• 한국염색가공학회지
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• 제19권5호
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• pp.8-16
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• 2007

The dye-resist effect of reactive dye-resist agents in reactive dyeing of silk was investigated. The dichlorotriazine-based dye-resists achieved a higher effectiveness than others since they make a charge barrier of diffusion in the silk fiber periphery due to high reactivity of dichlorotriazine group. Similarly, in the case of hetero-multifunctional dye-resist agent, the dye-resist agent containing both a dichlorotriazine and an ${\alpha}$-bromoacrylamide reactive groups achieved better resist effectiveness than those containing both a monochlorotriazine and an ${\alpha}$-bromoacrylamide groups. Also, their resist effectiveness was improved by increasing the number of sulfonate groups in the dye-resist agents and the number of reactive groups in the reactive dyes applied to them.

• Fibers and Polymers
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• 제7권2호
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• pp.117-122
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• 2006

The dye-resist effect and leveling properties of hetero-mulifunctional dye-resist agents in acid dyeing of wool were investigated. The dye-resist agent with dichlorotriazinyl group achieved better resist effectiveness than those with monochlo-rotriazinyl group. The resist effectiveness was improved by increasing the number of sulfonate group in dye-resist agents. Also, the resist agents with more sulfonate groups showed better dye-assist effectivness, attributable to the increased electrostatic attraction between dye-resist agents and the cationic dye. However, the leveling properties of dye-resist agents decreased with the number of sulfonate groups in the molecule.

• 한국염색가공학회지
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• 제7권3호
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• pp.22-30
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• 1995

The effects of agents in padding liquor on the fixation of vinylsulfonyl reactive dye of ground color and on the resist-dischargeability in resist-discharge printing of cotton fabrics with reactive/reactive dyes were investigated. Alkalis, such as sodium bicarbonate, sodium carbonate, sodium acetate and trichloro sodium acetate, were used to fix the dye for ground color on cotton fabrics. Sodium bicarbonate and sodium carbonate showed a good fixation of the dye for ground color, but they were ineffective to the white and the colored resistdsichargeabilities, which were caused by the fast fixation of the dye for ground color before its reaction with resist agent in printing paste. Therefore these are not suitable for the agent to fix the dyes for ground color because they deteriorate the resist-dischargeability. In case of sodium acetate, as the fixation yield of the dye for ground color was remarkably low. and the white resistdischargeability was not good, it had better not be used for the agent to fix the dye for ground color. However, the addition of sodium trichloroacetate to padding liquor gave a very good fixation yield of ground color, and showed an excellent resist-dischargeability. The effects of acetic acid in padding liquor on the fixation of the dye for ground color and on the resist-dischargeability were studied in case of immediate printing of resist-discharge pastes after padding and drying and in cases of printing after 1∼3 day-storage of padded goods. By the addition of 2% of 48% acetic acid aqueous solution to padding liquor, the white and the colored resist-dischargeabilities were improved and the fixation of the dye for ground color was good without any troubles. Especially, when the padded goods were stored for 2 or 3 days and printed with resist-discharge printing pastes, its addition was very effective on the resist-dischargeability.

• 한국염색가공학회지
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• 제6권3호
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• pp.67-73
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• 1994

The adsorption behaviors of acid dye and disperse dye on silk and nylon fabrics were examined, in one bath dyeing system on silk/nylon blend fabric with disperse dyes and acid dyes. In the dyeing of nylon fabric with C. I. Disperse Red 19 (Red 19) and C. I. Disperse Red 60 (Red 60), dye uptake of Red 19 was higher than that of Red 60. When silk/nylon blend fabric was dyed with Red 19 and Red 0, the dye uptake on nylon was influenced by the ffinity of the dye to the silk fabric. In the dyeing of silk/nylon with C. I. Acid Blue 80 and C. I. Acid Yellow 121, solid shade could not be obtained with the conventional method but could be obtained with the dyeing resist agent for nylon. There was not any relationship between K/S value and Munsell value, but Munsell value tended to change with the K/S value.

• 한국염색가공학회지
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• 제10권3호
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• pp.1-9
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• 1998

The dyeing properties of modified wool were examined with a series of acid, reactive and cationic dyes. Cationic agent and sulphamic acid were applied to wool fabric for dye assist and resist effect. Wool pretreated with cationic agent showed better uptake of acid and reactive dyes than did untreated wool. On the other hand, the dyeing behavior of wool pretreated with sulphamic acid was found as follows : Acid dyes were poorly resisted with a hydrophobic mechanism but acid dyes were strongly resisted with a hydrophilic mechanism. Reactive dyes were also found to be effectively resisted. Sulphamic acid introduces sulphonate group into wool's structure, it has increased better uptake of cationic dyes than untreated wool. The degree of differential uptake depends on the level of pretreatment and produces a variety of tone-on-tone and multicolor effect in piece dyeing.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2001년도 추계학술발표회 논문집
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• pp.3-11
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• 2001

Fundamental studies at the CSIRO division of Wool technology and ICI on the diffusion of dyes into wool〔1,2〕have let to development of a new approach to wool dyeing. In this method, the cell membrane complex of wool is modified before dyeing by treatment under mildly alkaline conditions with a special chemicals. Wool pretreated with ethoxylated quaternary ammonium salt has an increased rate of dyebath exhaustion and dye penetration early in the dyeing cycle. This enables the treated material to be dyed below the boil for a similar time to the conventional cycle. This technique can be used on untreated and shrinkresist-treated wool and wool/nylon blends. In addition to good macro-levelness and excellent coverage of tippiness, the low temperature dyeing process give higher exhaustion levels of dyestuffs and insect-resist agent and hence cleaner effluent liquors, compared with conventional dyeing process. Low Temperature Dyeing process cause significantly less fiber damage than conventional way. The reduction in damage is reflected in improved processing performance of the dyed wool.