• 한국연소학회지
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• 제19권4호
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• pp.28-34
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• 2014

Numerical study is conducted to grasp flame characteristics in $H_2/CO$ syngas counterflow diffusion flames diluted with He and Ar. An effective fuel Lewis number, applicable to premixed burning regime and even to moderately-stretched diffusion flames, is suggested through the comparison among fuel Lewis number, effective Lewis number, and effective fuel Lewis number. Flame characteristics with and without the suppression of the diffusivities of H, $H_2$, and He are compared in order to clarify the important role of preferential diffusion effects through them. It is found that the scarcity of H and He in reaction zone increases flame temperature whereas that of $H_2$ deteriorates flame temperature. Impact of preferential diffusion of H, $H_2$, and He in flame characteristics is also addressed to reaction pathways for the purpose of displaying chemical effects.

• 한국연소학회지
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• 제16권2호
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• pp.23-32
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• 2011

To investigate cell formation in hydrocarbon/hydrogen/carbon monoxide-air premixed flames, the outward propagation and cellular instabilities were experimentally studied in a constant pressure combustion chamber at room temperature and elevated pressures. Unstretched laminar burning velocities and Markstein lengths of the mixtures were obtained by analyzing high-speed schlieren images. In this study, hydrodynamic and diffusional- thermal instabilities were evaluated to examine their effects on flame instabilities. The experimentally-measured unstretched laminar burning velocities were compared to numerical predictions using the PREMIX code. Effective Lewis numbers of premixed flames with methane addition decreased for all of the cases; meanwhile, effective Lewis numbers with propane addition increased for lean and stoichiometric conditions and increased for rich and stoichiometric cases for hydrogen-enriched flames. With the addition of propane, the propensity for cell formation significantly was diminished, whereas cellular instabilities for hydrogen-enriched flames were promoted. However, similar behavior of cellularity was obtained with the addition of methane to the reactant mixtures.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.236-242
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• 2014

Isospecific propylene polymerization behavior of meta- and para-Lewis base (E) functionalized unbridged zirconocenes ($[1-(E_n-Ph)-3,4-Me_2C_5H_2]_2ZrCl_2$, E = $NMe_2$, OMe; n = 1 or 2) was investigated under bulk conditions. Catalytic activity of the zirconocenes, and molecular weight and isotacticity of polypropylenes are found to be dependent on the position and number of the Lewis base functional groups in the zirconocenes. All the crude polypropylenes possess a broad molecular weight distribution and multi-melting transitions, indicating an involvement of multi-catalytic active species in the polymerization. The highest [mmmm] value of an isotactic portion of the polypropylenes reached 89%, which is higher than that (85%) from the well-known $C_2$-symmetric EBIZr (rac-$Et(Ind)_2ZrCl_2$) catalyst. These results support that the in situ generated, rigid rac-like cation-anion pair through the Lewis acid-base interactions between the functional groups of zirconocenes and methylaluminoxane anion is effective in the formation of isotactic polypropylene under bulk propylene polymerization conditions.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.191-196
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• 2009

Experiments were conducted in a constant pressure combustion chamber using schlieren system to investigate the effects of carbon dioxide/nitrogen/helium diluents on cellular instabilities of syngas-air premixed flames at room temperature and elevated pressures. Laminar burning velocities and Markstein lengths were calculated by analyzing high-speed schlieren images at various diluent concentrations and equivalence ratios. Experimental results showed substantial reduction of the laminar burning velocities and of the Markstein lengths with the diluent additions in the fuel blends. Effective Lewis numbers of helium-diluted syngas-air flames increased but those of carbon dioxide- and nitrogen-diluted syngas-air flames decreased in increase of diluents in the reactant mixtures. With helium diluent, the propensity for cells formation was significantly diminished, whereas the cellular instabilities for carbon dioxide-diluted and nitrogen-diluted syngas-air flames were not suppressed.

• 한국의류학회지
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• 제22권8호
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• pp.1060-1068
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• 1998

The effects of various catalysts and softners on the anti-crease finish of ramie with glyoxal were investigated. A number of metal salts commonly used as Lewis acid catalysts in DP finishing of cotton with formaldehyde and N-methylol agents were screened for glyoxal treatment of ramie fabric. Various organic and inorganic acids were mixed with Lewis acid catalyst as co-catalysts to improve catalytic activity. As a result, the combination of aluminum sulfate and citric acid was proven highly effective in catalyzing the crosslinking of ramie cellulose by glyoxal under lower curing temperature. With a mixed catalyst, performance properties, such as whiteness and tearing strength as well as wrinkle recovery of treated ramie fabric were improved as compared with that treated with aluminum sulfate alone. Additional improvement of tearing strength and wrinkle recovery was achieved by applying silicons softner in the treatment bath.

