14 no.1
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    • pp.1-8
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    • 2009
  • To control the coating thickness of zinc in the process of continuous hot-dip galvanizing, it is known from early days that the gas wiping through an air knife system is the most effective because of the obtainable of uniformity of coating thickness, possibility of thin coating, working ability in high speed and simplicity of control. But, the gas wiping using in the galvanizing process brings about a problem of splashing from the strip edge for a certain high speed of coating. Also, it is known that the problem of splashing directly depends upon the galvanizing speed and nozzle stagnation pressure. In theses connections, in the present study, we proposed two kinds of air knife systems having the same expansion rate of nozzle, and the jet structures and coating thicknesses from a conventional and new proposed nozzles are compared. In numerical analysis, the governing equations consisted of two-dimensional time dependent Navier-Stokes equations, standard k-e turbulence model to solve turbulence stress and so on are employed. As a result, it is found that it had better to use the constant rate nozzle from the point view of the energy saving to obtain the same coating thickness. Also, to enhance the cutting ability at the strip, it is advisable to use an air knife with the constant expansion rate nozzle.

Preparation of Silicon Carbide Ceramic Thick Films by Liquid Process (액상공정을 이용한 탄화규소 세라믹 후막의 제조)

  • Kim, Haeng-Man;Kim, Jun-Su;Lee, Hong-Rim;Ahn, Young-Cheol;Yun, Jon-Do
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.95-99
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    • 2012
  • Silicon carbide ceramics are used for oxidation resistive coating films due to their excellent properties like high strength, good oxidation resistance, and good abrasion resistance, but they have poor formability and are prepared by vapor process which is complicated, costly, and sometimes hazardous. In this study, preparation of silicon carbide coating film by liquid process using polymer precursor was attempted. Coating film was prepared by dip coating on substrate followed by heat treatment in argon at $1200^{\circ}C$. By changing the dipping speed, the thickness was controlled. The effects of plasticizer, binder, or fiber addition on suppression of crack generation in the polymer and ceramic films were examined. It was found that fiber additives was effective for suppressing crack generation.