• 한국연소학회지
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• 제17권3호
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• pp.17-29
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• 2012

The effects of strain rate and preferential diffusion of $H_2$ on flame extinction are numerically studied in interacting premixed syngas-air flames with fuel compositions of 50% $H_2$ + 50% CO and 30% $H_2$ + 70% CO. Flame stability diagrams mapping lower and upper limit fuel concentrations at flame extinction as a function of strain rate are examined. Increasing strain rate reduces the boundaries of both flammable lean and rich fuel concentrations and produces a flammable island and subsequently even a point, implying that there exists a limit strain rate over which interacting flame cannot be sustained anymore. Even if effective Lewis numbers are slightly larger than unity on extinction boundaries, the shape of the lean extinction boundary is slanted even at low strain rate, i.e. $a_g=30s^{-1}$ and is more slanted in further increase of strain rate, implying that flame interaction on lean extinction boundary is strong and thus hydrogen (as a deficient reactant) Lewis number much less than unity plays an important role of flame interaction. It is also shown that effects of preferential diffusion of $H_2$ cause flame interaction to be stronger on lean extinction boundaries and weaker on rich extinction boundaries. Detailed analyses are made through the comparison between flame structures with and without the restriction of the diffusivities of $H_2$ and H in symmetric and asymmetric fuel compositions. The reduction of flammable fuel compositions in increase of strain rate suggests that the mechanism of flame extinction is significant conductive heat loss from the stronger flame to ambience.

• 한국연소학회지
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• 제21권1호
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• pp.8-17
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• 2016

Downstream interactions between lean premixed flames with mutually different fuels of syngas and $CH_4$ have been numerically investigated particularly on and near lean extinction limits. The interaction characteristics between lean premixed (50% $H_2$ + 50% CO)-air and $CH_4$-air flames were shown to be quite different from those between the same hydrocarbon flames. The lean extinction boundaries were of slanted shape, thereby implying strong interactions. The weaker flames had negative flame speeds on the upper extinction boundaries, whereas the weaker flame speeds on the lower extinction boundaries were both negative and positive. The results also showed that the flame interaction characteristics did not follow the general tendency with the dependency of Lewis number in downstream interactions between the same hydrocarbon flames. Importance of chemical interaction in flame characteristics is discussed in the downstream interactions between lean premixed (50% $H_2$ + 50% CO)-air and $CH_4$-air flames.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.65-73
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• 2003

An experimental study on flame lift-off characteristics of propane jet flame highly diluted with nitrogen has been conducted introducing acoustic forcing with a tube resonant frequency. A flame stability curve is attained according to forcing strength and nozzle exit velocity for $N_2$ diluted flames. Flame lift-off behavior with forcing strength and nozzle exit velocity is globally categorized into three; a well premixed behavior caused by a collapsible mixing for large forcing strength, a coexistent behavior of well-premixed and edge flames interacting with well-organized inner fuel vortices for moderate forcing strengths, and edge flame behavior for small forcing strengths. Special focus is concentrated on the coexistent behavior of the flame base in lifted flame since this may give a hint to a possibility which the flame base behaves like a well-mixed premixed flame in highly turbulent lifted flames. It is also shown that the acoustic forcing to self-pulsating laminar lifted flame affects flame lift-off behavior considerably which is closely related to downstream flow velocity, mixture strength, effective fuel Lewis number, and flame stretch.

• 한국수소및신에너지학회논문집
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• 제29권6호
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• pp.668-679
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• 2018

Experimental and numerical data were compared through a counterflow burner for the characteristic of basic flame about SNG- C11. In order to use the numerical mechanism accurately, the validation was carried out at strain rate ($a_g=30$, $120s^{-1}$) and the UCSD model showed satisfactory results. The effective Lewis number of the extinction boundary, and the behavior of extinction for the symmetric flames of the SNG-C11, could be explained through the trend of $Le_V$, and the flame of the extinction condition was inspected by the major species, key radicals and the chemical reaction paths. The interactions phenomenon in the merged flames has chemical reaction path for producing $HO_2$ were generated at stagnation point. It can be expected the one of major factors in interaction phenomenon.

• 한국수소및신에너지학회논문집
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• 제34권1호
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• pp.47-58
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• 2023

Experimental data conducted by Colson et al. and numerical data conducted in this study were compared through counterflow flames to understand of the characteristic of basic flame about mixture of ammonia/methane. In order to use the suitable numerical mechanism, the validation was performed using total four mechanisms and the Okafor's mechanism showed satisfactory experimental results. The extinction boundary of the stability map could be explained through the effective Lewis number and the trend of LeD. The extinction behavior of the flame was different under the lean and rich symmetric conditions and it was investigated by the major variables, global strain rate (a_g) and mole fraction of ammonia (Ω_NH3).